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Removal of microorganic pollutants based on reaction model of UV/chlorine process

자외선/염소 반응해석 모델에 의한 미량유기물질 제거에 관한 연구

  • Received : 2017.01.12
  • Accepted : 2017.02.08
  • Published : 2017.02.28

Abstract

The UV/chlorine process is a UV-based advanced oxidation process for removing various organic pollutants in water. The process is becoming increasingly popular because of its effectiveness in practice. It is important to the safe and efficient operation of a UV/chlorine process that the optimal operating conditions for both target removal objective and saving energy are determined. Treatment efficiency of target compounds in UV/chlorine process was mainly affected by pH and scavenging factor. In this study, kinetic based mathematical model considering water characteristics and electrical energy dose calculations model was developed to predict of treatment efficiency and optimal operating conditions. The model equation was validated for the UV/chlorine process at the laboratory scale and in pilot tests at water treatment plants.

Keywords

References

  1. Canonica, S., Meunier, L. and von Gunten, U. (2008) Phototransformation of selected pharmaceuticals during UV treatment of drinking water, Water Research, 42, 121-128. https://doi.org/10.1016/j.watres.2007.07.026
  2. Glaze, W. H., Kang, J. W. and Chapin, D. H. (1987) The chemistry of water treatment processes involving ozone, hydrogen peroxide and ultraviolet radiation, Ozone: Science Engineering, 9, 335-352. https://doi.org/10.1080/01919518708552148
  3. Kim, I., and Tanaka, H. (2009) Photodegradation characteristics of PPCPs in water with UV treatment, Environ. int., 35(5), 793-802. https://doi.org/10.1016/j.envint.2009.01.003
  4. Jung, Y. J. (2010) Treatment of emerging contaminants in water using ozone, UV, and UV/$H_2O_2$ combined processes considering its byproducts mitigation, Yonsei University.
  5. Mark, J. B., Benjamin D. S., Eric C. W. and Shane, A. S. (2009) Evaluation of a photocatalytic reactor membrane pilot system for the removal of pharmaceuticals and endocrine disrupting compounds from water, Water Research, 43, 1513-1522. https://doi.org/10.1016/j.watres.2008.12.049
  6. Rosenfeldt, E., Boal, A.K., Springer, J., Stanford, G., Rivera, S., Kashinkunti, R. D. and Metz, D. H. (2013) Comparison of UV-mediated Advanced Oxidation, Journal AWWA, July, 29-33.
  7. Yoon, Y., Ryu, J., Oh, J., Choi, B. G., and Snyder, S. A. (2010) Occurrence of endocrine disrupting compounds, pharmaceuticals, and personal care products in the Han River(Seoul, South Korea), Sci. Total Environ., 408(3), 636-643. https://doi.org/10.1016/j.scitotenv.2009.10.049
  8. Yuan, F., Hu, C., Hu, X. X., Qu, J. H. and Yang, M. (2009) Degradation of selected pharmaceuticals in aqueous solution with UV and UV/$H_2O_2$, Water Research, 43, 1766-1774. https://doi.org/10.1016/j.watres.2009.01.008
  9. Watts, M. J. and Linden, K. G. (2007) Chlorine photolysis and subsequent OH radical production during UV treatment of chlorinated water, Water Research, 41, 2871-2878. https://doi.org/10.1016/j.watres.2007.03.032
  10. Watts, M., Rosenfeldt, E., and Linden, K. G. (2007) Comparative OH Radical Oxidation Using UV-$Cl_2$ and UV-$H_2O_2$ Processes, Journal of Water Supply: Research and Technology-AQUA, 56(8), 469-477. https://doi.org/10.2166/aqua.2007.028
  11. Watts, M. J., Hofmann, R., and Rosenfeldt, E. (2012) Low-pressure UV/$Cl_2$ for advanced oxidation of taste and odor, Journal of American Water Works Association, 104(1), 58-65. https://doi.org/10.5942/jawwa.2012.104.0127
  12. Weinberg, H. S., Pereira, V. J., Linden, K. G. and Singer P. C. (2007) UV degradation kinetics and modeling of pharmaceutical compounds in laboratory grade and surface water via direct and indirect photolysis at 254 nm, Environmental Science and Technology, 41, 1682-1688. https://doi.org/10.1021/es061491b
  13. Shi, X., Dala N. S. and Jain, A. C. (1991) Antioxidant behaviour of caffeine: efficient scavenging of hydroxyl radicals, Food Chem Toxicol., 29(1), 1-6. https://doi.org/10.1016/0278-6915(91)90056-D

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