Journal of the Semiconductor & Display Technology (반도체디스플레이기술학회지)

The Korean Society Of Semiconductor & Display Technology (한국반도체디스플레이기술학회)
권호 표지

Selective Graphene Oxide Reduction Utilizing Photon Energy

광에너지를 활용한 선택적 산화그래핀의 환원

  • Shin, Jae-Soo (Department of Advanced Materials Engineering, Daejeon University) ;
  • Choi, Eunmi (Center for Materials and Energy Measurement, Korea Research Institute of Standards and Science)
  • 신재수 (대전대학교 신소재공학과) ;
  • 최은미 (한국표준과학연구원 소재에너지융합측정센터)
  • Received : 2018.10.31
  • Accepted : 2018.12.20
  • Published : 2018.12.31
Download PDF
⟨ Previous Next ⟩

Abstract

Graphene is attracting attention due to its outstanding properties as line material for next-generation semiconductor. Graphene pattern technology is essential to apply graphene line. Selective graphene oxide reduction as one of graphene pattern method does not require a substrate thereby a high flexibility device can be applied. Particularly, the method using photon energy has advantages of short process time and environment friendly. In this review, we introduce the photocatalytic method and the photo-thermal energy conversion method using photon energy in the selective reduction process of graphene oxides.

Keywords

References

  1. Lee, J, H., "A Study of Dynamic Properties of Graphene-Nanoribbon Memory," Journal of the Semiconductor & Display Technology, Vol. 13, pp. 53-56, 2014.
  2. Di, Bartolomeo, A., "Graphene Schottky diodes: An experimental review of the rectifying graphene/semiconductor heterojunction," Physics Reports, Vol. 606, pp. 1-58, 2016. https://doi.org/10.1016/j.physrep.2015.10.003
  3. Murali, R., Yang, Y., Brenner, K., Beck, T., and Meindl, J, D., "Breakdown current density of graphene nanoribbons," Applied Physics Letters, Vol. 94(24), pp. 243114, 2009. https://doi.org/10.1063/1.3147183
  4. Cheng, R., Bai, J., Liao, L., Zhou, H., Chen, Y., Liu, L., and et al., "High-frequency self-aligned graphene transistors with transferred gate stacks," Proceedings of the National Academy of Sciences, Vol. 109(29), pp. 11588-92. 2012. https://doi.org/10.1073/pnas.1205696109
  5. Feng, Z., Yu, C., Li, J., Liu, Q., He, Z., Song, X., and et al., "An ultra clean self-aligned process for high maximum oscillation frequency graphene transistors," Carbon, Vol. 75, pp. 249-54, 2014. https://doi.org/10.1016/j.carbon.2014.03.060
  6. Yoo, J, H., Park, J, B., Ahn, S., and Grigoropoulos, C, P., "Laser-Induced Direct Graphene Patterning and Simultaneous Transferring Method for Graphene Sensor Platform," Small, Vol. 9(24), pp. 4269-75, 2013. https://doi.org/10.1002/smll.201300990
  7. Kumar, P., Subrahmanyam, K., and Rao, C., "Graphene patterning and lithography employing laser/electron-beam reduced graphene oxide and hydrogenated graphene," Materials Express, Vol. 1(3), pp. 252-6, 2011. https://doi.org/10.1166/mex.2011.1024
  8. Yong, K., Ashraf, A., Kang, P., and Nam, S., "Rapid stencil mask fabrication enabled one-step polymer-free graphene patterning and direct transfer for flexible graphene devices," Scientific reports, Vol. 6, pp. 24890, 2016. https://doi.org/10.1038/srep24890
  9. Bell, D, C., Lemme, M, C., Stern, L, A., Williams, J, R., and Marcus, C, M., "Precision cutting and patterning of graphene with helium ions," Nanotechnology, Vol. 20(45), pp. 455301, 2009. https://doi.org/10.1088/0957-4484/20/45/455301
  10. Cabrero-Vilatela, A., Weatherup, R, S., Braeuninger-Weimer, P., Caneva, S., and Hofmann , S., "Towards a general growth model for graphene CVD on transition metal catalysts," Nanoscale, Vol. 8(4), pp. 2149-58, 2016. https://doi.org/10.1039/C5NR06873H
  11. Bower, W., Head, W., Droop, G., Zan, R., Pattrick, R., Wincott, P., and et al., "High-resolution imaging of biotite using focal series exit wavefunction restoration and the graphene mechanical exfoliation method," Mineralogical Magazine, Vol. 79(2), pp. 337-44, 2015. https://doi.org/10.1180/minmag.2015.079.2.11
  12. Novotny, Z., Netzer, F, P., and Dohnalek, Z., "Cerium Oxide Nanoclusters on Graphene/Ru (0001): Intercalation of Oxygen via Spillover," ACS Nano, Vol. 9(8), pp. 8617-26, 2015. https://doi.org/10.1021/acsnano.5b03987
