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Development of Geochemical Tracers to Identify a Specific Source Region of Mineral Dust in China and Preliminary Test of Their Applicability

중국 기원 광물성 먼지 입자의 지화학 추적자 개발 및 기초 적용연구

  • Lee, Sojung (Global Ocean Research Center, Korea Institute of Ocean Science and Technology) ;
  • Hyeong, Kiseong (Global Ocean Research Center, Korea Institute of Ocean Science and Technology) ;
  • Kim, Wonnyon (Deep-sea Mineral Resources Research Center, Korea Institute of Ocean Science and Technology) ;
  • Kim, Tae-Hoon (Department of Earth and Marine Sciences, College of Ocean Sciences, Jeju National University)
  • 이소정 (한국해양과학기술원 대양자원연구센터) ;
  • 형기성 (한국해양과학기술원 대양자원연구센터) ;
  • 김원년 (한국해양과학기술원 심해저광물자원연구센터) ;
  • 김태훈 (제주대학교 해양과학대학 지구해양과학과)
  • Received : 2019.07.25
  • Accepted : 2019.09.10
  • Published : 2019.09.30

Abstract

The purpose of this study is to develop geochemical tracers to identify a specific source desert of mineral dust in China using the published data. In addition, we tested the applicability of these tracers to wet-deposits and soil samples collected in Jeju, Korea. Because of similarity in trace elemental compositions of mineral dust from the major arid regions in China, such as Taklimakan, West Ordos (Badain Jaran), East Ordos (Mu Us and Hobq), East Northern China (Horqin), West Northern China (Gurbantunggut), and Chinese Loess Plateau, there has been limited to the use of geochemical data for source identification. Here we propose the four (4) plots using combination of seven (7) geochemical variables as a source indicator to distinguish one from other source regions in China: $\frac{Y}{Tb_N}$ vs. $\frac{Th}{{\Sigma}REE_N}$, $\(\frac{La}{Gd}\)_N$ vs. $\frac{Y}{{\Sigma}REE_N}$, $\frac{Th}{Tb_N}$ vs. $\frac{Y}{Nd_N}$, and $\frac{Th}{Tb_N}$ vs. $\(\frac{Ce}{Ce}\)_N^*$, where $_N$ and $\(\frac{Ce}{Ce}\)_N^*$ stand for values normalized to Post-Archean Average Shale composition and Ce anomaly, respectively. Mineral dusts from aforementioned six major deserts are distinguished one from the others by the combined use of these variables. Jeju rock and soil samples form a separate domain from Chinese mineral dusts in all four plots. In contrast, most of Jeju dust samples were comparable with the West Ordos desert (Badain Jaran) domain, indicative of strong influence of Badain Jaran dust in Jeju in spring season when the mineral dust was collected. A weak positive Ce anomaly in Jeju samples implies minimal local contribution. Our study suggests that the combination of $\frac{Y}{Tb_N}$ vs. $\frac{Th}{{\Sigma}REE_N}$, $\(\frac{La}{Gd}\)_N$ vs. $\frac{Y}{{\Sigma}REE_N}$, $\frac{Th}{Tb_N}$ vs. $\frac{Y}{Nd_N}$, and $\frac{Th}{Tb_N}$ vs. $\(\frac{Ce}{Ce}\)_N^*$ can be used to identify a specific source region of mineral dust in China as well as Jeju mineral particles.

