Resources Recycling (자원리싸이클링)

The Korean Institute of Resources Recycling (한국자원리싸이클링학회)
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A Study on Pretreatment and Acid Leaching for Wet Recycling of Waste Industrial Ni-Cd Secondary Battery

산업용 니켈-카드뮴 폐 이차전지 습식 재활용을 위한 전처리 및 산 침출에 대한 연구

  • Received : 2017.08.16
  • Accepted : 2017.10.13
  • Published : 2017.10.31
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Abstract

In order to efficiently recycle waste industrial nickel-cadmium batteries, anodic and cathodic materials were crushed by a cut mill and classified by sieves. We used wet magnetic separation method for eliminating iron components from the crushed powders. In addition, the acid leaching test for the obtained anode and cathode powders was carried out under various conditions by means of the wet process. At the optimum leaching conditions with 2.0 M $H_2SO_4$ at $90^{\circ}C$, 15 wt $H_2O_2$ and L/S=20 for 3 hours, the leaching efficiency of nickel and cadmium was 99%, respectively.

산업용 폐 니켈-카드뮴 전지를 효율적으로 재활용하기 위하여 케이스에서 분리된 양극 및 음극 스크랩을 cut mill로 분쇄하여 분급하였으며, 철 성분 제거를 위하여 습식 자력선별법을 이용하였다. 또한 얻어진 양극 및 음극 분말을 습식법을 이용하기 위하여 다양한 조건에서의 산 침출 실험을 실시하였다. 최적 침출조건으로 2.0 M $H_2SO_4$, 반응온도 $90^{\circ}C$, 15 wt% $H_2O_2$, L/S=20의 조건에서 3시간 침출을 하여 유가금속인 니켈 및 카드뮴의 침출율을 99% 이상 얻을 수 있었다.

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References

  1. J. S. Park et al., 1999 : Recovery of nickel from the spent nickel-cadmium battery, J. of Korean Inst. of Resources Recycling, 8(5), pp28-33.
  2. J. H. Kim and K. Y. Nam, 2000 : Recovery and separation of nickel from the spent Ni-Cd batteries, J. of Korean Inst. of Resources Recycling, 9(2), pp11-17.
  3. C. Pons et al., 1997 : Development of a hydrometallurgical process for the recycling of metals from nickel-cadmium batteries and other similar wastes, The Recycling of Metals-Third ASM Intern. Conf. and Exhibition, Barcelona, Spain, June, pp489.
  4. C. C. Yang, 2003 : Recovery of heavy metals from spent Ni-Cd batteries by a potentiostatic electrodeposition technique, Journal of Power Sources 115, pp352-359. https://doi.org/10.1016/S0378-7753(03)00015-6
  5. M. B. J. G. Freitas and S. F. Rosalem, 2005 : Electrochemical recovery of cadmium from spent Ni-Cd batteries, Journal of Power Sources 139, pp366-370. https://doi.org/10.1016/j.jpowsour.2004.06.074
  6. E. Rudnik and M. Nikiel, 2007 : Hydrometallurgical recovery of cadmium and nickel from spent Ni-Cd batteries, Hydrometallurgy 89, pp61-71. https://doi.org/10.1016/j.hydromet.2007.05.006
  7. C. A. Nogueira and F. Margarido, 2007 : Chemical and physical characterization of electrode materials of spent sealed Ni-Cd batteries, Waste Management 27, pp1570-1579. https://doi.org/10.1016/j.wasman.2006.10.007
  8. C. A. Nogueira and F. Margarido, 2004 : Leaching behaviour of electrode materials of spent nickel-cadmium batteries in sulphuric acid media, Hydrometallurgy 72, pp111-118. https://doi.org/10.1016/S0304-386X(03)00123-3
  9. B. Ramachandra Reddy and D. Neela Priya, 2006 : Chloride leaching and solvent extraction of cadmium, cobalt and nickel from spent nickel-cadmium, batteries using Cyanex 923 and 272, Journal of Power Sources 161, pp1428-1434. https://doi.org/10.1016/j.jpowsour.2006.05.044