  13. Choi, E., Chae, S, J., Kim, A., Kang, K, W., Oh, M, S., Kwon, S, H., and et al., "Hybrid Electrodes of Carbon Nanotube and Reduced Graphene Oxide for Energy Storage Applications," Journal of nanoscience and nanotechnology, Vol. 15(11), pp. 9104-9, 2015. https://doi.org/10.1166/jnn.2015.11573
  14. Choi, E., Kim, J., Chae, S, J., Kim, A., Pyo, S, G., and Yoon, S., "Performance of Graphene-Based Anode Using Chemically Reduced Nanocomposite Formation," Science of Advanced Materials, Vol. 7(12), pp. 2755-9, 2015. https://doi.org/10.1166/sam.2015.2603
  15. Qi, Z, J., Rodriguez-Manzo, J, A., Hong, S, J., Park, Y, W., Stach, E, A., Drndic, M., and et al. editors., "Direct electron beam patterning of sub-5nm monolayer graphene interconnects," SPIE Advanced Lithography, Vol. 8680, pp. 86802F 1-6, 2013.
  16. Tung, V, C., Allen, M, J., Yang, Y., and Kaner, R, B., "High-throughput solution processing of large-scale graphene," Nature Nanotechnology, Vol. 4(1), pp. 25-9, 2009. https://doi.org/10.1038/nnano.2008.329
  17. Zhou, M., Wang, Y., Zhai, Y., Zhai, J., Ren, W., Wang, F., and et al., "Controlled synthesis of large-area and patterned electrochemically reduced graphene oxide films," Chemistry-A European Journal, Vol. 15(25), pp. 6116-20, 2009. https://doi.org/10.1002/chem.200900596
  18. Fan, W., Lai, Q., Zhang, Q., and Wang, Y., "Nanocomposites of TiO2 and reduced graphene oxide as efficient photocatalysts for hydrogen evolution," The Journal of Physical Chemistry C, Vol. 115(21), pp. 10694-701, 2011. https://doi.org/10.1021/jp2008804
  19. Kawahara, T., Konishi, Y., Tada, H., Tohge, N., Nishii, J., and Ito, S., "A Patterned TiO2 (Anatase)/TiO2 (Rutile) Bilayer-Type Photocatalyst: Effect of the Anatase/Rutile Junction on the Photocatalytic Activity," Angewandte Chemie, Vol. 114(15), pp. 2935-7, 2002. https://doi.org/10.1002/1521-3757(20020802)114:15<2935::AID-ANGE2935>3.0.CO;2-6
  20. Wang, P., Wang, J., Ming, T., Wang, X., Yu, H., Yu, J., and et al., "Dye-sensitization-induced visible-light reduction of graphene oxide for the enhanced TiO2 photocatalytic performance," ACS Applied Materials & Interfaces, Vol. 5(8), pp. 2924-9, 2013. https://doi.org/10.1021/am4008566
  21. Radich, J, G., Krenselewski, A, L., Zhu, J., and Kamat, P, V., "Is graphene a stable platform for photocatalysis? Mineralization of reduced graphene oxide with UV-irradiated TiO2 nanoparticles," Chemistry of Materials, Vol. 26(15), pp. 4662-8, 2014. https://doi.org/10.1021/cm5026552
  22. Williams, G., Seger, B., and Kamat, PV., "TiO2-graphene nanocomposites. UV-assisted photocatalytic reduction of graphene oxide," ACS Nano, Vol. 2(7), pp. 1487-91, 2008. https://doi.org/10.1021/nn800251f
  23. Karampelas, I, H., Furlani, E, P., and editors., "Analysis of Pulsed-laser Plasmon-enhanced Photothermal Energy Transfer with Applications," The 16th Annual Graduate Student Research Symposium, 2013.
  24. Hosokawa, Y., Yashiro, M., Asahi, T., and Masuhara, H., "Photothermal conversion dynamics in femtosecond and picosecond discrete laser etching of Cuphthalocyanine amorphous film analysed by ultrafast UV-VIS absorption spectroscopy," Journal of Photochemistry and Photobiology A: Chemistry, Vol. 142(2), pp. 197-207, 2001. https://doi.org/10.1016/S1010-6030(01)00514-7
  25. Cote, L, J., Cruz-Silva, R., and Huang, J., "Flash reduction and patterning of graphite oxide and its polymer composite," Journal of the American Chemical Society, Vol. 131(31), pp. 11027-32, 2009. https://doi.org/10.1021/ja902348k
  26. Zhou, Y., Bao, Q., Varghese, B., Tang, L, A, L., Tan, C, K., Sow, C, H., and et al., "Microstructuring of graphene oxide nanosheets using direct laser writing," Advanced Materials, Vol. 22(1), pp. 67-71, 2010. https://doi.org/10.1002/adma.200901942
  27. Guo, H., Peng, M., Zhu, Z., and Sun, L., "Preparation of reduced graphene oxide by infrared irradiation induced photothermal reduction," Nanoscale, Vol. 5(19), pp. 9040-8, 2013. https://doi.org/10.1039/c3nr02805d
  28. Al-Hamry, A., Kang, H., Sowade, E., Dzhagan, V., Rodriguez, R., Muller, C., and et al., "Tuning the reduction and conductivity of solution-processed graphene oxide by intense pulsed light," Carbon, Vol. 102, pp. 236-44, 2016. https://doi.org/10.1016/j.carbon.2016.02.045