Journal of the Korea institute for structural maintenance and inspection (한국구조물진단유지관리공학회 논문집)

Korea Institute for Structural Maintenance Inspection (한국구조물진단유지관리공학회)
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A Study on the Cementitious Materials as Carbon Capture Materials-Micro-Structure Change by Carbonation Curing

시멘트계 재료의 탄소포집 건설재료로 활용연구 - 탄산화 양생에 의한 미세구조 변화

  • 문은진 (한국건설생활환경시험연구원) ;
  • 김상준 (가천대학교 토목환경공학과) ;
  • 박홍기 (가천대학교 토목환경공학과) ;
  • 최영철 (가천대학교 토목환경공학과)
  • Received : 2018.09.05
  • Accepted : 2018.10.11
  • Published : 2018.11.01
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Abstract

Recently, there has been a growing interest in the study of treatment of $CO_2$ generated by industrial activities and resource recycling of industrial byproducts. The aim of this study is to investigate the applicability of industrial byproducts that can be used as concrete mixed materials by carbonation curing. For this purpose, the physical and chemical changes of the pastes with research cement(RC), blast furnace slag powder (GGBFS) and circulating fluidized bed combustion ashes (CFBC) were evaluated by carbonation curing. XRD and SEM analyzes were performed to investigate micro-structural changes. As a result, it was confirmed that calcium carbonate, which is a reaction product produced by carbonation curing, filled the space inside the paste and formed a dense micro-structure. Also, as the $CO_2$ curing time increased, it was confirmed that calcium carbonate crystals were grown together to form a dense micro-structure.

최근 산업 활동에 의해 발생하는 $CO_2$에 대한 처리와 산업부산물에 대한 유효처리 및 자원화 방안이 시급히 요구되고 있다. 본 연구는 콘크리트 혼합재료로 활용이 가능한 산업부산물를 대상으로 탄산화 양생에 의한 건설재료로의 적용성 평가를 목적으로 한다. 이러한 목적을 위해 연구용 시멘트(research cement, RC), 고로슬래그 미분말(GGBFS) 및 유동층 보일러 애시(CFBC)를 대상으로 탄산화 양생에 의한 물리 화학적 변화를 비교 검토하였다. 페이스트 내부의 미세조직 변화를 살펴보기 위해 XRD, SEM 분석을 수행하였다. 실험결과 탄산화 양생을 통해 생성된 반응 생성물인 탄산칼슘은 페이스트 내부의 공간을 채우며 밀도가 높은 미세 구조를 형성함을 확인하였다. 또한, $CO_2$ 양생시간이 길어짐에 따라 탄산칼슘 결정이 함께 성장하여 밀실한 미세구조를 이루는 것을 확인하였다.

Keywords

References

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