Journal of Industrial and Engineering Chemistry

  • Volume 54
  • /
  • Pages.447-453
  • /
  • 2017
  • /
  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
권호 표지
DOI QR코드

DOI QR Code

In-situ catalytic pyrolysis of lignin in a bench-scale fixed bed pyrolyzer

  • Shafaghat, Hoda (School of Environmental Engineering, University of Seoul) ;
  • Rezaei, Pouya Sirous (School of Environmental Engineering, University of Seoul) ;
  • Ro, Donghoon (School of Environmental Engineering, University of Seoul) ;
  • Jae, Jungho (Clean Energy Research Center, Korea Institute of Science and Technology) ;
  • Kim, Beom-Sik (School of Environmental Engineering, University of Seoul) ;
  • Jung, Sang-Chul (Department of Environmental Engineering, Sunchon National University) ;
  • Sung, Bong Hyun (Bioenergy & Biochemical Research Center, Korea Research Institute of Bioscience & Biotechnology) ;
  • Park, Young-Kwon (School of Environmental Engineering, University of Seoul)
  • Received : 2017.03.06
  • Accepted : 2017.06.17
  • Published : 2017.10.25
⟨ Previous Next ⟩

Abstract

Thermal and in-situ catalytic pyrolysis of lignin were carried out in a bench-scale pyrolyzer. The yield and composition of the bio-oil produced were influenced largely by the type of lignin samples, pyrolysis temperature, and nitrogen carrier gas flow rate. The highest bio-oil yield of 35.95 wt.% was achieved using kraft lignin at $500^{\circ}C$ and a carrier gas flow rate of 600 ml/min. In-situ catalytic pyrolysis resulted in a decrease of the bio-oil yield, but the aromatic product distribution was altered greatly depending on the types of catalysts. In-situ catalytic pyrolysis also showed enhanced selectivity to valuable aromatic hydrocarbons.

Keywords

Acknowledgement

Supported by : Korea Institute of Energy Technology Evaluation and Planning (KETEP), National Research Council of Science & Technology (NST)

Cited by

  1. Catalytic in Situ Hydrogenolysis of Lignin in Supercritical Ethanol: Effect of Phenol, Catalysts, and Reaction Temperature vol.6, pp.5, 2018, https://doi.org/10.1021/acssuschemeng.8b00701
  2. Microwave Assisted Depolymerization of Alkaline Lignin over Hydrotalcite-Based CuNiAl Mixed Oxides vol.6, pp.9, 2017, https://doi.org/10.1021/acssuschemeng.8b01697
  3. Mild hydrodeoxygenation of phenolic lignin model compounds over a FeReOx/ZrO2 catalyst: zirconia and rhenium oxide as efficient dehydration promoters vol.20, pp.7, 2017, https://doi.org/10.1039/c7gc03823b
  4. Catalytic fast pyrolysis of pressure-sensitive adhesives wastes using Py-GC/MS vol.40, pp.6, 2017, https://doi.org/10.1080/15567036.2018.1440331
  5. Stabilization of bio-oil over a low cost dolomite catalyst vol.35, pp.4, 2017, https://doi.org/10.1007/s11814-018-0002-3
  6. Catalytic Pyrolysis of Waste Paper Cup Containing Coffee Residuals vol.29, pp.2, 2017, https://doi.org/10.14478/ace.2018.1004
  7. Review of the use of activated biochar for energy and environmental applications vol.26, pp.None, 2017, https://doi.org/10.5714/cl.2018.26.001
  8. The Effect of Biomass Torrefaction on the Catalytic Pyrolysis of Korean Cork Oak vol.29, pp.3, 2018, https://doi.org/10.14478/ace.2018.1050
  9. Pyrolysis of Waste Oriental Medicine Byproduct Obtained from the Decoction Process of Achyranthes Root vol.29, pp.4, 2017, https://doi.org/10.14478/ace.2018.1068
  10. Adsorptive removal of odour substances and NO and catalytic esterification using empty fruit bunch derived biochar vol.28, pp.None, 2017, https://doi.org/10.5714/cl.2018.28.081
  11. Catalytic Pyrolysis of Polyethylene and Polypropylene over Desilicated Beta and Al-MSU-F vol.8, pp.11, 2017, https://doi.org/10.3390/catal8110501
  12. Catalytic Co-Pyrolysis of Kraft Lignin with Refuse-Derived Fuels Using Ni-Loaded ZSM-5 Type Catalysts vol.8, pp.11, 2018, https://doi.org/10.3390/catal8110506
  13. Surface Engineering of CoMoS Nanosulfide for Hydrodeoxygenation of Lignin-Derived Phenols to Arenes vol.9, pp.1, 2017, https://doi.org/10.1021/acscatal.8b03402
  14. Acetaldehyde removal and increased H2/CO gas yield from biomass gasification over metal-loaded Kraft lignin char catalyst vol.232, pp.None, 2019, https://doi.org/10.1016/j.jenvman.2018.11.054
  15. Renewable jet-fuel range hydrocarbons production from co-pyrolysis of lignin and soapstock with the activated carbon catalyst vol.88, pp.None, 2017, https://doi.org/10.1016/j.wasman.2019.03.030
  16. The effect of Kankara zeolite-Y-based catalyst on some physical properties of liquid fuel from mixed waste plastics (MWPs) pyrolysis vol.77, pp.3, 2017, https://doi.org/10.1007/s00289-019-02806-y
  17. Co‐pyrolysis characteristics of polysaccharides‐cellulose and the co‐pyrolyzed compound distributions over two kinds of zeolite catalysts vol.44, pp.8, 2017, https://doi.org/10.1002/er.5360
  18. Upgrading crude bio-oil by in situ and ex situ catalytic pyrolysis through ZSM-5, Ni2Fe3, and Ni2Fe3/ZSM-5: Yield, component, and quantum mechanism vol.12, pp.5, 2017, https://doi.org/10.1063/5.0009689
  19. Effects of metal promoters in bimetallic catalysts in hydrogenolysis of lignin derivatives into value‐added chemicals vol.12, pp.21, 2017, https://doi.org/10.1002/cctc.202001124
  20. Production of Aromatic Hydrocarbons from Biomass vol.61, pp.1, 2021, https://doi.org/10.1134/s0965544121010023
  21. Stabilization of acid-rich bio-oil by catalytic mild hydrotreating vol.272, pp.None, 2021, https://doi.org/10.1016/j.envpol.2020.116180
  22. High-Yield Production of Deoxygenated Monomers from Kraft Lignin over ZnO-Co/N-CNTs in Water vol.9, pp.8, 2021, https://doi.org/10.1021/acssuschemeng.0c08664
  23. Effect of Temperature on the Pilot-Scale Catalytic Pyrolysis of Loblolly Pine vol.35, pp.16, 2017, https://doi.org/10.1021/acs.energyfuels.1c01685
  24. A critical review on metal-based catalysts used in the pyrolysis of lignocellulosic biomass materials vol.299, pp.None, 2017, https://doi.org/10.1016/j.jenvman.2021.113597
  25. Development of metal-doping mesoporous biochar catalyst for co-valorizing biomass and plastic waste into valuable hydrocarbons, syngas, and carbons vol.227, pp.None, 2017, https://doi.org/10.1016/j.fuproc.2021.107127