Effects of Sewage Effluent on Organic Matters of Nakdong River: Comparison of Daily Loading

낙동강 수계 내 하수처리 방류수가 하류 하천 유기물에 미치는 영향: 부하량 비교

  • Seong, Jin-Uk (Department of Environmental Engineering, Kumoh National Institute of Technology) ;
  • Park, Je-Chul (Department of Environmental Engineering, Kumoh National Institute of Technology)
  • 성진욱 (금오공과대학교 환경공학과) ;
  • 박제철 (금오공과대학교 환경공학과)
  • Received : 2012.03.01
  • Accepted : 2012.05.31
  • Published : 2012.06.30

Abstract

This study investigated the water quality of effluents from the wastewater treatment plants, located at the Gumi Complex 4, Gumi, and Wonpyong, in Gumi. DOC accounted for higher than 70% of TOC, and oxidation efficiencies, calculated from carbon, were 13~43% for BOD and 37~73% for CODMn, respectively. Based on the biological decomposition experiments, R-DOC account for higher than 70% of DOC, mostly being occupied by refractory organic matters. This indicated that the biodegradable organics occupied more proportions of organic loadings than the refractory organics. The effect of the organics from a discharge of a sewage treatment plant on rivers, Gumi industrial Complex 4, Gumi, and Wonpyong on lower streams of the Nakdong River were found to be 15%, 6% and 16% respectively. The ratio of 15% suggests that comparatively, no large portions of TOC loadings are occupied, but the problem is that the biodegradable organic matters occupy a lot more proportions than that of the refractory organic matters. Thus, it is highly estimated that the refractory organics can gradually increase the pollution level of organics and precursors of disinfection by-products to the down-stream water treatment plants.

본 연구는 하수처리장 방류수가 하천 유기물 오염에 미치는 영향을 파악하기 위하여 구미시 관내에 위치한 구미 4단지, 구미, 구미 원평하수처리장 방류수와 처리장 상 하류 하천을 조사하였다. TOC 중 DOC가 70% 이상으로 대부분 용존성으로 존재하였고, TOC에 대한 BOD, $COD_{Mn}$의 산화율은 각각 13~43%, 37~73%로 나타났다. 하지만 현재 사용되고 있는 BOD, $COD_{Mn}$이 총 유기탄소에서 차지하는 비율이 약 50% 이하로 나타나, 유기물을 대표하는 데 어려움이 있을 것으로 보이며, 향후 TOC로 지표를 전환하는 방향도 모색해 보아야 할 것으로 판단된다. DOC 분해실험 결과 DOC 중 R-DOC가 70% 이상으로 난분해성 유기물이 대부분을 차지하는 것으로 나타났다. 하수처리장 방류수의 유기물이 하천에 미치는 영향을 보면, 낙동강 하류에서 구미 4단지, 구미, 구미 원평하수처리장 방류수의 총 TOC 부하량이 차지하는 비율은 15%로 나타났다. 총 비율은 15%로 비교적 많은 부분을 차지하지는 않았지만 이 중 생분해성 유기물보다 난분해성 유기물이 더 많은 부분을 차지하는 것으로 나타나, 상수 처리 시 소독부산물의 전구물질이 증가하는 원인으로 작용할 수 있을 것으로 판단된다.

