Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Adsorption of Pb(II) Ions from Aqueous Solution Using Activated Carbon Prepared from Areca Catechu Shell: Kinetic, Isotherm and Thermodynamic Studies

  • Muslim, A. (Process Technology Laboratory, Department of Chemical Engineering, Faculty of Engineering, Syiah Kuala University) ;
  • Aprilia, S. (Process Technology Laboratory, Department of Chemical Engineering, Faculty of Engineering, Syiah Kuala University) ;
  • Suha, T.A. (Process Technology Laboratory, Department of Chemical Engineering, Faculty of Engineering, Syiah Kuala University) ;
  • Fitri, Z. (Process Technology Laboratory, Department of Chemical Engineering, Faculty of Engineering, Syiah Kuala University)
  • Received : 2017.01.22
  • Accepted : 2017.04.14
  • Published : 2017.06.20
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Abstract

This study proposed adsorption of Pb(II) ions from aqueous solution using activated carbon prepared from areca catechu shell (ACS AC) using Timphan Method. The effects of independent variables on adsorption kinetic and isotherm have been investigated by conducting experiments in batch mode at neutral pH. The structural characterization of adsorbent was done by FT-IR and SEM analysis. The Pb(II) adsorption was correlated very well with the pseudo second-order kinetic (PSOKM) and Langmuir isotherm models (LIM). Increasing NaOH mass for activation and adsorption temperature increased weakly all the parameters of adsorption kinetic and isotherm. The Pb(II) ions adsorption capacity of the ACS AC at 27 and $45^{\circ}C$ was 50.51 and 55.25 mg/g, respectively. Thermodynamic parameters were determined, and the results confirmed the Pb(II) ions adsorption should be endothermic and spontaneous process, and both physical and chemical adsorption should be taken place.

