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Application of coagulation pretreatment for enhancing the performance of ceramic membrane filtration

세라믹 막여과의 성능향상을 위한 응집 전처리의 적용

  • Kang, Joon-Seok (Department of Environmental Engineering and Energy, Myongji University) ;
  • Song, Jiyoung (Department of Environmental Engineering and Energy, Myongji University) ;
  • Park, Seogyeong (Department of Environmental Engineering and Energy, Myongji University) ;
  • Jeong, Ahyoung (Department of Environmental Engineering and Energy, Myongji University) ;
  • Lee, Jeong-Jun (Department of Environmental Engineering and Energy, Myongji University) ;
  • Seo, Inseok (Water Supply Resurch Center, K-water Institute) ;
  • Chae, Seonha (Water Supply Resurch Center, K-water Institute) ;
  • Kim, Seongsu (Water Supply Resurch Center, K-water Institute) ;
  • Kim, Han-Seung (Department of Environmental Engineering and Energy, Myongji University)
  • 강준석 (명지대학교 환경에너지공학과) ;
  • 송지영 (명지대학교 환경에너지공학과) ;
  • 박서경 (명지대학교 환경에너지공학과) ;
  • 정아영 (명지대학교 환경에너지공학과) ;
  • 이정준 (명지대학교 환경에너지공학과) ;
  • 서인석 (K-water 연구원 스마트워터연구소) ;
  • 채선하 (K-water 연구원 스마트워터연구소) ;
  • 김성수 (K-water 연구원 스마트워터연구소) ;
  • 김한승 (명지대학교 환경에너지공학과)
  • Received : 2017.07.10
  • Accepted : 2017.11.10
  • Published : 2017.12.15

Abstract

In this study, it is estimated that ceramic membrane process which can operate stably in harsh conditions replacing existing organic membrane connected with coagulation, sedimentation etc.. Jar-test was conducted by using artificial raw water containing kaolin and humic acid. It was observed that coagulant (A-PAC, 10.6%) 4mg/l is the optimal dose. As a results of evaluation of membrane single filtration process (A), coagulation-membrane filtration process (B) and coagulation-sedimentation-membrane filtration process (C), TMP variation is stable regardless of in Flux $2m^3/m^2{\cdot}day$. But in Flux $5m^3/m^2{\cdot}day$, it show change of 1-89.3 kpa by process. TMP of process (B) and (C) is increased 11.8, 0.6 kpa each. But, the (A) showed the greatest change of TMP. When evaluate (A) and (C) in Flux $10m^3/m^2{\cdot}day$, TMP of (A) stopped operation being exceeded 120 kpa in 20 minutes. On the other hand, TMP of (C) is increased only 3 kpa in 120 minutes. Through this, membrane filtration process can be operated stably by using the linkage between the pretreatment process and the ceramic membrane filtration process. Turbidity of treated water remained under 0.1 NTU regardless of flux condition and DOC and $UV_{254}$ showed a removal rate of 65-85%, 95% more each at process connected with pretreatment. Physical cleaning was carried out using water and air of 500kpa to show the recovery of pollutants formed on membrane surface by filtration. In (A) process, TMP has increased rapidly and decreased the recovery by physical cleaning as the flux rises. This means that contamination on membrane surface is irreversible fouling difficult to recover by using physical cleaning. Process (B) and (C) are observed high recovery rate of 60% more in high flux and especially recovery rate of process (B) is the highest at 95.8%. This can be judged that the coagulation flocs in the raw water formed cake layer with irreversible fouling and are favorable to physical cleaning. As a result of estimation, observe that ceramic membrane filtration connected with pretreatment improves efficiency of filtration and recovery rate of physical cleaning. And ceramic membrane which is possible to operate in the higher flux than organic membrane can be reduce the area of water purification facilities and secure a stable quantity of water by connecting the ceramic membrane with pretreatment process.