Keywords

References

  1. An, Y.K. 2009. A study on the relationship between TOC and COD at effluent of the Sewage Treatment Plant. Graduate School of Kumoh National Institute of Technology.
  2. Byun, J.D., T.D. Kim, B.H. Jung, T.S. Shin and H.O. Kim. 2010. TOC as a potential index for organic contents of wastewater treatment plant effluents. Journal of the Korean Society for Environmental Analysis 13(2): 99-103.
  3. Chin, Y.P., G.R. Aiken and K.M. Danielsen. 1997. Binding of pyrene to aquatic and commercial humic substances: The role of molecular weight and aromaticity. Environmental Science and Technology 31(6): 1630-1635. https://doi.org/10.1021/es960404k
  4. Croue, J.P., G.V. Korshin, J.A. Leenheer and M.M. Benjamin. 1998. Isolation fractionation and characterization of natural organic matter in drinking water. AWWARF report.
  5. Degens, E.T. 1982. SCOPE/UNEP Transport of carbon and minerals in major river part 1, University of Hamburg, German.
  6. Dignac, M.F., P. Ginestet, D. Rybacki, A. Bruchet, V. Urbail and P. Scribe. 2000. Fate of wastewater organic pollu-tion during activated sludge treatment: Nature of residual organic matter. Water Research 34(17): 4185-4194. https://doi.org/10.1016/S0043-1354(00)00195-0
  7. Grieve, I.C. 1990. Seasonal, hydrological, and land management factors controlling dissolved organic carbon concentrations in the Loch Fleet catchments, southwest Scotland. Hydrological Processes 4: 231-239. https://doi.org/10.1002/hyp.3360040304
  8. Hong, J.H. and J.S. Sohn. 2004. Treatment efficiency and organic matter characterization of wastewater through activated sludge process and advanced wastewater treatment process. Journal of the Korean Society of Water and Wastewater 18(6): 807-813.
  9. Hur, J. and M.A. Schlautman. 2004. Influence of humic substance adsorptive fractionation on pyrene partitioning to dissolved and mineral-associated humic substance. Environmental Science and Technology 38(22): 5871- 5877. https://doi.org/10.1021/es049790t
  10. Imai, A., T. Fukushima, K. Matsushige, Y.H. Kim and K. Choi. 2002. Characterization of dissolved organic matter in effluents from wastewater treatment plants. Water Research 36(4): 859-870. https://doi.org/10.1016/S0043-1354(01)00283-4
  11. Jang, C.W., J.K. Kim, D.H. Kim, B.C. Kim and J.H. Park. 2008. The distribution of organic carbon and its decomposition rate in the Kum River, Korea. Journal of Korean Society on Water Quality 24(2): 174-179.
  12. Jung, N.I. 2007. Analysis and Prediction of Water Quality Variation in Flow Line of Gwangju Stream. Graduate School of Jhonnam National University.
  13. Kim, J.K., M.S. Shin, C.W. Jang, S.M. Jung and B.C. Kim. 2007. Comparison of TOC and DOC distribution and the oxidation efficiency of BOD and COD in several reservoirs and rivers in the Han River System. Journal of Korean Society on Water Quality 23(1): 72-80.
  14. Kwak, M.A., J.H. Jung, S.M. Eo and H.K. Lee. 2004. The assessment on the effect of discharge and variation of water quality from the sewage treatment plants in Seoul. Korean Journal of Sanitation 19(3): 1-13.
  15. Lalah, J.O. and S.O. Wangdiga. 2007. Copper binding by dissolved organic matter in freshwaters in Kenya. Bulletin of Environmental Contamination and Toxicology 79: 633-638. https://doi.org/10.1007/s00128-007-9278-4
  16. Lee, T.H., B.M. Lee, J. Hur, M.S. Jung and T.G. Kang. 2010. Conversion of CODMn into TOC and refractory organic matter concentrations for treated sewage using regression equations. Journal of Korean Society on Water Quality 26(6): 969-975.
  17. Lee, T.H., M.H. Park, B.M. Lee, J. Hur and H.J. Yang. 2009. Effects of the characteristics of influent wastewater on removal efficiencies for organic matters in wastwater treatment plants. Journal of Korean Society on Water Quality 25(5): 674-681.
  18. Marhaba, T.F. and D. Van. The variation of mass and disinfection by-product formation potential of dissolved organic matter fractions along a conventional surface water treatment plant. Journal of Hazardous Materials A74: 133-147.
  19. Meyer, J.L. 1986. Dissolved organic carbon dynamics in two subtropical blackwater rivers. Archiv fur Hydrobiologie 108: 119-134.
  20. Ogura, N. 1972. Rate and extent of decomposition of dissolved organic matter in surface seawater. Journal of Experimental Marine Biology and Ecology 13: 89-93.
  21. Park, J.C., M. Aizaki, T. Fukushima and A. Otsuki. 1997. Production of labile and refractory dissolved organic carbon by zooplankton excretion: An experimental study using large outdoor continuous flow-throught pond. Canadian Journal of Fisheries and Aquatic Sciences 54: 434-443. https://doi.org/10.1139/f96-278
  22. Peiris, R.H., H. Budman, C. Moresoli and R.L. Legge. 2010. Understanding fouling behavior of ultrafiltration membrane processes and natural water using principal component analysis of fluorescence. Journal of Membrane Science 357(1-1): 62-72.
  23. Selcuk, H., L. Rizzo, A.N. Nikolaou, S. Meric, V. Belgiorno and M. Bekbolet. 2007. DBPs formation and toxicity monitoring in different origin water treated by ozone and alum/PAC coagulation. Desalination 210(1-3): 31- 43. https://doi.org/10.1016/j.desal.2006.05.030
  24. Seo, H.J., Y.J. Kang, K.W. Min, G.Y. Seo, S.H. Kim, K.J. Paik and S.J. Kim. 2010. Characteristics of distribution and decomposition of organic matters in stream water and sewage effluent. Analytical Science and Technology 23(1): 36-44. https://doi.org/10.5806/AST.2010.23.1.036
  25. Seoul Development institute. 1996. A Study on the Applicability of Small-Scale Sewage Treatment Facilities in Seoul.
  26. Seong, J.U., H.J. Kim and J.C. Park. 2011. Characteristics of TOC Distribution in Lake Hapcheon. Journal of the Environmental Sciences 20(6): 711-719. https://doi.org/10.5322/JES.2011.20.6.711
  27. Servais, P., G. Billen and M.C. Hascoet. 1987. Determination of the biodegradable fraction of dissolved organic matter in waters. Water Research 21: 445-450. https://doi.org/10.1016/0043-1354(87)90192-8
  28. Shin, J.K., J.L. Cho, S.J. Hwang, K.J. Cho. 2000. Eutrophication and water pollution chracteristics of the Kyongan Stream to paltang reservoir. Korean Journal of Limnology 33(4): 387-394.
  29. Thurman, E.M. 1985. Organic geochemistry of natural water, Dordrecht, The Netherland.