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Effect of Urea-Formaldehyde Resin Adhesive Viscosity on Plywood Adhesion

  • Hong, Min-Kug (Department of Wood and Paper Sciences, Kyungpook National University) ;
  • Park, Byung-Dae (Department of Wood and Paper Sciences, Kyungpook National University)
  • Received : 2017.03.01
  • Accepted : 2017.03.10
  • Published : 2017.03.25

Abstract

This work was conducted to investigate on the effect of urea-formaldehyde (UF) resin viscosity on plywood adhesion. The viscosity of UF resin was controlled either by adjusting the condensation reaction during its synthesis to obtain different target viscosities (100, 200 and 300 mPa.s) at two levels of formaldehyde/urea (F/U) mole ratios (1.0 and 1.2) or by adding different amounts (10, 20 and 30%) of wheat flour into the resins for the manufacture of plywood. When the viscosity of UF resin increased by the condensation reaction, the adhesion strength of plywood bonded with UF resin of 1.2 F/U mole ratio consistently increased, while those bonded with the 1.0 F/U mole ratio resin slightly decreased, suggesting a difference in the adhesion in plywood. However, the adhesion strength of plywood decreased as the viscosity increased by adding wheat flour, regardless of F/U mole ratio. The manipulation of UF resin viscosity by adjusting the condensation reaction was much more efficient than by adding wheat flour in improving the adhesion performance of plywood. These results indicated that a way of controlling the viscosity of UF resin adhesives has a great influence to their adhesion in plywood.

Keywords

References

  1. Derkyi, N.S., Darkwa, N.A., Yartey, J.G. 2008. Effect of cassava flour as urea formaldehyde adhesive extender on the bonding strength of plywood. Ghana Journal of Forestry 23(24): 25-34.
  2. Ding, R., Su, C., Yang, Y., Li, C., Liu, J. 2013. Effect of wheat flour on the viscosity of urea-formaldehyde adhesive. International Journal of Adhesion and Adhesives 41: 1-5. https://doi.org/10.1016/j.ijadhadh.2012.08.003
  3. Dunky, M. 1998. Urea-formaldehyde (UF) adhesive resins for wood. International Journal of Adhesion and Adhesives 18(2): 95-107. https://doi.org/10.1016/S0143-7496(97)00054-7
  4. Gavrilovic-Grmusa, I., Dunky, M., Miljkovic, J., Djiporovic-Momcilovic, M. 2010a. Radial penetration of urea-formaldehyde adhesive resins into beech (Fagus Moesiaca). Journal of Adhesion Science and Technology 24(8-10): 1753-1768. https://doi.org/10.1163/016942410X507812
  5. Gavrilovic-Grmusa, I., Miljkovic, J., Diporovic- Momcilovic, M. 2010b. Influence of the Degree of Condensation on the Radial Penetration of Urea-Formaldehyde Adhesives into Silver Fir (Abies alba, Mill.) Wood Tissue. Journal of Adhesion Science and Technology 24(8-10): 1437-1453. https://doi.org/10.1163/016942410X501034
  6. Gavrilovic-Grmusa, I., Dunky, M., Miljkovic, J., Djiporovic-Momcilovic, M. 2012. Influence of the viscosity of UF resins on the radial and tangential penetration into poplar wood and on the shear strength of adhesive joints. Holzforschung 66(7): 849-856. https://doi.org/10.1515/hf-2011-0177
  7. Gindl, W., Sretenovic, A., Vincenti, A., Muller, U. 2005. Direct measurement of strain distribution along a wood bond line. Part 2: Effects of adhesive penetration on strain distribution. Holzforschung 59(3): 307-310. https://doi.org/10.1515/HF.2005.051
  8. Hass, P., Wittel, FK., Mendoza, M., Herrmann, HJ., Niemz, P. 2012. Adhesive penetration in beech wood: experiments. Wood Science and Technology 46(1-3): 243-256. https://doi.org/10.1007/s00226-011-0410-6
  9. Modzel, G., Kamke, F.A., De Carlo, F. 2011. Comparative analysis of a wood: adhesive bondline. Wood Science and Technology 45(1): 147-158. https://doi.org/10.1007/s00226-010-0304-z
  10. Myers, G.E. 1984. How mole ratio of UF resin affects formaldehyde emission and other properties: a literature critique. Forest Products Journal 34(5): 35-41.
  11. Nuryawan, A., Park, B.D., Singh, A.P. 2014. Penetration of urea-formaldehyde resins with different formaldehyde/urea mole ratios into softwood tissues. Wood Science and Technology 48(5): 889-902. https://doi.org/10.1007/s00226-014-0649-9
  12. Nuryawan, A., Singh, A.P., Zanetti, M., Park, B.D., Causinc, V. 2017, Insights into the development of crystallinity in liquid urea-formaldehyde resins, International Journal of Adhesion and Adhesives 72: 62-69. https://doi.org/10.1016/j.ijadhadh.2016.10.004
  13. Osemeahon, S.A., Barminas, J.T. 2006. Properties of a low viscosity urea-formaldehyde resin prepared through a new synthetic Route. Bulletin of Pure and Applied Sciences-Chemistry 25(2): 67-67.
  14. Osemeahon, S.A., Barminas, J.T., Aliyu, BA. 2007. Effect of urea formaldehyde viscosity on some physical properties of a composite from reactive blending of urea formaldehyde with natural rubber. International Journal of Physical Sciences 2(9): 242-248.
  15. Park, B.D., Kang, E.C., Park, J.Y., 2006. Effects of formaldehyde to urea mole ratio on thermal curing behavior of urea-formaldehyde resin and properties of particleboard, Journal of Applied Polymer Science 101(3): 1787-1792. https://doi.org/10.1002/app.23538
  16. Park, B.D., Kim, J.W. 2008. Dynamic mechanical analysis of urea-formaldehyde resin adhesives with different formaldehyde-to-urea molar ratios. Journal of Applied Polymer Science 108(3): 2045-2051. https://doi.org/10.1002/app.27595
  17. Park, B.D., Jeong, H.W. 2011. Hydrolytic stability and crystallinity of cured urea-formaldehyde resin adhesives with different formaldehyde/urea mole ratios. International Journal of Adhesion and Adhesives 31(6): 524-529. https://doi.org/10.1016/j.ijadhadh.2011.05.001
  18. Pizzi, A., Mittal, K.L. 2003. Urea-formaldehyde adhesives. Handbook of Adhesive Technology pp: 635-652.
  19. Singh, A.P., Causin, V., Nuryawan, A., Park, B.D. 2014. Morphological, chemical and crystalline features of urea-formaldehyde resin cured in contact with wood. European Polymer Journal 56: 185-193. https://doi.org/10.1016/j.eurpolymj.2014.04.014
  20. Singh, AP., Nuryawan, A., Park, B.D., Lee, K.H. 2015. Urea-formaldehyde resin penetration into Pinus radiata tracheid walls assessed by TEM-EDXS. Holzforschung 69(3): 303-306.
  21. Xing, C., Riedl, B., Cloutier, A., Shaler, S.M. 2005. Characterization of urea-formaldehyde resin penetration into medium density fiberboard fibers. Wood Science and Technology 39(5): 374-384. https://doi.org/10.1007/s00226-005-0294-4

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