Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Modeling and Applications of Electrochemical Impedance Spectroscopy (EIS) for Lithium-ion Batteries

  • Choi, Woosung (Department of Energy Science, Sungkyunkwan University) ;
  • Shin, Heon-Cheol (School of Materials Science and Engineering, Pusan National University) ;
  • Kim, Ji Man (Department of Chemistry, Sungkyunkwan University) ;
  • Choi, Jae-Young (School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU)) ;
  • Yoon, Won-Sub (Department of Energy Science, Sungkyunkwan University)
  • Received : 2019.09.04
  • Accepted : 2019.10.27
  • Published : 2020.02.28
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Abstract

As research on secondary batteries becomes important, interest in analytical methods to examine the condition of secondary batteries is also increasing. Among these methods, the electrochemical impedance spectroscopy (EIS) method is one of the most attractive diagnostic techniques due to its convenience, quickness, accuracy, and low cost. However, since the obtained spectra are complicated signals representing several impedance elements, it is necessary to understand the whole electrochemical environment for a meaningful analysis. Based on the understanding of the whole system, the circuit elements constituting the cell can be obtained through construction of a physically sound circuit model. Therefore, this mini-review will explain how to construct a physically sound circuit model according to the characteristics of the battery cell system and then introduce the relationship between the obtained resistances of the bulk (Rb), charge transfer reaction (Rct), interface layer (RSEI), diffusion process (W) and battery characteristics, such as the state of charge (SOC), temperature, and state of health (SOH).

