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Comparison of Residue Patterns for Systemic and Non-systemic Pesticides in Strawberry

딸기 중 침투성 및 비침투성 농약에 따른 잔류특성 연구

  • You, Jung-Sun (Department of Food & Pharmaceutical Engineering, College of Life & Health Sciences, Graduate School of Hoseo University) ;
  • Gwak, Hye-Min (Department of Food & Pharmaceutical Engineering, College of Life & Health Sciences, Graduate School of Hoseo University) ;
  • Chang, Hee-Ra (Department of Food & Pharmaceutical Engineering, College of Life & Health Sciences, Graduate School of Hoseo University)
  • 유정선 (호서대학교 생명보건대학 식품제약공학부) ;
  • 곽혜민 (호서대학교 생명보건대학 식품제약공학부) ;
  • 장희라 (호서대학교 생명보건대학 식품제약공학부)
  • Received : 2020.10.05
  • Accepted : 2020.10.30
  • Published : 2020.12.31

Abstract

BACKGROUND: The healthy food trend has encouraged the consumption of natural products, including berries. This trend is expected to increase the strawberry consumption. There has been a concern about the exposure of pesticides approved for use on strawberry. In this study, the dissipation patterns of systemic and non-systemic pesticides were evaluated in strawberry under plastic-covered greenhouse conditions. METHODS AND RESULTS: Cyflumetofen and dimethomorph were applied on strawberry in the critical GAP (Good Agricultural Practices). Strawberries were harvested at 0, 1, 2, 3, 5, 7 and 10 days after final application of the pesticides. The analyses of the residual pesticides were performed by HPLC-DAD with C18 column. The limits of quantitation (LOQ) of cyflumetofen and dimethomorph were 0.04 and 0.02 mg/kg, respectively. The recovery of cyflumetofen and dimethomorph were 88.1 ~ 103.3% and 79.0 ~ 110.2% for the spiked two levels (LOQ and 10LOQ), respectively. The biological half-lives of cyflumetofen and dimethomorph werer 7.5 and 8.9 days, respectively. The dissipation rates in strawberry were calculated by the statistics method at a 95% confidence level. The distribution showed that pesticides with low log Pow were indicated by the decreased dissipation rate and pesticides with similar log Pow and low solubility also showed the decreased dissipation rate. CONCLUSION: The residues of cyflumetofen and dimethomorph in strawberry at time 0 after the final application were below the established MRL in Korea. The dissipation behavior of systemic and non-systemic pesticides in strawberry is affected by their log Pow and water solubility values.

Keywords

References

  1. Ayala-Zavala JF, Wang SY, Wang CY, Conzalez-Aguilar GA (2004) Effect of storage temperatures on antioxidant capacity and aroma compounds in strawberry fruit. LWT-Food Science and Technology, 37(7), 687-695. https://doi.org/10.1016/j.lwt.2004.03.002.
  2. Cho JI, Ha SD, Kim KS (2004) Inhibitory effects of temperature, pH, and potassium sorbate against natural microflora in strawberry paste during storage. Korean Society of Food Science and Technology, 36(2), 355-360.
  3. Park KH, Kim SH (2011) A comparative study of consumer preference for strawberries in Korea and Singapore. Korean Journal of Agricultural Management and Policy, 38(2), 321-340.
  4. Nam MH, Jeon YN, Lee HC, Lee HD, Kang HK (2012) Comparative analysis between healthy and powdery mildew-infected plants of strawberry cultivar Seolhyang. The Korean Society of Plant Pathology, 18(2), 80-85. https://doi.doi.org/10.5423/RPD.2012.18.2.080.
  5. Lee HS, Hong SM, Kwon HY, Kim DB, Moon BC (2017) Comparison of residue patterns between foliar application and drenching in export strawbeerry. Journal of Applied Biological Chemistry, 60(4), 313-319. https://doi.org/10.3839/jabc.2017.049.
  6. Ryu KY, Kim JP, Park DK, Lee DV, Song NJ, Cho BS, Seo KW, Kim SH (2020) A statistical analysis of pesticide residues on leafy vegetables selling at agricultural wholesale markets in Gwangju. The Korean Journal of Pesticide Science, 24(1), 91-104. https://doi.org/10.7585/kjps.2020.24.1.91.
  7. Hayashi N, Sasama Y, Takahashi N, Lkemi N (2012) Cyflumetofen, a novel acaricide - its mode of action and selectivity. Pest Management Science, 69(9), 1080-1084. https://doi.org.10.1002/ps.3470.
  8. Lee DY, Kim YJ, Kim SG, Kang KY (2013) Residual characteristics of insecticides used for oriental tobacco budworm control of paprika. Korean Journal of Environmental Agriculture, 32(1), 84-93. https://doi.org/10.5338/KJEA.2013.32.1.84.
  9. Park JS, Yang SH, Choi H (2017) Residue patterns and biological half-lives of pyridalyl and fluopicolide in watermelon. Korean Journal of Environmental Agriculture, 36(1), 50-56. https://doi.org/10.5338/KJEA.2017.36.1.08.
  10. Jeong HR, Noh HH, Lee JY, Park HK, Jin MJ, Kim JC, Hong SM, Kyung KS (2017) Residual characteristics and safety assessments of bifenthrin, carbendazim and metconazole in angelica gigas Nakai. The Korean Journal of Pesticide Science, 21(1), 97-105. https://doi.org/10.7585/kjps.2017.21.1.97.
  11. Kim YJ, Kim JG, Kwon YS, Song JW, Seo JS (2017) Residual characteristics and monitoring of cyenopyrafen and cyflumetofen in strawberries for export. Korean Journal of Environmental Agriculture, 36(4), 279-287. https://doi.org/10.5338/KJEA.2017.36.4.35.
  12. Liu Congyun, Wan K, Huang J, Wang Y, Wang F (2012) Behavior of mixed formulation of metalaxyl and dimethomorph in grape and soil under field conditions. Ecotoxicology and Environmental Safety, 84(1), 112-116. https://doi.org/10.1016/j.ecoenv.2012.06.030.
  13. Lee SH, Kwak SY, Hwang JI, Kim HJ, Kim TH, Kim JE (2019) Correlation between physicochemical properties and biological half-life of triazole fungicides in perilla leaf. The Korean Society for Applied Biological Chemistry, 62(4), 407-415. https://doi.org/10.3839/jabc.2019.056.
  14. Cohen Y, Baider A, Cohen B (1995) Dimethomorph activity against oomycete fungal plant pathogens. The American Phytopathological Society, 85(12), 1500-1506. https://doi.org/10.1094/phyto-85-1500.