Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
권호 표지

Modification of Tencel Fabric Treated with Chitosan ( I ) - Change of Physical Properties -

키토산처리에 의한 텐셀 직물의 개질기능화(I) - 물성 변화를 중심으로 -

  • Published : 2002.02.01
Download PDF
⟨ Previous Next ⟩

Abstract

Chitosan has reactive amino and hydroxyl groups which can be used to chemically alter its properties under the mild reaction conditions. Thus the cationization of Tencel with Chitosan is effective to modify the fabric. To investigate the modified properties of Tencel fabric, the tests were performed under the several finishing process with enzyme/glutaraldehyde/softener. The internal structure of Tencel which has the structure of cellulose II wasn't changed by enzyme, chitosan and crosslinking agent treatment and the thermal stability was improved by chitosan and crosslinking agent treatment. Wrinkle recovery angle under the dry condition increased highly until $0.1\textrm{mol}/\ell$ of glutaraldehyde concentration, and then decreased. Tensile strength of modified Tencel fabric decreased with increasing of weight loss, but it was improved more or less by chitosan, crosslinking agent and softener. Moisture regain was improved by enzyme and chitosan treatment. And antibacterial activity showed nearly 100% on Tencel fabric treated with 0.5% chitosan and adsorption of metal ion increased with increasing of chitosan concentration.

Keywords

References

  1. U.S. Patent, 2,179,181 106/200.3 C. Graenacher;R. Sallman
  2. U.S. Patent, 4,196, 282 Process for Making a Shapeable Cellulose and Shaped Cellulose Products N. E. Franks;J. K. Varga
  3. U.S. Patent, 4, 416, 698 Shaped Cellulose Article Prepared from a Solution Containing Cellulose Dissolved in a Tertiary Amine N-oxide Solvent and a Process for Making the Article C. C. McCorsley
  4. Chem. Fibers Int. v.47 Lyocell Fibers W. Albrecht;M. Reinthes;B. Wulfhorst
  5. Cellulose Chem. Technol. v.24 Fibrillar Structure and Deformation Behaviour of Regenerated Cellulose Fibers J. Leuz;J. Schurg
  6. Textile Res. J. v.17 Introduction of Amino Groups into Cotton Fabric by use of 2-Aminoethylsulfuric Acid J. D. Guthrie https://doi.org/10.1177/004051754701701105
  7. J. Appl. Polym. Sci. v.22 Preparation of Chemically Modified Cotton via Introduction of Aromatic Amino Group A. Hebeish;A. Waly;A. A. Moursi;M. H. E. I. Rafie https://doi.org/10.1002/app.1978.070220928
  8. J. Korean Fiber Soc. v.34 no.9 Study on the Change of Hand of Chitosan treated Fabrics J. J. Kim;D. W. Jeon;S. Y. Ahn
  9. Macromol. Chem. v.186 Metachromatic Behavior of Sodium 2'-Hydroxy 1,1' Azo-Naphthalene-4-Sulfon ate in the Presence of Chitosan B. D. Gummow;G.A.F. Roberts https://doi.org/10.1002/macp.1985.021860612
  10. Int. J. Biol. Macromol. v.13 Determination of the Mark Houwink Equation for Chitosan with Degree of Deacetylation W. Wang;S. Bo;W. Qin https://doi.org/10.1016/0141-8130(91)90027-R
  11. J. Korean Fiber Soc. v.24 no.5 Enzymatic Treatment of Tencel Fabrics Treated with NaOH and Prefibrillation(Ⅱ) K. H. Son;Y. S. Shin
  12. Textile Res. J. v.70 Effect of Liquid Ammonia, Sodkum Hydroxide/Liquid Ammonia and Subsequent Cellulase Treatments on Mechanical Properties of Cotton Fabric T. Wakida;T. Moriya;M. Lee;H. Yoshioka;Y. Yanai https://doi.org/10.1177/004051750007000212
  13. J. Korean Fiber Soc. v.33 no.5 Enzymatic Treatment of the Liquid Ammonia and Subsequent Cellulase Treatments on Mechanical Properties of Cotton Fabric T. Wakida;T. Moriya;M. Lee;H. Yoshioka;Y. Yanai
  14. J. Korean Fiber Soc. v.33 no.5 Enzymatic Treatment of the Liquid Ammonia Pretreated Cellulose Fabrics(Ⅱ) S. Y. Bae;M. C. Lee;I. G. Shin;K. W. Kim
  15. Technology of Textile and Industry v.2 no.2 Technology of Deying and Finishing of Lyocell J. H. Jeon;W. S. Lee
  16. J. Korean Fiber. Soc. v.36 no.9 Interactions between Polyelectrolyte Based on Crosslinked Chitosan and Amphoteric Surfactant H. S. Bae
  17. J. Korean Fiber Soc. v.32 no.8 A Study on the Change of Hand of Chitosan-treated Cotton Fabric J. J. Kim;S. H. Kim;D. W. Jeon
  18. Colloid Polym. Sci. v.271 Properties and Structure of Solvent-Spun and Viscose-Type Fibers in the Swollen State J. Lenz;J. Schurz;E. Wrentschur https://doi.org/10.1007/BF00657390
  19. Proceedings from the 3rd International Conference on Chitin and Chitosan In the Chitin in Nature and Technology L. A. Hadwiger;D. F. Kendra;B. W. Fristensky;W. Wagoner;R.A.A. Muzzarelli(ed.)
  20. Sen-i Kagaku v.50 no.5 Preparation and Antibacterial Activites of N-Teimethylammonium Salts of Chitosan T. Katsumasa;H. Takao
  21. J. Korean Fiber Soc. v.33 no.6 Y. S. Shin;H. K. Min
  22. Pure & Appl. Chem. v.54 no.11 N-(o - carboxylvenzyl) Chitosan, N-Carboxylmethyl Chitosan and Dithiocarbamate Chitosan : New Chelating Derivatives of Chitosan R. A. A. Muzzarelli;F. Tanfani