Journal of the Korean Physical Society

Korean Physical Society (한국물리학회)
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Effect of Lanthanum Doping on the Structural, Ferroelectric, and Strain Properties of $Bi_{1/2}(Na_{0.82}K_{0.18})_{1/2}TiO_3$ Lead-free Ceramics

  • Dinh, Thi Hinh (School of Materials Science and Engineering, University of Ulsan) ;
  • Lee, Hyun-Young (School of Materials Science and Engineering, University of Ulsan) ;
  • Yoon, Chang-Ho (School of Materials Science and Engineering, University of Ulsan) ;
  • Malik, Rizwan Ahmed (School of Materials Science and Engineering, University of Ulsan) ;
  • Kong, Young-Min (School of Materials Science and Engineering, University of Ulsan) ;
  • Lee, Jae-Shin (School of Materials Science and Engineering, University of Ulsan) ;
  • Tran, Vu Diem Ngoc (School of Materials Science and Technology, Hanoi University of Science and Technology)
  • Received : 2012.10.08
  • Accepted : 2013.01.28
  • Published : 2013.04.15
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Abstract

To clarify the effect of A-site donor doping on the phase transition and the strain enhancement, we investigated the crystal structure, as well as the piezoelectric, ferroelectric and electric-field-induced strain (EFIS) properties of La-doped $Bi_{1/2}(Na_{0.82}K_{0.18})_{1/2}TiO_3$ (BNKT) ceramics. Similarly to our previous studies on BNKT doped with B-site donors such as Nb and Ta, La doping was found to induce a ferroelectric-to-nonpolar (FE-NP) phase transition, leading to a large enhancement in EFIS just after the transition. The result provides strong evidence that a close relationship exists between the Goldschumidt's tolerance factor and the FE-NP transition in BNKT, which has been observed in B-site-donor or isovalent impurity-doped BNKT.

Keywords

References

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