Keywords

References

  1. O. Heaviside, The Electriian., reprinted as Electrical Papers, 1886, 212.
  2. E. Warburg, Ann. Phys. Chem., 1899, 3, 493. https://doi.org/10.1002/andp.18993030302
  3. A.E. Thiessen, Gen. Radio Exp., 1933, 7, 7-9.
  4. D.C Grahame, Chem. Rev., 1947, 41(3), 441-501. https://doi.org/10.1021/cr60130a002
  5. V.D.D. MacDonald, Plenum Press. New York-London, 1977, 1, 358-359.
  6. D.E. Smith, H.H. Bauer, CRC Crit. Rev. Anal. Chem., 1971, 2(2), 247-343.
  7. C. Gabrielli, Tech. Rep. No 004, Solartron, Hampshire, UK., 1984, (3), 1-120.
  8. M.J. Ross, K.R. William, Impedance Spectroscopy: Emphasizing Solid Materials and Systems; John Wiley & Sons: John Wiley Sons New York, 1987.
  9. Y.H. Kim, Y.S. Kwon, M.Y. Shon, M.J. Moon, J. Electrochem. Sci. Technol., 2018, 9(1), 1-8. https://doi.org/10.5229/JECST.2018.9.1.1
  10. N.N. Hazani, Y. Mohd, S. Ahmad, I. Sheikh, M. Ghazali, Y. Farina, N.N. Dzulkifli, J. Electrochem. Sci. Technol., 2019, 10(1), 29-36. https://doi.org/10.5599/jese.717
  11. H.-B. Choe, H.-S. Lee, M.A. Ismail, M.W. Hussin, Int J Electrochem Sci., 2015, 10, 9775-9789.
  12. K. Pandey, S.T.A. Islam, T. Happe, F.A. Armstrong, F. A. Proc. Natl. Acad. Sci. U. S. A, 2017, 114(15), 3843-3848. https://doi.org/10.1073/pnas.1619961114
  13. A. Papaderakis, D. Tsiplakides, S. Balomenou, S. Sotiropoulos, J. Electroanal. Chem., 2015, 757, 216-224. https://doi.org/10.1016/j.jelechem.2015.09.033
  14. A.S. Dezfuli, M.R. Ganjali, H.R. Naderi, P. Norouzi, RSC Adv., 2015, 5, 46050-46058. https://doi.org/10.1039/C5RA02957K
  15. W. Du, Z. Wang, Z. Zhu, S. Hu, X. Zhu, Y. Shi, H. Pang, X. Qian, J. Mater. Chem. A, 2014, 2, 9613. https://doi.org/10.1039/C4TA00414K
  16. E.K. Park, J.W. Yun, J. Electrochem. Sci. Technol., 2016, 7(1), 33-40. https://doi.org/10.33961/JECST.2016.7.1.33
  17. A. Bertei, E. Ruiz-trejo, F. Tariq, V. Yufit, A. Atkinson, N.P. Brandon, Int. J. Hydrogen Energy, 2016, 41, 22381-22393. https://doi.org/10.1016/j.ijhydene.2016.09.100
  18. X. Zhang, W. Wu, Z. Zhao, B. Tu, D. Ou, D. Cui, M. Cheng, Catal. Sci. Technol., 2016, 6, 4945-4952. https://doi.org/10.1039/C5CY02232K
  19. X. Hu, S. Li, H. Peng, J. Power Sources, 2012, 198, 359-367. https://doi.org/10.1016/j.jpowsour.2011.10.013
  20. T. Momma, M. Matsunaga, D. Mukoyama, T. Osaka, J. Power Sources, 2012, 216, 304-307. https://doi.org/10.1016/j.jpowsour.2012.05.095
  21. A. Barai, K. Uddin, W.D. Widanage, A. McGordon, P. Jennings, Sci. Rep., 2018, 8(21).
  22. U. Krewer, F. Röder, E. Harinath, R.D. Braatz, B. Bedürftig, R. Findeisen, J. Electrochem. Soc., 2018, 165(16), A3656-A3673 https://doi.org/10.1149/2.1061814jes
  23. S. Rodrigues, N. Munichandraiah, A.K Shukla, J Solid State Electrochem., 1999, 3, 397-405. https://doi.org/10.1007/s100080050173
  24. S. Kochowski, K. Nitsch, Thin Solid Films, 2002, 415, 133-137. https://doi.org/10.1016/S0040-6090(02)00506-0
  25. S.P. Jing, J.G. Love, S.P.S. Badwal, Key Eng. Mater., 1997, 125-126, 81-132. https://doi.org/10.4028/www.scientific.net/KEM.125-126.81
  26. J.E.B. Randle, Discuss. Faraday Soc., 1947, 1, 11-19. https://doi.org/10.1039/df9470100011
  27. M. Gaberscek, J. Moskon, B. Erjavec, R. Dominko, J. Jamnik, Electrochem. Solid-State Lett., 2008, 11(10), A170-A174. https://doi.org/10.1149/1.2964220
  28. U. Westerhoff, K. Kurbach, F. Lienesch, M. Kurrat, Energy Technol., 2016, 4, 1620-1630. https://doi.org/10.1002/ente.201600154
  29. T. Momma, T. Yokoshima, H. Nara, Y. Gima, T. Osaka, Electrochim. Acta, 2014, 131, 195-201. https://doi.org/10.1016/j.electacta.2014.01.091
  30. O.S. Mendoza-Hernandez, H. Ishikawa, Y. Nishikawa, Y. Maruyama, Y. Sone, M. Umeda, Electrochim. Acta, 2014, 131, 168-173. https://doi.org/10.1016/j.electacta.2014.01.057
  31. D. Andre, M. Meiler, K. Steiner, H. Walz, T. Soczkaguth, D.U. Sauer, J. Power Sources, 2011, 196(12), 5349-5356. https://doi.org/10.1016/j.jpowsour.2010.07.071
  32. P. Gao, C. Zhang, G. Wen, J. Power Sources, 2015, 294, 67-74. https://doi.org/10.1016/j.jpowsour.2015.06.032
  33. B.T. Habte, F. Jiang, Solid State Ionics, 2018, 314, 81-91. https://doi.org/10.1016/j.ssi.2017.11.024
  34. H. Nara, D. Mukoyama, R. Shimizu, T. Momma, T. Osaka, J. Power Sources, 2019, 409, 139-147. https://doi.org/10.1016/j.jpowsour.2018.09.014