Keywords

References

  1. Ahn, Y. T., Lee, C. Y., Jang, H. S. and Shin, H. S. (2005). Direct observation of membrane fouling in PAC-MF process, J. KSWW, KSWE, 91-95.
  2. Cha, B. J. and Chi, S. D. (2011). Recent Trends and Prospect in Microfiltration Membrane, KIC News, 14(6), 29-37.
  3. Chan, K. K. and Brownstein, A. M.(1991). Ceramic Membranes-Growth Prospects and Opportunities, Am. Ceram. Soc. Bull., 70(4), 703-707.
  4. Charpin, J., Bergez, P., Valin, F., Barnier, H., Maurel, A., Martinate, J.M.(1987). Inorganic membranes : Preparation, Characterization, Specific Application, High Tech Ceramics(P. Vincenzini, ed.), Elsevier, Amsterdam, 2211-2225.
  5. Choksuchart, P., Heran M. and Grasmick A. (2002). Ultrafiltration enhanced by coagulation in an immersed membrane system, Desalination, 145, 265-272. https://doi.org/10.1016/S0011-9164(02)00421-6
  6. Crozes, G., White, P. and Marshall, M. (1995). Enhanced Coagulation: its Effect on NOM Removal and Chemical cost, J. AWWA., 87(1), 78-89. https://doi.org/10.1002/j.1551-8833.1995.tb06303.x
  7. Gregory, J.(1988), Colloidal interactions, Material Science Forum, 25-26, 125-144. https://doi.org/10.4028/www.scientific.net/MSF.25-26.125
  8. Gregory, J. and Duan, J. (2001). Hydrolysing metal salts as coagulants, Pure Appl. Chem., 73(12), 2017-2026. https://doi.org/10.1351/pac200173122017
  9. Guigui, C., Rouch, J.C., Durand-Bourlier, L., Bonnelye, V. and Aptel P. (2002). Impact of coagulation conditions on the in-line coagulation/UF process for drinking water production, Desalination, 147, 95-100. https://doi.org/10.1016/S0011-9164(02)00582-9
  10. Ha, C. W. (2013). Ozonation and/or coagulation-ceramic membrane hybrid for filtration of impaired-Quality source waters, Doctor of Philosophy's Thesis, King Abdullah University of Science and Technology Thuwal, Kingdom of Saudi Arabia, 50-51.
  11. Hong, S. H., Bae, C. H., Huh, W. S. and Zhoh, C. K. (1999). Removal of heavy metals and natural organic matter by chemical treatment in drinking water-The study for the removal of natural organic matters and the behavior of activated carbon adsorption with coagulation condition, J. KSEE, 21(3), 525-535.
  12. Hyun, S. H. (1993). Present Status and Preparation Technology of Ceramic Membrane, J. Korean Membrane, 3(1), 1-11.
  13. You, S. J., Park, S. H., Lim, J. L., Suh, J. M., Jang, S. H., Hong, S. C., Yi, P. I.(2014). Removal characteristics of NOM in advanced water treatment using ceramic MF membrane, JSKWW, 367-376.
  14. Kim, C. S., Choi, S. I. and Lee, G. C. (2000). Effect of Coagulation on Adsorptive Capacity of Powdered Activated Carbon, J. KSWQ, 16(2), 211-222.
  15. Kim, E. O. (1993). Application of Ceramic Membrane, J. Korean Membrane, 3(1), 12-21.
  16. Kim, M. H. and Park, J. Y. (2001). Membrane Fouling control Effect of periodic Water-back-flushing in the Tubular Carbon Ceramic Ultrafiltration system for Recycling Paper wastewater, Car, J. Korean Membrane, 11(4), 190-203.
  17. Kweon, J. H., Choi, Y. H., Lee, S. H., Ahn, K. H. (2004). "Coagulation Characteristics of a Natural Water and the Effects on MIcrofiltration", Proceedings of the autumn Co-Conference of the Korean society on Water Environment and Korean Society of Water and wastewater, 3-4, November, 2004, Daejeon, Korea.
  18. Kwon, H. S., Kim, S .J., Yeon, Y. C., Kim, J. W. and Jung, D. M. (2008). Optimal Dose of Powdered Activated Carbon for 2-MIB and Organic Matters Removal, J. KSEE, 804-810.
  19. Lee, J., Lee, S., Jo, M., Park, P., Lee, C. and Kwak, J. (2000). Effect of Coagulation Conditions on Membrane Filtration Characteristics in Coagulation-Microfiltration Process for Water Treatment, Environmental Science & Technology 34(17), 3780-3788. https://doi.org/10.1021/es9907461
  20. Lee, Y. T. and Oh, J. K. (1999). A study on the Optimization of Process and Operation Condition for Membrane System in Tap Water Treatment, J. KOR. Korean Membrane, 9(4), 193-201.
  21. Lee, Y. T. and Oh, J. K. (2003). Membrane Fouling Effect with Organic-Inorganic Materials Using the Membrane Separation in Drinking Water Treatment process, J. Korean Membrane, 13(4), 219-228.
  22. Miltner, R. J., Speth, T., Endocott, D. and Reionhold, J. (1987). Final Internal Report on Carbon Use Rate Data., U. S. EPA, Cincinnati, Ohio, USA
  23. Moritz, T., Benfer, S., Arki, P. and Tomandl, G. (2001), Influence of the surface charge on the permeate flux in the dead-end filtration with ceramic membranes. Separation and Purification Technology, 25(1-3), 501-508. https://doi.org/10.1016/S1383-5866(01)00080-6
  24. Ok, C. S., Kim, J. A. and Bae, K. C. (1992). The Adsorption Removal Characteristics of Trace Organic By-Products in Disinfection of Drinking Water by Biological Activated Carbon (BAC), J. KOR, KSEE, 14, 53-68.
  25. Shimizu, Y., Matsushta, K., Miura, I., Yazawa, T., Eguchi, K.(1988). Characterization of pore geometry of alumina membranes, J. JPN. Ceram. Soc., 96, pp. 556-560 https://doi.org/10.2109/jcersj.96.556
  26. Uhlhorn, R. J. R., Huis In't Veld, M.H.B.J., Keizer, K. and Burggraaf, A. J. (1992). Synthesis of Ceramic Membranes, Part I Synthesis of Non-supported and Supported ${\gamma}$ -Alumina Membranes without Defects, J. Mater. Sci., 27, 527-537. https://doi.org/10.1007/BF00543947
  27. White, M. C., Thompson, J. D., Harrington, G. W. and Singer, P. C.(1997). Evaluating criteria for enhanced coagulation compliance, J. AWWA, 89(5), 64-77. https://doi.org/10.1002/j.1551-8833.1997.tb08228.x

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