Keywords

References

  1. Koh JS, Yun SH, Kang SS (2003) Petrology of the volcanic rocks in the Paekrogdam crater area, Mt. Halla, Jeju Island. J Petrolog Soc Kor 12(1):1-15
  2. Koh JS, Yun SH, Jeong EJ (2007) Petrology of the basalt in the Seongsan-Ilchulbong area, Jeju Island. J Korean Earth Sci Soc 28(3):324-342 https://doi.org/10.5467/JKESS.2007.28.3.324
  3. Kwon YI, Shin JB, Yu KM (2003) Scanning cathodoluminescence characteristics of the surface quartz grains of Ordos and Alashan deserts, China: eolian quartz provenance and fingerprint. J Geol Soc Kor 39(4):423-430
  4. Kwon YI, Lee SG, Kim KH, Shin JB, Yu KM (2004a) Geochemical characteristics of the surface sediments from the middle-to-eastern Taklimakan desert, China. J Geol Soc Kor 40(4):383-393
  5. Kwon YI, Lee SG, Yu KM, Shin JB, Kim KH (2004b) Geochemical characteristics of the surface sediments of Ordos and Alashan deserts, China: eolian sediment provenance and fingerprint. J Geol Soc Kor 40(2):119-132
  6. Kim D, Kim J, Ban S (2010) A study on the characteristics of soil in the Asian dust source regions of Mongolia. J Korean Soc Atmos Environ 26(6):606-615 https://doi.org/10.5572/KOSAE.2010.26.6.606
  7. Kim YS, Choi SH (2012) Plagioclase-rich nodules in Taeheungri basalt from Namwon, Jeju Island and its implications for tholeiite magmatism. J Geol Soc Kor 48(4):313-324
  8. Park ME, Cho JH, Kim S, Lee SS, Kim JE, Lee HC, Cha JW, Ryoo SB (2016) Case study of the heavy Asian dust observed in Late February 2015. Atmosphere 26(2):257-275 https://doi.org/10.14191/Atmos.2016.26.2.257
  9. Park SM, Moon KJ, Park JS, Kim HJ, Ahn JY, Kim JS (2012) Chemical characteristics of ambient aerosol during Asian dusts and high PM episodes at Seoul intensive monitoring site in 2009. J Korean Soc Atmos Environ 28(3):282-293 https://doi.org/10.5572/KOSAE.2012.28.3.282
  10. Park JB, Kwon ST (1996) Tholeiitic volcanism in Cheju Island, Korea. J Petrolog Soc Kor 5(1):66-83
  11. Park JS, Han JS, Ahn JY (2013) The research trend of Asian dust storm(AD) of Korea and recent episode analysis. J Korean Soc Atmos Environ 29(5):553-573 https://doi.org/10.5572/KOSAE.2013.29.5.553
  12. Shin SA, Han JS, Hong YD, Ahn JY, Moon KJ, Lee SJ, Kim SD (2005) Chemical composition and features of Asian dust observed in Korea (2000-2002). J Korean Soc Atmos Environ 21(1):119-129
  13. Lee SG, Youm SJ (2008) Geochemical Implication of Rare earth element from Yellow sand (Asian Dust) at Daejeon area, Korea : a preliminaty study for clarifying source area of Yellow sand. J Petrolog Soc Kor 17(1):44-50
  14. Chang KH, Park JB, Kwon ST (2006) Geochemical characteristics of trachytes in Jeju Island. J Geol Soc Kor 42(2):235-252
  15. Aries S, Valladon M, Polve M, Dupre B (2000) A routine method for oxide and hydroxide interference corrections in ICP-MS chemical analysis of environmental and geological samples. Geostandard Newslett 24(1):19-31 https://doi.org/10.1111/j.1751-908X.2000.tb00583.x
  16. Blank M, Leinen M, Prospero JM (1985) Major Asian aeolian inputs indicated by the mineralogy of aerosols and sediments in the western North Pacific. Nature 314(6006):84-86 https://doi.org/10.1038/314084a0
  17. Chen J, Li G, Yang J, Rao W, Lu H, Balsam W, Sun Y, Ji J (2007) Nd and Sr isotopic characteristics of Chinese deserts: implications for the provenances of Asian dust. Geochim Cosmochim Ac 71(15):3904-3914 https://doi.org/10.1016/j.gca.2007.04.033