Keywords

References

  1. Hawkes, S. J. J. Chem. Educ. 1997, 74, 1374. https://doi.org/10.1021/ed074p1374
  2. Srivastava, N. K.; Majumder, B. C. J. Hazard Mater. 2008, 151, 1. https://doi.org/10.1016/j.jhazmat.2007.09.101
  3. Bala, M.; Shehu, R. A.; Lawal, M. J. Pure Appl. Sci. 2008, 1, 6.
  4. Yan-Biao, G.; Hong, F.; Chong, C.; Chong-Jian, J.; Fan, X.; Ying, L. Pol. J. Environ. Stud. 2013, 22, 1357.
  5. Dimple, L. Int. J. Environ. Res. Dev. 2014, 4, 41.
  6. Munaf, E.; Takeuchi, T. In Hazardous Waste Control in Research and Education; T. Korenaga, T.; Tsukube, H.; Shinoda, S.; Nakamura, I. Eds.; C. R. C. Press: Boca Raton, F. L. 1994.
  7. Cohen, A. R.; Trotzky, M. S. Pediatrics. 1981, 67, 904.
  8. Grandjean, P. Environ. Res. 1978, 17, 303. https://doi.org/10.1016/0013-9351(78)90033-6
  9. Marino, P. E.; Landrigan, P. J.; Graef, J.; Nussbaum, A.; Bayan. G.; Boch, K.; Boch, S. Am. J. Public Health 1990, 80, 1183. https://doi.org/10.2105/AJPH.80.10.1183
  10. Levin, R.; Brown, M. J.; Kashtock, M. E. Environ. Health Perspect. 2008, 116, 1285. https://doi.org/10.1289/ehp.11241
  11. Nah, I. W.; Hwang, K. Y.; Jeon, C.; Choi, H. B. Miner. Eng. 2006, 19, 1452. https://doi.org/10.1016/j.mineng.2005.12.006
  12. Solenera, M.; Tunalib, S.; Ozcan, A. S.; Ozcanc, A.; Gedikbey, T. Desalination 2008, 223, 308. https://doi.org/10.1016/j.desal.2007.01.221
  13. Aklil, A.; Mouflihb, M.; Sebti, S. J. Hazard. Mater. 2004, A112, 183.
  14. Pan, B. C.; Zhang, Q. R.; Zhang, W. M.; Pana, B. J.; Dua, W.; Zhanga, Q. J.; Xua, Z. W.; Zhang, Q. X. J. Colloid Interface Sci. 2007, 310, 99. https://doi.org/10.1016/j.jcis.2007.01.064
  15. Fenga, D.; Aldrich, C. Hydrometallurgy. 2004, 73, 1. https://doi.org/10.1016/S0304-386X(03)00138-5
  16. Gupta, V. K.; Rastogi, A. Colloids Surf. B: Biointerfaces 2008, 64, 170. https://doi.org/10.1016/j.colsurfb.2008.01.019
  17. Ahluwalia, S. S.; Goyal, D. Bioresour. Technol. 2006, 98, 2243.
  18. Tarley, C. R. T.; Ferreira, S. L. C.; Arruda, M. A. Z. Microchem. J. 2004, 77, 163. https://doi.org/10.1016/j.microc.2004.02.019
  19. Wong, K. K.; Lee, C. K.; Low, K. S.; Haron, M. J. Chemosphere 2003, 50, 23. https://doi.org/10.1016/S0045-6535(02)00598-2
  20. Igwe, J. C.; Ogunewe, D. N.; Abia, A. A. Afr., J. Biotechnol. 2005, 4, 1113.
  21. Zein, R.; Suhaili, R.; Earnestly, F.; Idrawati, E. J. Hazard. Mater. 2011, 181, 52.
  22. Giraldo, L.; Moreno-Pirajan, J. C. Braz. J. Chem. Eng. 2008, 25, 143. https://doi.org/10.1590/S0104-66322008000100015
  23. Momcilovic, M.; Purenovic, M.; Bojic, A.; Zarubica, A.; Randelovic, M. Desalination 2011, 276, 53. https://doi.org/10.1016/j.desal.2011.03.013
  24. Giraldo-Gutierrez, L.; Moreno-Pirajan, J. C. J. Anal Appl. Pyrol. 2008, 81, 278. https://doi.org/10.1016/j.jaap.2007.12.007
  25. Sreejalekshmi, K. G.; Krishnan, K. A.; Anirudhan, T. S. J. Hazard. Mater. 2009, 161, 1506. https://doi.org/10.1016/j.jhazmat.2008.05.002
  26. Mouni, L.; Merabet, D.; Bouzaza, A.; Belkhiri, L. Desalination 2011, 276, 148. https://doi.org/10.1016/j.desal.2011.03.038
  27. Largitte, L.; Lodewyckx, P. J. Environ. Chem. Eng. 2014, 2, 788. https://doi.org/10.1016/j.jece.2014.02.001
  28. Tao, H. C.; Zhang, H. R.; Li, J. B.; Ding, W. Y. Bioresour. Technol. 2015, 192, 611. https://doi.org/10.1016/j.biortech.2015.06.006
  29. Bohli, T.; Ouederni, A.; Fiol, N.; Villaescusa, I. Comptes Rendus Chimie. 2015, 18, 88. https://doi.org/10.1016/j.crci.2014.05.009
