Corrosion Science and Technology

The Corrosion Science Society of Korea (한국부식방식학회)
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Use of Local Electrochemical Methods (SECM, EC-STM) and AFM to Differentiate Microstructural Effects (EBSD) on Very Pure Copper

  • Martinez-Lombardia, Esther (Vrije Universiteit Brussel, Research Group Electrochemical and Surface Engineering) ;
  • Lapeire, Linsey (Ghent University, Department of Materials Science and Engineering) ;
  • Maurice, Vincent (CNRS - Chimie ParisTech (UMR 8247), Institut de Recherche de Chimie Paris) ;
  • De Graeve, Iris (Vrije Universiteit Brussel, Research Group Electrochemical and Surface Engineering) ;
  • Klein, Lorena (CNRS - Chimie ParisTech (UMR 8247), Institut de Recherche de Chimie Paris) ;
  • Marcus, Philippe (CNRS - Chimie ParisTech (UMR 8247), Institut de Recherche de Chimie Paris) ;
  • Verbeken, Kim (Ghent University, Department of Materials Science and Engineering) ;
  • Kestens, Leo (Ghent University, Department of Materials Science and Engineering) ;
  • Gonzalez-Garcia, Yaiza (Delft University of Technology,Department of Materials Science and Engineering) ;
  • Mol, Arjan (Delft University of Technology,Department of Materials Science and Engineering) ;
  • Terryn, Herman (Vrije Universiteit Brussel, Research Group Electrochemical and Surface Engineering)
  • Received : 2016.09.21
  • Accepted : 2017.01.04
  • Published : 2017.02.28
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Abstract

When aiming for an increased and more sustainable use of metals a thorough knowledge of the corrosion phenomenon as function of the local metal microstructure is of crucial importance. In this work, we summarize the information presented in our previous publications[1-3] and present an overview of the different local (electrochemical) techniques that have been proven to be effective in studying the relation between different microstructural variables and their different electrochemical behavior. Atomic force microscopy (AFM)[1], scanning electrochemical microscopy (SECM)[2], and electrochemical scanning tunneling microscopy (EC-STM)[3] were used in combination with electron backscatter diffraction (EBSD). Consequently, correlations could be identified between the grain orientation and grain boundary characteristics, on the one hand, and the electrochemical behavior on the other hand. The grain orientation itself has an influence on the corrosion, and the orientation of the neighboring grains also seems to play a decisive role in the dissolution rate. With respect to intergranular corrosion, only coherent twin boundaries seem to be resistant.

Keywords

References

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