Korean Journal of Chemical Engineering

The Korean Institute of Chemical Engineers (한국화학공학회)
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Improved dielectric properties and energy density of PVDF composites using PVP engineered BaTiO3 nanoparticles

  • Dai, Yu (School of Energy Science and Engineering, Central South University) ;
  • Zhu, Xiaojun (School of Energy Science and Engineering, Central South University)
  • Received : 2017.10.16
  • Accepted : 2018.03.15
  • Published : 2018.07.01
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Abstract

his work systematically investigates the effect of modifier polyvinylpyrrolidone (PVP) on the microstructure, dielectric and energy storage properties of $BaTiO_3/PVDF$ composites. The results demonstrate that the $BaTiO_3$ nanoparticles modified by PVP are uniformly dispersed in the composites, and the defects including cracks and voids are obviously decreased in contrast to the composites with unmodified $BaTiO_3$ nanoparticles. Due to the enhanced interfacial polarization, the composites with $BaTiO_3@PVP$ show improved dielectric properties compared with the composites with unmodified $BaTiO_3$ nanoparticles. For instance, at 1 kHz, the dielectric constant and dielectric loss of the composite with 50 vol% of $BaTiO_3@PVP$ nanoparticles are 80.4 and 0.085, while of which the $BaTiO_3/PVDF$ are 35 and 0.265, respectively. The discharge energy density of the composites is largely improved with PVP engineered $BaTiO_3$ nanoparticles. The composite with 30 vol% $BaTiO_3@PVP$ achieves a discharged energy density of 4.06 J/cc at 240 kV/mm, which is 116% larger than that of pure PVDF (1.88 J/cc). This research provides an effect modifier to prepare high performance dielectric materials.

Keywords

Acknowledgement

Supported by : Hunan Provincial Education Department

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