  18. Eguchi K, Uno I, Yumimoto K, Takemura T, Shimizu A, Sugimoto N, Liu Z (2009) Trans-pacific dust transport: integrated analysis of NASA/CALIPSO and a global aerosol transport model. Atmos Chem Phys 9:3137-3145 https://doi.org/10.5194/acp-9-3137-2009
  19. Feng JL, Hu ZG, Ju JT, Zhu LP (2011) Variations in trace element (including rare earth element) concentrations with grain sizes in loess and their implications for tracing the provenance of eolian deposits. Quatern Int 236(1-2):116-126 https://doi.org/10.1016/j.quaint.2010.04.024
  20. Ferrat M, Weiss DJ, Strekopytov S, Dong S, Chen H, Najorka J, Sun Y, Gupta S, Tada R, Sinha R (2011) Improved provenance tracing of Asian dust sources using rare earth elements and selected trace elements for palaeomonsoon studies on the eastern Tibetan Plateau. Geochim Cosmochim Ac 75(21):6374-6399 https://doi.org/10.1016/j.gca.2011.08.025
  21. Grousset FE, Biscaye PE (2005) Tracing dust sources and transport patterns using Sr, Nd and Pb isotopes. Chem Geol 222(3-4):149-167 https://doi.org/10.1016/j.chemgeo.2005.05.006
  22. Honda M, Yabuki S, Shimizu H (2004) Geochemical and isotopic studies of aeolian sediments in China. Sedimentology 51(2):211-230 https://doi.org/10.1111/j.1365-3091.2004.00618.x
  23. Hu F, Yang X (2016) Geochemical and geomorphological evidence for the provenance of aeolian deposits in the Badain Jaran Desert, northwestern China. Quaternary Sci Rev 131:179-192 https://doi.org/10.1016/j.quascirev.2015.10.039
  24. Jeong GY (2008) Bulk and single-particle mineralogy of Asian dust and a comparison with its source soils. J Geophys Res-Atmos 113(2):1-16 https://doi.org/10.1029/2007JD008606
  25. Kanakidou M, Seinfeld JH, Pandis SN, Barnes I, Dentener FJ, Facchini MC, van Dingenen R, Ervens B, Nenes A, Nielsen CJ, Swietlicki E, Putaud JP, Balkanski Y, Fuzzi S, Horth J, Moortgat GK, Winterhalter R, Myhre CEL, Tsigaridis K, Vignati E, Stephanou EG, Wilson J (2005) Organic aerosol and global climate modelling: a review. Atmos Chem Phys 5(4):1053-1123 https://doi.org/10.5194/acp-5-1053-2005
  26. Kim J (2008) Transport routes and source regions of Asian dust observed in Korea during the past 40 years (1965-2004). Atmos Environ 42(19):4778-4789 https://doi.org/10.1016/j.atmosenv.2008.01.040
  27. Kim W, Doh SJ, Yu Y, Lee M (2008) Role of Chinese wind-blown dust in enhancing environmental pollution in Metropolitan Seoul. Environ Pollut 153(2):333-341 https://doi.org/10.1016/j.envpol.2007.08.014
  28. Kumar A, Sarin MM (2010) Atmospheric water-soluble constituents in fine and coarse mode aerosols from high-altitude site in western India: long-range transport and seasonal variability. Atmos Environ 44(10):1245-1254 https://doi.org/10.1016/j.atmosenv.2009.12.035
  29. Lee MK, Lee Y, Yi H (2010) Provenances of atmospheric dust over Korea from Sr-Nd isotopes and rare earth elements in early 2006. Atmos Environ 44(20):2401-2414 https://doi.org/10.1016/j.atmosenv.2010.04.010
  30. Lee MK, Lee SH, Lee YI, Yoon HI, Yoo KC (2014) Rare earth element composition of paleo-maar sediments (latest Pleistocene-Early Holocene), Jeju Island, Korea: implications for Asian dust record and monsoon climate. Quatern Int 344:32-42 https://doi.org/10.1016/j.quaint.2014.05.036
  31. Lee PK, Youm SJ, Jo HY (2013) Heavy metal concentrations and contamination levels from Asian dust and identification of sources: a case-study. Chemosphere 91(7):1018-1025 https://doi.org/10.1016/j.chemosphere.2013.01.074