  35. D.W. Abarbanel, K.J. Nelson, J.R. Dahn, J. Electrochem. Soc., 2016, 163(3), A522-A529. https://doi.org/10.1149/2.0901603jes
  36. N.S. Zhai, M.W. Li, W.L. Wang, D.L Zhang, D.G. Xu, J. Phys. Conf. Ser, 2006, 48, 1157. https://doi.org/10.1088/1742-6596/48/1/215
  37. M.D. Murbach, D.T. Schwartz, J. Electrochem. Soc., 2018, 165(2), A297-A304. https://doi.org/10.1149/2.1021802jes
  38. A. Eddahech, O. Briat, J.-M Vinassa, J. Power Sources, 2014, 258, 218-227. https://doi.org/10.1016/j.jpowsour.2014.02.020
  39. S.F. Schuster, T. Bach, E. Fleder, J. Muller, M. Brand, G. Sextl, A. Jossen, J. Energy Storage, 2015, 1, 44-53. https://doi.org/10.1016/j.est.2015.05.003
  40. S.F. Schuster, M.J. Brand, C. Campestrini, M. Gleissenberger, A. Jossen, J. Power Sources, 2016, 305, 191-199. https://doi.org/10.1016/j.jpowsour.2015.11.096
  41. J. Vetter, P. Novak, M.R. Wagner, C. Veit, K.-C. Moller, J.O. Besenhard, M. Winter, M. Wohlfahrt-Mehrens, C. Vogler, A. Hammouche, J. Power Sources, 2005, 147, 269-281. https://doi.org/10.1016/j.jpowsour.2005.01.006
  42. K.M. Shaju, F. Jiao, A. lie Debart, P.G. Bruce, Phys. Chem. Chem. Phys., 2007, 9, 1837-1842. https://doi.org/10.1039/B617519H
  43. K.-A. Kwon, H.-S. Lim, Y.-K. Sun, K.-D. Suh, J. Phys. Chem. C, 2014, 118, 2897-2907. https://doi.org/10.1021/jp5000057
  44. S. Xu, C.M. Hessel, H. Ren, R. Yu, Q. Jin, M. Yang, H. Zhao, D. Wang, Energy Environ. Sci., 2014, 7, 632. https://doi.org/10.1039/C3EE43319F
  45. D. Chen, H. Quan, J. Liang, L. Guo, Nanoscale, 2013, 5, 9684. https://doi.org/10.1039/c3nr03484d
  46. Y. Xiao, X. Wang, W. Wang, D. Zhao, M. Cao, ACS Appl. Mater. Interfaces, 2014, 6, 2051-2058. https://doi.org/10.1021/am405142p
  47. S.S. Zhang, K. Xu, T.R. Jow, Electrochim. Acta, 2006, 51(8-9), 1636-1640. https://doi.org/10.1016/j.electacta.2005.02.137
  48. M. Steinhauer, S. Risse, N. Wagner, K.A. Friedrich, Electrochim. Acta., 2017, 228, 652-658. https://doi.org/10.1016/j.electacta.2017.01.128
  49. J.S. Gnanaraj, R.W. Thompson, S.N. Iaconatti, J.F. Dicarlo, K.M. Abraham, Electrochem. Solid-State Lett., 2005, 8(2), A128-A132. https://doi.org/10.1149/1.1850390
  50. T.S. Sahu, S. Mitra, Sci. Rep., 2015, 5, 12571. https://doi.org/10.1038/srep12571
  51. W. Lee, S. Muhammad, T. Kim, H. Kim, E. Lee, M. Jeong, S. Son, J.-H. Ryou, W.-S. Yoon, Adv. Energy Mater, 2018, 8, 1701788. https://doi.org/10.1002/aenm.201701788
  52. S.S. Zhang, K. Xu, T.R. Jow, Electrochim. Acta, 2004, 49(7), 1057-1061. https://doi.org/10.1016/j.electacta.2003.10.016
  53. N. Ogihara, S. Kawauchi, C. Okuda, Y. Itou, Y. Takeuchi, Y. Ukyo, J. Electrochem. Soc., 2012, 159(7), A1034-A1039. https://doi.org/10.1149/2.057207jes
  54. N. Ogihara, Y. Itou, T. Sasaki, Y. Takeuchi, J. Phys. Chem. C, 2015, 119(9), 4612-4619. https://doi.org/10.1021/jp512564f
  55. C. Ho, I.D. Raistrick, R.A. Huggins, J. Electrochem. Soc., 1980, 127(2), 343-350. https://doi.org/10.1149/1.2129668
  56. H. Xia, L, Lu, G. Ceder, J. Power Sources, 2006, 159, 1422-1427. https://doi.org/10.1016/j.jpowsour.2005.12.012
  57. X.H. Rui, N. Ding, J. Liu, C. Li, C.H. Chen, Electrochim. Acta, 2010, 55(7), 2384-2390. https://doi.org/10.1016/j.electacta.2009.11.096
  58. J. Xie, N. Imanishi, T. Matsumura, A. Hirano, Y. Takeda, O. Yamamoto, Solid State Ionics, 2008, 179(9-10), 362-370. https://doi.org/10.1016/j.ssi.2008.02.051
  59. S.B. Tang, M.O. Lai, L. Lu, J. Alloys Compd., 2008, 449(1-2), 300-303. https://doi.org/10.1016/j.jallcom.2005.12.131
  60. H. Liu, C. Li, H.P. Zhang, L.J. Fu, Y.P. Wu, H.Q. Wu, J. Power Sources, 2006, 159(1), 717-720. https://doi.org/10.1016/j.jpowsour.2005.10.098
  61. J. Xie, T. Tanaka, N. Imanishi, T. Matsumura, A. Hirano, Y. Takeda, O. Yamamoto, J. Power Sources, 2008, 180(1), 576-581. https://doi.org/10.1016/j.jpowsour.2008.02.049
  62. X.H. Rui, N. Ding, J. Liu, C. Li, C.H. Chen, Electrochim. Acta, 2010, 55(7), 2384-2390. https://doi.org/10.1016/j.electacta.2009.11.096
  63. N. Ding, J. Xu, Y.X. Yao, G. Wegner, X. Fang, C.H. Chen, I. Lieberwirth, Solid State Ionics, 2009, 180(1-2), 222-225. https://doi.org/10.1016/j.ssi.2008.12.015

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