DOI QR코드

DOI QR Code

Contamination Assessment of Heavy Metals in River Sediments (For the Surface Sediments from Nakdong River)

하천 퇴적물 내 중금속 오염도 평가에 관한 연구 (낙동강 수계 표층 퇴적물을 대상으로)

  • Kim, Shin (Nakdong River Environment Research Center, National Institute of Environmental Research) ;
  • Ahn, Jungmin (Nakdong River Environment Research Center, National Institute of Environmental Research) ;
  • Jung, Kangyoung (Nakdong River Environment Research Center, National Institute of Environmental Research) ;
  • Lee, Kwonchul (Nakdong River Environment Research Center, National Institute of Environmental Research) ;
  • Kwon, Heongak (Nakdong River Environment Research Center, National Institute of Environmental Research) ;
  • Shin, Dongseok (Nakdong River Environment Research Center, National Institute of Environmental Research) ;
  • Yang, Deukseok (Nakdong River Environment Research Center, National Institute of Environmental Research)
  • 김신 (국립환경과학원 낙동강 물환경 연구소) ;
  • 안정민 (국립환경과학원 낙동강 물환경 연구소) ;
  • 정강영 (국립환경과학원 낙동강 물환경 연구소) ;
  • 이권철 (국립환경과학원 낙동강 물환경 연구소) ;
  • 권헌각 (국립환경과학원 낙동강 물환경 연구소) ;
  • 신동석 (국립환경과학원 낙동강 물환경 연구소) ;
  • 양득석 (국립환경과학원 낙동강 물환경 연구소)
  • Received : 2017.03.08
  • Accepted : 2017.07.18
  • Published : 2017.07.30

Abstract

In order to certificate the contamination assessment of heavy metals in surface sediments from the Nakdong river. Surface sediments were collected of 24 sampling sites (main 14st., tributary 10st.) and analyzed for grain size heavy metals contents. Study area mainly composed of sand (avg. 94.1%) and mean grain size was $1.46{\Phi}$ on average. Heavy metals contents (avg. Al: 12.5%, Zn; 74.4, Cr: 45.3, Li: 26.0, Pb: 17.1, Ni: 10.5, Cu: 7.8, Cd: 0.22 mg/kg) were relatively high contents in the composed of fine sediments. In addition, the results of pearson's correlation coefficient showed that most heavy metals and grain size (silt and clay) were highly correlated. The contents of Zn (6st.) and Ni (1st.) evaluated as moderately polluted, Zn (6st.) evaluated as LEL when compared with sediment quality standard of USEPA and Ontario sediment quality guidelines. Most heavy metals contents were I levels that dose not affected the benthos when compared with sediment pollution evaluation standard of NIER. The results of EX, EF, Igeo and CF showed the contents of Zn, Pb and Cd exceed the background contents and distributing of anthropogenic pollution and evaluated as moderately polluted level. And Nm-08 were relatively high level of contamination in the study area. However as results of PLI (less than 1), all sampling sites were evaluated unpolluted level.