  32. Lee PK, Yu S (2016) Lead isotopes combined with a sequential extraction procedure for source apportionment in the dry deposition of Asian dust and non-Asian dust. Environ Pollut 210:65-75 https://doi.org/10.1016/j.envpol.2015.12.010
  33. Maher BA, Prospero JM, Mackie D, Gaiero D, Hesse PP, Balkanski Y (2010) Global connections between aeolian dust, climate and ocean biogeochemistry at the present day and at the last glacial maximum. Earth-Sci Rev 99(1-2):61-97 https://doi.org/10.1016/j.earscirev.2009.12.001
  34. McLennan SM (1989) Rare earth elements in sedimentary rocks: influence of provenance and sedimentary processes. In: Bruce R, Lipin GA (eds) Geochemistry and mineralogy of rare earth elements. Mineralogical Society of America, NewYork, pp 169-200
  35. Nagashima KR, Tada A, Tani Y, Sun Y, Isozaki S, Toyoda S, Hasegawa H (2011) Millennial-scale oscillations of the westerly jet path during the last glacial period. J Asian Earth Sci 40:1214-1220 https://doi.org/10.1016/j.jseaes.2010.08.010
  36. Rao W, Tan H, Jiang S, Chen J (2011) Trace element and REE geochemistry of fine- and coarse-grained sands in the Ordos deserts and links with sediments in surrounding areas. Geochemistry 71(2):155-170 https://doi.org/10.1016/j.chemer.2011.02.003
  37. Seo I, Lee Y, Yoo CM, Kim HJ, Hyeong K (2014) Sr-Nd isotope composition and clay mineral assemblages in eolian dust from the central Philippine Sea over the last 500 kyr: Implications for the transport mechanism of Asian dust. J Geophys Res-Atmos 119:11492-11504 https://doi.org/10.1002/2014JD022025
  38. Sun Y, Tada R, Chen J, Chen H, Toyoda S, Tani A, Isozaki Y, Nagashima K, Hasegawa H, Ji J (2007) Distinguishing the sources of Asian dust based on electron spin resonance signal intensity and crystallinity of quartz. Atmos Environ 41(38):8537-8548 https://doi.org/10.1016/j.atmosenv.2007.07.014
  39. Taylor SR, McLennan SM (1981) The composition and evolution of the continental crust - Rare earth element evidence from sedimentary rocks. Philos T Roy Soc A 301(1461):381-399 https://doi.org/10.1098/rsta.1981.0119
  40. Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell Scientific Publications, Oxford, 312 p
  41. Tegen I, Lacis AA, Fung I (1996) The influence on climate forcing of mineral aerosols from disturbed soils. Nature 380(6573):419-422 https://doi.org/10.1038/380419a0
  42. Uno I, Amano H, Emori S, Kinoshita K, Matsui I, Sugimoto N (2001) Trans-Pacific yellow sand transport observed in April 1998: a numerical simulation. J Geophys Res-Atmos 106:18331-18344 https://doi.org/10.1029/2000JD900748
  43. Uno I, Eguchi K, Yumimoto K, Takemura T, Shimizu A, Uematsu M, Liu Z, Wang Z, Hara Y, Sugimoto N (2009) Asian dust transported one full circuit around the globe. Nat Geosci 2(8):557-560 https://doi.org/10.1038/ngeo583
  44. Yang X, Zhu B, White PD (2007a) Provenance of aeolian sediment in the Taklamakan Desert of western China, inferred from REE and major-elemental data. Quatern Int 175(1):71-85 https://doi.org/10.1016/j.quaint.2007.03.005
  45. Yang X, Liu Y, Li C, Song Y, Zhu H, Jin X (2007b) Rare earth elements of aeolian deposits in Northern China and their implications for determining the provenance of dust storms in Beijing. Geomorphology 87(4):365-377 https://doi.org/10.1016/j.geomorph.2006.10.004
  46. Zhang W, Zhao J, Chen J, Ji J, Liu L (2018) Binary sources of Chinese loess as revealed by trace and REE element ratios. J Asian Earth Sci 166:80-88 https://doi.org/10.1016/j.jseaes.2018.07.017