Journal of Korean Society of Water Science and Technology (한국수처리학회지)

Korean Society of Water Science and Technology (한국수처리학회)
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Use of Hybrid Bead, Tannin and Chitosan, for Treatment of Pb(II) from Aqueous Solution

타닌과 키토산 하이브리드 비드를 이용한 수용액의 Pb(II) 제거

  • Yu, Sungwhan (Department of Health and Environment, Catholic Kwandong University) ;
  • Choi, Hee-Jeong (Department of Health and Environment, Catholic Kwandong University)
  • 유성환 (가톨릭 관동대학교 보건환경학과) ;
  • 최희정 (가톨릭 관동대학교 보건환경학과)
  • Received : 2018.03.09
  • Accepted : 2018.04.08
  • Published : 2018.04.30
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Abstract

In this study, hybrid beads were prepared using tannin and chitosan. Batch experiments were carried out to remove Pb(II) from aqueous solution using hybrid bead. According to the FT-IR analysis, the hybrid beads had carboxylic, carbonyl groups, carboxylic acids, and bonded-OH groups, which made it very easy to adsorb heavy metals. The adsorption of Pb(II) using hybrid beads was suitable for pseudo-second-order and Langmuir isotherms. The maximum adsorption capacity of Langmuir was 123.19 mg/g of Pb(II). The adsorption strength of Pb(II) to the hybrid bead was high and showed the isothermal adsorption characteristics of L type. In the thermodynamic experiment, ${\Delta}G^o$ shows a negative value, and ${\Delta}H^o$ and ${\Delta}S^o$ show a positive value. It can be seen that the adsorption process of Pb(II) using hybrid bead is a spontaneous endothermic reaction and the affinity between adsorbent and adsorbate is very good. Hybrid beads can efficiently adsorb and remove Pb(II) as an inexpensive and environmentally friendly adsorbent.

Keywords

Acknowledgement

Supported by : 한국연구재단

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