Keywords

References

  1. Ahn, J. M., Im, T. H., Lee, I. J., Lee K. L., Jung, K. Y., Lee, J. W., Cheon, S. U., and Park, I. H. (2014). A Study on Efficiency of Water Supply through Conjunctive Operation of Reservoirs and Multi-function Weir in the Nakdong River, Journal of Korean Society on Water Environmental, 30(2), 138-147. [Korean Literature] https://doi.org/10.15681/KSWE.2014.30.2.138
  2. Alloway, B. J., Thornton, I., Smart, G. A., Sherlock, J. C., and Quinn, M. J. (1988). Metal Availability, Science of the Total Environment, 75, 41-69. https://doi.org/10.1016/0048-9697(88)90159-3
  3. Bruland, K. W., Bertine, K., Koide, M. and Golberg, E. D. (1974). History of metal pollution in southern California coastal zone, Environmental Science and Technology, 8, 425-432. https://doi.org/10.1021/es60090a010
  4. Brugmann, L., Bernard, P. C., and Grieken, R. (1992). Geochemistry of Suspended matter from the Baltic sea 2, Results of Bulk Trace Metal Analysis by AAS, Marine Chemistry, 38(3-4), 303-323. https://doi.org/10.1016/0304-4203(92)90039-D
  5. Canadian Council of Ministers of the Environmental Protection. (1995). Protocol for the Derivation of Canadian Sediment Quality Guidelines for the Protection of Aquatic Life, Report CCME, EPA-98E, 1-8.
  6. Choi, J. Y., Choi, H. Y., and Seo, M. S. (1995). Physical and Sedimentological Changes in the Keum River Weir, Journal of the Korean Society of Oceanography, 30(4), 262-270. [Korean Literature]
  7. Folk, R. L. and Ward, W. C. (1957). Brazos River Bar: a Study in the Significance of Grain size Parameter, Journal of Sedimentary Petrology, 27(1), 3-27. https://doi.org/10.1306/74D70646-2B21-11D7-8648000102C1865D
  8. Hokanson, L. (1980). Ecological Risk Index for Aquatic Pollution Control. a Sedimentological Approach, Water Research, 14, 975-1001. https://doi.org/10.1016/0043-1354(80)90143-8
  9. Hong, D. I., and Kim, S. K. (1996). Characteristic Behavior of Toxic Pollutants in Sediments of Kumho River, Journal of Nakdong Enviromental Research Institute, 1(1), 171-182. [Korean Literature]
  10. Horowitz, A. J. (1991). A primer on Sediment-Trace Element Chemistry, Lewis publish, Chelsea, 1-136.
  11. Hyun, S., Lee, C. H., Lee, T., and Choi, J. W. (2007). Anthropogenic Contributions to Heavy metal Distributions in the Surface Sediments of Masan Bay, Korea, Marine Pollution Bulletin, 54(7), 1030-1071.
  12. Hwang, D. W., Ryu, S. O., Kim, S. G., Choi, O. I., Kim, S., and Koh, B. S. (2010). Geochemical Characteristics of Intertidal Surface Sediments along the Southwestern Coast of Korea, Journal of Fisheries and Aquatic Sciences, 43(2), 146-158. [Korean Literature] https://doi.org/10.5657/kfas.2010.43.2.146
  13. Jeong, H. R., Ra, G. T., Kim, K. T., Kim, E. S., Lee, S. Y., Choi, J. Y., and Kim, K. R. (2016). Evaluation of the Distributions and Status of Heavy metal Pollution in Stream Sediments of the Sooyoung River Basin in Busan, Proceeding of the 2016 Spring Co-Conference of the Korean Society for Marine Environment & Energy, Korean Society for Marine Environment & Energy, 205-211. [Korean Literature]
  14. Kim, J. G., and Jang, H. S. (2014). Evaluation of Characteristics of Particle Composition and Pollution of Heavy Metals for Bottom Sediments in Cheonsu Bay, Korea. - Comparison of the Sediments Environment of Farming Area and Non-farming Area, Journal of the Korean Society of Marine Environment & Safety, 20(4), 358-371. [Korean Literature] https://doi.org/10.7837/kosomes.2014.20.4.358
  15. Kim, J. Y., Eun, G. Y. N., Koh, Y. K., Youn, S. T., Oh, K. H., and Kim D. J. (2001). Sedimentary Environments and Geochemical Characters of the Core Sediments Near Naju-Yeongam Area in the Lower Part of the Yeongsan River, Cheonnam, Korea, Journal of Korea Earth Science Society, 22(4), 301-316. [Korean Literature]
  16. Kim, D. H., and Um, H. H. (2013). Estimation of the Sediment Pollution in Coast of Gwangyang, Mokpo and Shinan, Korea, Journal of the Korean Society of Marine Environment & Safety, 19(4), 303-308. [Korean Literature] https://doi.org/10.7837/kosomes.2013.19.4.303
  17. Kim, S.. Y., Kim, H. C., Lee, W. C., Hwang, D. W., Hong, S. J., Kim, J. B., Cho, Y. S., and Kim, C. S. (2013). Environmental Characteristics of Seawater and Sediment in Mariculture Management Area in Ongjin-gun, Korea, Journal of the Korean Society if Marine Environment & Safety, 19(6), 570-581. [Korean Literature] https://doi.org/10.7837/kosomes.2013.19.6.570
  18. Kim, S., Kim, J. E., Lee, K. C., Lee, G. Y., Jeon, H. R., Yu, J. J., Lee, I. J., and Ahn, J. M. (2015). Distribution and Pollution of Heavy metals in Surface Sediments from Nakdong River, Journal of Environmental Science International, 24(7), 841-849. [Korean Literature] https://doi.org/10.5322/JESI.2015.24.7.841
  19. Lee, J. K., and Lee, T. Y. (2009), Evaluation of Sediments Qualities for the Urban Stream in the Busan City, Proceeding of the 2009 Co-Conference of the Korean Geo-environmental Society, Korean Geo-environmental Society, 285-291. [Korean Literature]
