Korean Journal of Chemical Engineering

The Korean Institute of Chemical Engineers (한국화학공학회)
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Characterization of metal corrosion by aqueous amino acid salts for the capture of $CO_2$

  • Ahn, Seong-Yeon (Department of Chemical and Biomolecular Engineering, Yonsei University) ;
  • Song, Ho-Jun (Department of Chemical and Biomolecular Engineering, Yonsei University) ;
  • Park, Jin-Won (Department of Chemical and Biomolecular Engineering, Yonsei University) ;
  • Lee, Ji-Hyun (Green Growth Laboratory, Korea Electric Power Research Institute) ;
  • Lee, In-Young (Green Growth Laboratory, Korea Electric Power Research Institute) ;
  • Jang, Kyung-Ryong (Green Growth Laboratory, Korea Electric Power Research Institute)
  • Received : 2009.11.16
  • Accepted : 2010.01.12
  • Published : 2010.09.01
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Abstract

We investigated the absorption ability of potassium salts of amino acid solutions for carbon dioxide and compared the results with MEA. The corrosion and degradation behavior were investigated in a $CO_2$ absorption process using aqueous potassium salts of glycine and taurine. The experimental parameters varied were the concentration, amino acid type, temperature, $CO_2$ loading, piperazine, and the presence of corrosion inhibitors. The corrosion characteristics of carbon steel were measured with potassium glycinate and potassium taurate solutions over a wide range of concentrations (1.5 to 5.0M) and temperatures (313.15 to 353.15 K). The corrosion rate was calculated using a weight loss method averaging the results of four specimens. The experimental results indicate that increases in the concentration of the aqueous amino acid salts, solution temperature, $CO_2$ loading, and piperazine concentration accelerate the corrosion rate. In addition, corrosion inhibitors were proven to be effective in controlling corrosion.

Keywords

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