Journal of Industrial and Engineering Chemistry

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Hemicelluloses obtaining from rapeseed cake residue generated in the biodiesel production process

  • Egues, I. (Chemical and Environmental Engineering Department, University of the Basque Country) ;
  • Alriols, M. Gonzalez (Chemical and Environmental Engineering Department, University of the Basque Country) ;
  • Herseczki, Z. (Cooperative Research Centre for Environmental and Information, Technology & Bioresource Group, University of Pannonia) ;
  • Marton, G. (Cooperative Research Centre for Environmental and Information, Technology & Bioresource Group, University of Pannonia) ;
  • Labidi, J. (Chemical and Environmental Engineering Department, University of the Basque Country)
  • Received : 2009.08.22
  • Accepted : 2009.10.27
  • Published : 2010.03.25
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Abstract

The processing of rapeseed oil seeds for biodiesel production generates huge amounts of lignocellulosic cake residue mainly composed by cellulose, hemicelluloses and lignin. In this work, the valorisation of these components, especifically the majoritary fraction, hemicelluloses, was studied. Hemicelluloses were extracted, purified and characterized by different techniques (FTIR, $^1H\;NMR$, $^{13}C\;NMR$, and GPC). Autohydrolysis and acid hydrolysis processes were applied to obtain sugar monomers and oligomers. Glucose and xylose were the main simple sugars in the obtained hydrolysates, representing 22.7% and 40.2% of total sugars content in the autohydrolysis hydrolysates and 27.7% and 36.6% in the acid hydrolysates respectively. Arabinose, galactose and mannose were present in relatively minor quantities.

Keywords

Acknowledgement

Supported by : Spanish Ministry of Environmental and Rural and Marine Affairs

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