  20. Lee, J. K., Kim, S. K., Song, J. H., and Lee, T. Y. (2010), Evaluation of Organic Compounds and heavy Metals in Sediments from the Urban Stream in the Busan City, Journal of Korean Geo-Environmental Society, 11(1), 35-43. [Korean Literature]
  21. Lee, K. Y., Kim, J. E., Lee, G. K., Lee, K. L., Lee, I. J., and Im, T. H. (2013). Characteristics of Changes in DOC Concentration according to Concentrations of Organic Matter and Suspended Solids in the Nakdong River, Journal of Korean Society on Water Environmental, 29(4), 540-550. [Korean Literature]
  22. Lee, M. K., Bae, W., Um, I. K., and Jung, H. S. (2004). Characteristics of Heavy Metal Distribution in Sediments of Youngil Bay, Korea, Journal Korean Society of Environmental Engineers, 26(5), 71-83. [Korean Literature]
  23. Mason, B. and Moore, C. B. (1982). Principles of Geochemistry, John Wiley & Sons Inc, Newyork, 389.
  24. Miall, A. D. (1977). A Review of the Braided River Depositional Environment. Earth Science Review, 13(1), 1-62. https://doi.org/10.1016/0012-8252(77)90055-1
  25. Ministry of Land, Infrastructure and Transport (MOLIT). (2009). River Maintence Master Plan in the Nakdong River, Ministry of Land, Infrastructure and Transport. [Koeran Literature].
  26. Ministry of Environment (MOE). (2012). Official Test Methods of Water Quality, Notification No. 2012-99, Ministry of Enivironment, 1-333. [Korean Literature].
  27. Muller, G., 1979, Schwermetalle in den sediments des Rheins Veranderungen seit 1971, Umschan, 79, 778-783.
  28. National Institute of Environmental Research (NIER). (2012). River and Lake Sediment Contamination Evaluation Guide line, Ministry of Enivironment, National Institude of Environmental Research, published rulings, 2014-575, National Institute of Environmental Research. [Korean Literature]
  29. National Institute of Environmental Research (NIER). (2015). Sediment Pollution Evaluation Standard of River and Lake, published rulings 687, National Institute of Environmental Research. [Korean Literature]
  30. Oh, H. S., Shin, W. S., Kim, J. H., Hwang, I. S., Hur. J., Shin, H. S., Oh, J. E., Huh, I. A., and Kim, Y. H. (2010). Comparison of Particle Size Analysis and Distribution of Heavy metals in River and Lake Sediments, Journal of Korean Geo-Environmental Society, 11(5), 15-23. [Korean Literature]
  31. Oh, K. H., Kim, J. Y., Koh, Y. K., Youn, S. T., Shin, S. E., Park, B. Y., Moon, B. C., and Kim, H. G. (2003). Geochemical Characteristics and Contamination of Surface Sediments in Stream of Gwangju City, Journal of the Korean Earth science society, 24(4), 346-360. [Korean Literature]
  32. Paulson, A. J., Curl, H. C., and Feely, R. A. (1993). The Biogeochemistry of Nutrients and Trace Metals in Hood Canal, a Puget Sound Fjord, Marine Chemistry, 43(1-4), 157-173. https://doi.org/10.1016/0304-4203(93)90222-A
  33. Pekey, H., Karakas, D., Ayberk, S., Tolun, L., and Bakoglu, M. (2004). Ecological Risk Assessment using Trace Elements from Surface Sediments of Izmit Bay (Northeastern Marmara Sea) Turkey, Marine Pollution Bulletin, 48(9), 946-953. https://doi.org/10.1016/j.marpolbul.2003.11.023
  34. Savvides, C., Papadopoulos, A., Haralambous, K. J., and Loizidou, M. (1995). Sea Sediments Contaminated with Heavy metals: Metal Speciation and Removal, Water Science & Technology, 32(9-10), 65-73. https://doi.org/10.1016/0273-1223(96)00077-7
  35. Sekabira, K., Oryem Origa, H., Basamba, T. A., Mutumba, G., and Kakudidi. E. (2010). Assessment of Heavy metal Pollution in the Urban Stream Sediments and its Tributaries, International Hournal of Environmental Science & Technology, 7(3), 435-446. https://doi.org/10.1007/BF03326153
  36. Shin, S. E., Youn, S. T., Koh, Y. G., and Oh, K. H. (2015). The Geochemical Characteristics and Environmental Changes of Surface Sediment in Yeongsan River Area, Journal of The Korean Geomorphological Association, 22(3), 31-42. [Korean Literature]
  37. Thornton, I. (1983). Applied Environmental Geochemistry, Academic Press, London, 501.
  38. Tomlinson, D. L., Wilson, J. G., Harris, C. R., and Jeffrey, D. W. (1980). Problems in the Assessment of Heavy metals in Estuaries and the Formation Pollution Index, Helgoland Marine Research, 3(1-4), 566-575.
  39. United States Environmental Protection Agency (U. S. EPA). (1999). Protocol for Developing Sediment TMDLs, EPA 841-B-99-004, United States Environmental Protection Agency.
  40. Woo, H. Y., Lim, J. H., Lee, J. K., Lee, J. H., Ham, K. S., and Lee, T. Y. (2013). Characterization and Estimation of Heavy Metal Contents of Tongyong Marine Products Breeding Ground Sediments, Journal of Korea Society of Waste Management, 30(3), 213-219. [Korean Literature] https://doi.org/10.9786/kswm.2013.30.3.213
  41. You, H. S., Cho, S. H., and Koh, Y. K. (2000). Fluvial Deposits Distributed along the Seomjin River, Journal of the Korean Earth Science Society, 21(2), 174-189. [Korean Literature]
  42. Zhang, J. H., and Liu, C. L. (2002). Riverine Composition and Estuarine Geochemistry of Particle metals in China-weathering features, Anthropogenic Impact and Chemical Fluxes, Estuarine Coast Shelf Science, 54(6), 1051-1070. https://doi.org/10.1006/ecss.2001.0879