Concentrations of $C_2$~$C_9$ Volatile Organic Compounds in Ambient Air in Seoul

서울 대기 중에서 $C_2$~$C_9$ 휘발성 유기화합물의 농도

  • 나광삼 (한국과학기술연구원 지구환경 연구센터) ;
  • 김용표 (한국과학기술연구원 지구환경 연구센터) ;
  • 김영성
  • Published : 1998.04.01

Abstract

Volatile organic compounds (VOCs) from Ca to C9 were investigated with nine ambient air samples collected in April 26, August 17, 1996 and January 23, 1997 in a Seoul site. On each sampling day, three 2-hr integrated canister samples were collected in early morning, early afternoon and late afternoon, respectively to study temporal . variation of VOCs. Most of VOC species showed diurnal variation with higher concentrations in the early morning and lower concentrations in the afternoon. The concentrations of light alkanes were high, probably due to the emission from liquefied petroleum gas (LPG) and evaporation of gasoline. Especially, the concentration of propane was the highest in the morning samples. The concentrations of propane, ethylene, acetylene, and toluene were prominent in their hydrocarbon groups, respectively. These components were the main source of car exhaust, gasoline evaporization, LPG, or solvent usage.

Keywords

References

  1. 도시가스(천연가스) 기술자료 극동도시가스
  2. 한국대기보전학회 울산 대기 중의 입자상, 기체상 이온성분과 휘발성 유기화합물의 농도 나광삼;김용표;문길주
  3. 서울지역 도시가스 보급율 조사 도시가스협회
  4. 석유년보 대한석유협회
  5. 한국대기보전학회지 v.10 no.1 서울시의 1993년 가을철 시정 및 입자 특성 측정 및 분석 백남준;김태오;김성주;김용표;문길주
  6. 서울의 환경 서울특별시
  7. 휘발유분석자료 석유품질검사소
  8. 에너지 통계 연보 상공자원부 에너지 경제 연구원
  9. LPG 자료 유공가스 사업개발팀
  10. 국립환경연구원보 v.15 도시 대기오염의 특성과 광화학반응에 관한 연구 최덕일;한의정;한진석;신찬기;강인구;김상균;김정수;유승도;최수언;권평수
  11. 도시가스 보급률 자료 통계청
  12. 지역별 부탄, 프로판 소비 한국석유개발공사 국내조사부
  13. 유해 대기오염물질 규제에 관한 국내 대응 방안 연구 한화진
  14. VOC 배출원별 배출량 산정 및 저감기술 연구 한화진
  15. 한국대기보전학회지 v.9 다변량해석을 이용한 서울시 하계 스모그의 형태 분류 홍낙기;이종범;김용국
  16. 1995 환경통계연감 환경부
  17. Atmos. Environ. v.23 Wintertime source-reconciliation of ambient organics Aronian, P. F.;P. A. Scheff;R. A. Wadden
  18. Atmos. Environ. v.24A Gas-phase tropospheric chemistry of organic compounds : A review Atkinson, R
  19. Atmos. Environ. v.24A Speciated hydrocarbon emissions from vehicles operated over the normal speed range on the road Bailey, J. C.;B. Schmidl;M. L. Williams
  20. Atmos. Environ. v.31 Determination of aromatic hydrocarbons in urban air of Rome Brocco, D;R. Fratarcangeli;L. Lepore;M. Petricca;I. Ventrone
  21. Environ. Sci. Technol. v.30 Viability of using SUMMA polished canisters for the collection and storage of parts per bilion by volume level volatile organics Brymer, D.;L. D. Ogle;C. J. Johnes;D. L. Lewis
  22. Atmos. Environ. v.30 Benzene and toluene in New Zealand Air Clarkson, T. S.;R. J. Martin;J. Rudolph;B. W. L. Graham
  23. Atmos. Environ. v.19 The concentrations of specific C_2~C_6 hydrocarbons in the air of NW England Colbeck, I;R. M. Harrison
  24. United Kingdom Atomic Energy Authority, Harwell modeling and assessments group, AEA environment and energy, harwell laboratory report AERE R 13736 Hydrocarbon involvement in photochemical ozone formation in Europe Derwent, R. G.;M. E. Jenkin
  25. Atmos. Environ. v.27A The production and release to the atmosphere of CFCs 113, 114, and 115 Fisher, D. A.;P. M. Midgley
  26. Evaluation and development of methods for the measurement of hydrocarbons and carbonyl compounds in planning and managing regional air quality-modeling and measurement studies Fung, K;M. Porter;D. Fitz;E. Fujita;P. S. Solomon(ed.);T. A. Silver(ed.)
  27. Report to KIST, Atm AA, Inc. Analysis of hydrocarbons in air Fung, K.
  28. J. Air Poll. Control Ass v.34 Hydrocarbons and carbonyls in Los Angeles air Grosjean, D;K. Fung
  29. Atmos. Environ. v.24A C_2~C_5 hydrocarbons in rural south Norway Hov, O.;N. Schmidbauer;M. Oehme
  30. Environ. Sci. Technol. v.28 Concentrations and transformations of hazardous air pollutants Kelly, T. J.;R. Mukund;C. W. Spicer;A. J. Pollack
  31. Atmos. Environ. v.24A Estimation of volatile organic compounds(VOC) emissions for Hungary Molnar, A.
  32. Atmos. Environ. v.30 Source attribution of ambient air toxic and other VOCs in Columbus, Ohio Mukund, R.;T. J. Kelly;C. W. Spicer
  33. Envir. Sci. Technol. v.16 Non-methane hydrocarbons in the atmosphere of Sydney;A Quantitative determination using a source reconciliation technique Nelson, P. F.;S. M. Quigley
  34. Atmos. Environ. v.17 Sources of atmospheric hydorcarbons in Sydney;A quantitative determination using a source reconciliation technique Nelson, P. F.;S. M. Quigley;M. Y. Smith
  35. Atmos. Environ. v.20 Sampling integrity of trace level volatile organic compounds in ambient air stored in SUMMA polished canisters Oliver, K. D.; J. D. Pleil;W. A. McClenny
  36. J. Air Pollut. Control Ass. v.39 Source fingerprints for receptor modeling of volatile organics Scheff, P. A.; R. A. Wadden;P. Aronian;B. Bates
  37. Environ. Sci. Technol. v.14 Ambient hydrocarbon and ozone measurements downwind of a large automotive painting plant Sexton, K.;H. Westberg
  38. Atmos. Environ. v.24A Measurement of volatile organic chemicals at selected sites in California Singh, H. B.;L. Salas;W. Viezee;B. Sitton;R. Ferek
  39. Atmos. Environ. v.24A The infulence of ambient temperature on tailpipe emissions from 1985 to 1987 model year light-duty gasoline vehicle-Ⅱ Stump, F.;S. Tejada;W. Ray;D. Dropkin;F. Black;R. Snow;W. Crews;P. Suidak;C. O. Davis;P. Carter
  40. EPA/600/4-89/017 Compendium of methods for the determination of toxic organic compounds in ambient air US EPA
  41. Environ. Sci. Technol. v.20 Source discrimination of short-term hydrocarbon samples measured aloft Wadden, R. A.;I. Uno;S. Wakamatsu
  42. Atmos. Environ. v.28 Receptor modeling of VOCs-Ⅱ Development of VOC control functions for ambient ozone Wadden, R. A.;P. A. Scheff;I. Uno