Korean Journal of Chemical Engineering

The Korean Institute of Chemical Engineers (한국화학공학회)
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The effects of mineral salt catalysts on selectivity of phenolic compounds in bio-oil during microwave pyrolysis of peanut shell

  • Mamaeva, Alisa (Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering, University of Science and Technology Liaoning) ;
  • Tahmasebi, Arash (Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering, University of Science and Technology Liaoning) ;
  • Yu, Jianglong (Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering, University of Science and Technology Liaoning)
  • Received : 2016.05.08
  • Accepted : 2016.10.15
  • Published : 2017.03.01
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Abstract

Catalytic microwave pyrolysis of peanut shell (PT) using $Fe_3O_4$, $Na_2CO_3$, NaOH, and KOH for production of phenolic-rich bio-oil was investigated. The effects of catalyst type, pyrolysis temperature, and biomass/catalyst ratio on product distribution and composition were studied. Among four catalysts tested, $Na_2CO_3$ significantly increased the selectivity of phenolic compounds in bio-oil during microwave pyrolysis. The highest phenolics concentration of 57.36% (area) was obtained at $500^{\circ}C$ and $PT:Na_2CO_3$ ratio of 8 : 1. The catalytic effect to produce phenolic compounds among all the catalysts tested can be summarized in the order $Na_2CO_3$>$Fe_3O_4$>KOH>NaOH. Using KOH and NaOH as catalyst resulted in formation of bio-oil with enhanced higher heating value (HHV) and lower oxygen content, indicating that these catalysts enhanced the deoxygenation of bio-oil. The scanning-electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS) analysis of char particles showed the melting of magnetite and vaporization-condensation of mineral salt catalysts on char particle, which was attributed to extremely high local temperatures during microwave heating.

Keywords

Acknowledgement

Supported by : National Natural Science Foundation of China

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