Journal of Powder Materials (한국분말재료학회지)

The Korean Powder Metallurgy & Materials Institute (한국분말재료학회 (*구 분말야금학회))
권호 표지
DOI QR코드

DOI QR Code

Synthesis of YAG:Ce3+ Phosphor Powders by Polymer Solution Route and Alumina Seed Application

폴리머용액법 및 알루미나 seed를 도입한 YAG:Ce3+ 형광체 분말 합성

  • Kim, Yong-Hyeon (Department of Advanced Materials Science and Engineering, Mokpo National University) ;
  • Lee, Sang-Jin (Department of Advanced Materials Science and Engineering, Mokpo National University)
  • 김용현 (국립목포대학교 신소재공학과) ;
  • 이상진 (국립목포대학교 신소재공학과)
  • Received : 2013.01.23
  • Accepted : 2013.02.25
  • Published : 2013.02.28
Download PDF
⟨ Previous Next ⟩

Abstract

$YAG:Ce^{3+}$ phosphor powders were synthesized using a $Al_2O_3$ seed (average particle size: 5 ${\mu}m$) by the polymer solution route. PVA solution was added to the sol precursors consisting of the seed powder and metal nitrate salts for homogeneous mixing in atomic scale. All dried precursor gels were calcined at $500^{\circ}C$ and then heated at $1400^{\circ}C{\sim}1500^{\circ}C$ in $N_2/H_2$ atmosphere. The final powders were characterized by using XRD, SEM, PSA, PL and PKG test. All synthesized powders were crystallized to YAG phase without intermediate phases of YAM or YAP. The phosphor properties and morphologies of the synthesized powders were strongly dependent on the PVA content. Finally, the synthesized $YAG:Ce^{3+}$ phosphor powder heated at $1500^{\circ}C$, which is prepared from 12:1 PVA content and has an average particle size of 15 ${\mu}m$, showed similar phosphor properties to a commercial phosphor powder.

Keywords

References

  1. H. G. Jung, G. H. Hwang, K. Y. Lim, Y. H. Lee and S. G. Kang: J. Kor. Powder. Metall. Inst., 13 (2006) 243. https://doi.org/10.4150/KPMI.2006.13.4.243
  2. Y. Pan, M. Wu and Q. Su: Mater. Sci. Eng. B., 106 (2004) 251. https://doi.org/10.1016/j.mseb.2003.09.031
  3. X. Li, H. Liu, J. Wang, H. Cui and F. Han: Mater, Res. Bull., 39 (2004) 1923. https://doi.org/10.1016/j.materresbull.2004.05.013
  4. J. Zhou, F. Zhao, X. Wang, Z. Li, Y. Zhang and I. Yang: J. Luminescence., 119-120 (2006) 237. https://doi.org/10.1016/j.jlumin.2005.12.036
  5. Y. C. Kang, I. W. Lenggoro, S. B. Park and K. Okuyama: J. Phy. Chem. Solids., 60 (1999) 185.
  6. S. K. Lee and H. W. Choi: J. Kor. Institute of Electrical and Electronic Mater. Eng., 20 (2007) 536.
  7. C. H. Lu, W. T. Hsu, W. T. J. Dhanaraj and R. Jagannathan: J. Eur. Ceram. Soc., 24 (2004) 3723. https://doi.org/10.1016/j.jeurceramsoc.2003.12.009
  8. T. M. Chen, S. C. Chen and C. J. Yu: J. Solid State Chem., 144 (1999) 437. https://doi.org/10.1006/jssc.1999.8202
  9. H. J. Lee, S. K. Hong, D. S. Jung, Y. C. Kang and K. Y. Jung: Kor. Chem. Eng. Res., 43 (2005) 407.
  10. M. Suarez, A. Fernandez, J. L. Menendez and R. Torrecillas: J. Alloy. Comp., 493 (2010) 391. https://doi.org/10.1016/j.jallcom.2009.12.108
  11. M. L. Saladino, G. Nasillo, D. C. Martino and E. Caponetti: J. Alloy. Comp., 491 (2010) 737. https://doi.org/10.1016/j.jallcom.2009.11.054
  12. Y. Li, J. Zhang, Q. Xiao and R. Zeng: Mater. Lett., 62 (2008) 3787. https://doi.org/10.1016/j.matlet.2008.03.061
  13. D. Haranath, H. Chande, P. Shama and S. Sigh: Appl. Phys. Lett., 89 (2006) 173118. https://doi.org/10.1063/1.2367657
  14. J. Li, T. Ikegami, J. Lee, M. Toshyuki and Y. Yoshiyuk: J. Eur. Ceram. Soc., 20 (2000) 2395. https://doi.org/10.1016/S0955-2219(00)00116-3
  15. T. Ogi, A. B. D. Nandiyanto, W. N. Wang, F. Iskandar and K. Okuyama: Chem. Eng. J., 210 (2012) 461. https://doi.org/10.1016/j.cej.2012.09.033
  16. M. A. Gulgun, M. H. Nguyen and W. M. Kriven: J. Am. Ceram. Soc., 77 (1994) 531. https://doi.org/10.1111/j.1151-2916.1994.tb07026.x
  17. S. J. Lee, M. D. Biegalski and W. M. Kriven: J. Mater. Res., 14 (1999) 3001. https://doi.org/10.1557/JMR.1999.0403
  18. M. Harada and M. Goto: J. Alloy, Comp., 408-412 (2005) 1193.
  19. S. L. Lee and J. E. Park: J. Kor. Powder Metall. Inst., 18 (2011) 35. https://doi.org/10.4150/KPMI.2011.18.1.035
  20. S. J. Lee and C. H. Jung: J. Nonosci. Nanotechnol., 12 (2012) 800. https://doi.org/10.1166/jnn.2012.5352

Cited by

  1. Phosphor Powders Prepared by a Solid-liquid Hybrid Route vol.51, pp.5, 2014, https://doi.org/10.4191/kcers.2014.51.5.424