  30. Muslim, A.; Zulfian; Ismayanda, H.; Devrina, E.; Fahmi, H. J. Eng. Sci. Technol. 2015, 10, 1654.
  31. Varmudy, V. Market Survey, 2012, Sept. 28.
  32. Muslim, A. J. Eng. Sci. Technol. 2017, 12, 1654.
  33. Nikolov, I.; Vitanova, I.; Najdenov, N.; Milusheva, T.; Vitanov, T. J. Appl. Electrochem. 1997, 27, 77. https://doi.org/10.1023/A:1026423100998
  34. Mohammad, I.; Al-Wabel; Al-Omran, A.; El-Naggar, H. A.; Nadeem, M.; Usman, A. R. A. Bioresour. Technol. 2013, 131, 374. https://doi.org/10.1016/j.biortech.2012.12.165
  35. Kurniawan, T. A. G.; Chan, Y. S.; Lo, W.; Babel, S. Sci. Total Environ. 2006, 366, 409. https://doi.org/10.1016/j.scitotenv.2005.10.001
  36. Yang, T.; Lua, A. J. Colloid Interface Sci. 2003, 267, 408. https://doi.org/10.1016/S0021-9797(03)00689-1
  37. Hesas, R. H.; Niya, A. A.; Daud, W. M. A. W.; Sahu, J. N. Bio Resources. 2013, 8, 2950.
  38. Figueiredo, J. L.; Pereira, M. F. R.; Freitas, M. M. A.; Qrfao, J. J. M. Carbon. 1999, 37, 1379. https://doi.org/10.1016/S0008-6223(98)00333-9
  39. Zengin, A.; Akalin, M. K.; Tekin, K.; Erdem, M.; Turga, T.; Karagoz, K. Ekoloji. 2012, 21, 123. https://doi.org/10.5053/ekoloji.2012.8514
  40. Sun, Y.; Yue, Q.; Gao, B.; Li, Q.; Huang, L.; Yao, F.; Xu, X. J. Colloid Interface Sci. 2012, 368, 521. https://doi.org/10.1016/j.jcis.2011.10.067
  41. Mengistie, A. A.; Siva, R. T.; Prasada, R. A. V.; Singanan, M. Bull. Chem. Soc. Ethiop. 2008, 22, 349.
  42. Chakravarty, P.; Sarma, N. S.; Sarma, H. P. Desalination 2010, 256, 16. https://doi.org/10.1016/j.desal.2010.02.029
  43. Lagergren, S. K. Sven. Vetensk. Akad. Handl. 1989, 24, 1.
  44. Ho, Y. S.; Wase, D. A. J.; Forster, C. F. Environ. Technol. 1996, 17, 71. https://doi.org/10.1080/09593331708616362
  45. Ahmad, R.; Kumar, R. J. Korean Chem. Soc. 2010, 54, 125. https://doi.org/10.5012/jkcs.2010.54.01.125
  46. Karagoz, S.; Tay, T.; Ucar, S.; Erdem, M. Bioresour. Technol. 2008, 99, 6214. https://doi.org/10.1016/j.biortech.2007.12.019
  47. Freundlich, H. J. Phys. Chem. 1960, 57, 384.
  48. Langmuir, I. J. Am. Chem. Soc. 1981, 40, 1361.
  49. Kobya, M.; Demirbas, E.; Senturk, E.; Ince, M. Bioresour. Technol. 2005, 96, 1518. https://doi.org/10.1016/j.biortech.2004.12.005
  50. Kikuchi, Y.; Qian, Q.; Machida, M.; Tatsumoto, H. Carbon 2006, 44, 195. https://doi.org/10.1016/j.carbon.2005.07.040
  51. Abdulkarim, M.; Al-Rub, F. A. Adsorp. Sci. Technol. 2004, 22, 119. https://doi.org/10.1260/026361704323150908
  52. Ricordel, S.; Taha, S.; Cisse, I.; Dorange, G. Sep. Purif. Technol. 2001, 24, 389. https://doi.org/10.1016/S1383-5866(01)00139-3
  53. Issabayeva, G.; Aroua, M. K.; Sulaiman, N. M. N. Bioresour. Technol. 2006, 97, 2350. https://doi.org/10.1016/j.biortech.2005.10.023
  54. Mohan, D.; Gupta, V. K.; Srivastava, S. K.; Chander, S. Colloids Surf. 2001, 177, 169. https://doi.org/10.1016/S0927-7757(00)00669-5
  55. Papirer, E. Adsorption on silica surfaces: Surfactant science series; Marcel Dekker, Inc.: New York, USA, 2000.
  56. Kumar, A.; Awasthi, A. Bioseparation engineering; I.K. International Publishing House, Pvt. Ltd.: New Dehli, India, 2009.
  57. Rao, S. R. Surface Chemistry of froth flotation: Fundamentals; Springer Science: New York, USA, 2004.
  58. Tan, I. A. W.; Ahmad, A. L.; Hameed, B.H. J. Hazard. Mater. 2009, 164, 473. https://doi.org/10.1016/j.jhazmat.2008.08.025

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