Transactions of the Korean hydrogen and new energy society (한국수소및신에너지학회논문집)

The Korean Hydrogen and New Energy Society (한국수소및신에너지학회)
권호 표지

Partial Reduction and Water Splitting Characteristics of Metal Substituted Ferrite Mediums for Thermochemical Hydrogen Production

열화학 수소 제조를 위한 금속 치환 페라이트 매체의 부분 환원 및 물 분해 특성

  • Lee, Dong-Hee (Department of Fine Chemicals Engineering & Applied Chemistry, BK21-E2M, Chungnam National University) ;
  • Kim, Hong-Soon (Department of Fine Chemicals Engineering & Applied Chemistry, BK21-E2M, Chungnam National University) ;
  • Cha, Kwang-Seo (Department of Fine Chemicals Engineering & Applied Chemistry, BK21-E2M, Chungnam National University) ;
  • Park, Chu-Sik (Korea Institute of Energy Research) ;
  • Kang, Kyung-Soo (Korea Institute of Energy Research) ;
  • Kim, Young-Ho (Department of Fine Chemicals Engineering & Applied Chemistry, BK21-E2M, Chungnam National University)
  • 이동희 (충남대학교 정밀응용화학과 BK21-에너지환경소재사업단) ;
  • 김홍순 (충남대학교 정밀응용화학과 BK21-에너지환경소재사업단) ;
  • 차광서 (충남대학교 정밀응용화학과 BK21-에너지환경소재사업단) ;
  • 박주식 (한국에너지기술연구원) ;
  • 강경수 (한국에너지기술연구원) ;
  • 김영호 (충남대학교 정밀응용화학과 BK21-에너지환경소재사업단)
  • Published : 2007.12.15
Download PDF
⟨ Previous Next ⟩

Abstract

The partial reduction and water splitting properties of metal substituted ferrite mediums for two-step thermochemical hydrogen production, were carried out by TPR/O(Temperature programmed reduction/oxidation) method at a temperature of below 1173 K and under atmospheric pressure. $ZrO_2$ was added to the ferrite as a binder to prevent the sintering. As the results, the reactivity of the metal species added to the ferrite mediums decreased in the order of Cu>Co>Ni>Mn, on the basis of water-splitting temperature. It was also found that the produced hydrogen amounts in the water-splitting step on partial reduced mediums were corresponding to the consumed hydrogen amounts in the previously partial reduction step.

Keywords

References

  1. J. E. Funk, and R. M. Reinstrom, 'Energy requirements in the production of hydrogen from water', Ind. Eng. Chem. Proc. Des. Develop., Vol. 5, 1966, p. 336
  2. T. Nakamura, 'Hydrogen production from water utilizing solar heat at high temperatures', Solar Energy, Vol. 19, 1977, p. 467 https://doi.org/10.1016/0038-092X(77)90102-5
  3. A. Steinfeld, S. Sanders, and R. Palumbo, 'Design aspects of solar thermochemical engineering-a case study: two-step watersplitting cycle using the $Fe_3O_4/FeO$ redox system' Solar Energy, Vol. 65, 1999, p. 45
  4. K. Otsuka, M. Hatano, and A. Morikawa, 'Hydrogen from water by reduced cerium oxide', J. Catal., Vol. 79, 1983, p. 493 https://doi.org/10.1016/0021-9517(83)90346-9
  5. A. Steinfeld, 'Solar hydrogen production via a two-step water-splitting thermochemical cycle based on Zn/ZnO redox reactions', Int. J. Hydrogen Energy, Vol. 27, 2002, p. 611 https://doi.org/10.1016/S0360-3199(01)00177-X
  6. 조미선, 김우진, 김창희, 강경수, 김영호, 박주식, '고에너지 볼 밀링을 통한 Co-ferrite 제조 및 열적 환원에 대한 연구', 한국수소 및 신에너지 학회 논문집, Vol. 17, No. 3, 2006, p. 309
  7. 김진웅, 최승철, 주오심, 정광덕, '열화학싸이클 수소 제조를 위한 ($Cu_{0.5}Mn_{0.5}$)Fe_2O_4$의 열적 거동', 한국수소 및 신에너지학회 논문집, Vol. 15. No. 1, 2004, p. 32
  8. Y. Tamaura, M. Kojima, T. Sano, Y. Ueda, N. Hasegawa, and M. Tsuji, 'Thermodynamic evaluation of water splitting by a cation -excessive (Ni, Mn) ferrite', Int. J. Hydrogen Energy, Vol. 23, 1998, p. 1185 https://doi.org/10.1016/S0360-3199(98)00007-X
  9. T. Kodama, Y. Wada, T. Yamamoto, M. Tsuji, and Y. Tamaura, 'ynthesis and characterization of ultrafine Nickel(II)-bering ferrites', J. Mater. Chem., Vol. 5, 1995, p. 1413 https://doi.org/10.1039/jm9950501413
  10. T. Kodama, Y. Kondoh, R. Yamamoto, H. Andou, and N. Satou, 'Thermochemical hydrogen production by a redox system of $ZrO_2$-supported Co(II)-ferrite', Solar Energy, Vol. 78, 2005, p. 623 https://doi.org/10.1016/j.solener.2004.04.008
  11. 차광서, 류재춘, 이동희, 김영호, 박주식, 김종원, '$ZrO_2$ 첨가 MnO_2/Mn_2O_3 /NaOH$ 계를 이용한 열화학적 물분해 수소제조 실험 연구', 한국수소 및 신에너지학회 논문집, Vol 17, No. 4, 2006, p. 353
  12. C. Agrafiotis, M. Roeb, A. G.Konstandopoulos, L. Nalbandian, V. T. Zaspalis, C. Sattler, P. Stobbe, and A. M. Steele, 'Solar water splitting for hydrogen production with monolithic reactors', Solar Energy, Vol. 79, No. 4, 2005, p. 409 https://doi.org/10.1016/j.solener.2005.02.026
  13. 차광서, 이동희, 조원준, 이영석, 김영호, '페라이트계 금속 산화물 매체 상에서 열화학 메탄 개질 반응 특성', 한국수소 및 신에너 지학회 논문집, Vol. 18, No. 2, 2007, p. 140
  14. K. Chen, Y. Fan, Z. Hu, and Q. Yan, 'Study on the reduction behavior of zirconia supported iron oxide catalysts by Temperature- Programmed reduction combined with in situ Mossbauer Spectroscopy', J. Solid State Chem., Vol. 121, 1996, p. 240 https://doi.org/10.1006/jssc.1996.0034