Journal of Industrial and Engineering Chemistry

  • Volume 63
  • /
  • Pages.95-102
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  • 2018
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  • 1226-086X(pISSN)
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  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Porous PEDOT-SiO2 hybrid conductive micro particles prepared by simultaneous co-vaporized vapor phase polymerization

  • Jung, Seul Gi (Division of Advanced Materials Engineering, Kongju National University) ;
  • Cho, Kuk Young (Department of Materials Science and Chemical Engineering, Hanyang University) ;
  • Yim, Jin-Heong (Division of Advanced Materials Engineering, Kongju National University)
  • Received : 2017.12.21
  • Accepted : 2018.02.01
  • Published : 2018.07.31
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Abstract

Porous $PEDOT-SiO_2$ particles were successfully prepared using simultaneous co-vaporized vapor phase polymerization (SC-VPP). By controlling the TEOS content, the morphologies of the obtained particles could be tuned from appearance of hollow egg shells aggregates to the hybrid particle composed of microspheres. Despite only having up to 40% of TEOS in the SC-VPP process, $SiO_2$ accounts for over 90% of the resulting hybrid particle, because the hydrolysis/condensation reactions of TEOS would be much faster as compared with the PEDOT polymerization. The specific capacitance of a single hybrid particle decreased with increasing $SiO_2$ portion, owing to changes in its external/internal structures.

Keywords

Acknowledgement

Supported by : National Research Foundation of Korea (NRF)

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