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Electrospinning Fabrication of Poly(vinyl alcohol)/Pullulan/TiO2 Nanofibers

전기방사를 이용한 Poly(vinyl alcohol)/Pullulan/TiO2 나노부직포의 제조

  • Yang, Seong Baek (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University) ;
  • Choi, Woo Seok (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University) ;
  • Hyun, Jae Min (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University) ;
  • Shin, Jae Cheon (Pohang Center for Evaluation of Biomaterials) ;
  • Choi, Jin Hyun (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University) ;
  • Yeum, Jeong Hyun (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University)
  • 양성백 (경북대학교 기능물질공학과) ;
  • 최우석 (경북대학교 기능물질공학과) ;
  • 현재민 (경북대학교 기능물질공학과) ;
  • 신재천 (포항테크노파크 바이오정보지원센터) ;
  • 최진현 (경북대학교 기능물질공학과) ;
  • 염정현 (경북대학교 기능물질공학과)
  • Received : 2014.06.30
  • Accepted : 2014.09.16
  • Published : 2014.09.27

Abstract

Poly(vinyl alcohol)(PVA)/pullulan/titanium dioxide($TiO_2$) composite nanofibers were produced at different $TiO_2$ concentrations(1 and 3 wt.%) using the electrospinning method. The parameters of electrospinning including polymer contents, voltage and tip-to-collector distance(TCD) were optimized for fabrication process. The study showed that the best condition to make PVA/pullulan nanofiber and effect of $TiO_2$ nanoparticles. The PVA/pullulan/$TiO_2$ nanofibers were characterized by scanning electron microscope(SEM), transmission electron microscope(TEM), Thermogravimetric analysis (TGA) and X-ray diffraction(XRD).

Keywords

References

  1. W. Wu, T. He, J. Chen, X. Zhang, and Y. Chen, Study on in situ Preparation of Nano Calcium Carbonate/PMMA Composite Particles, Mater. Lett, 60(19), 2410(2006). https://doi.org/10.1016/j.matlet.2005.03.077
  2. M. Okamoto, S. Morita, H. Taguchi, Y. H. Kim, T. Kotaka, and H. Tateyama, Synthesis and Structure of Smectic Clay/poly(methylmethaacrylate) and Clay/polystyrene Nanocomposites via in situ Intercalative Polymerization, Polymer, 41(10), 3887 (2000). https://doi.org/10.1016/S0032-3861(99)00655-2
  3. J. Ramos, A. Millan, and F. Palacio, Production of Magnetic Nanoparticles in a Polyvinyl Pyridine Matrix, Polymer, 41(24), 8461(2000). https://doi.org/10.1016/S0032-3861(00)00272-X
  4. Z. K. Zhu, J. Yin, F. Cao, X. Y. Shang, and Q. H. Lu, Photosensative Polyimide/silica Hybrids, Adv. Mater, 12(14), 1055(2000). https://doi.org/10.1002/1521-4095(200007)12:14<1055::AID-ADMA1055>3.0.CO;2-#
  5. M. Mukherjee, A. Datta, and D. Chakravorty, Electrical Resistivity of Nanocrystalline PbS Grown in a Polymer Matrix, Appl. Phy. Lett, 64(9), 1159(1994). https://doi.org/10.1063/1.110838
  6. K. Lee and S. Lee, Fabrication and Evaluation of Electrospun Nanocomposite Fibers for the Development of UV-protective Textile Materials, J. Korean Soc. Clothing and Textiles, 34(11), 1767(2010). https://doi.org/10.5850/JKSCT.2010.34.11.1767
  7. S. C. Lee, H. Y. Kim, D. R. Lee, D. Bin, and S. J. Park, Morphological Characteristics of Electrospun Poly(vinyl alcohol) Nonwoven, J. Korean Fiber Society, 39(3), 316(2002).
  8. I. K. Kim and J. H. Yeum, Electrospinning Fabrication and Characterization of Poly(vinyl alcohol)/Waterborne Polyurethane/Montmorillonite Nanocomposite Nanofibers, Polymer(Korea), 35(6), 553(2011).
  9. J. H. Park, M. R. Karim, I. K. Kim, I. W. Cheong, J. W. Kim, D. G. Bae, J. W. Cho, and J. H. Yeum, Electrospinning Fabrication and Characterization of Poly(vinyl alcohol)/Montmorillonite/ Silver Hybrid Nanofibers for Antibacterial Applications, Colloid. Polym. Sci., 288(1), 115(2010). https://doi.org/10.1007/s00396-009-2147-4
  10. H. J. Jin, J. Chen, V. Karageorgiou, V. G. H. Altman, and D. L. Kaplan, Human Bone Marrow Stromal Cell Responses on Electrospun Silk Fibron Mats, Biomaterials, 25(6), 1039(2004). https://doi.org/10.1016/S0142-9612(03)00609-4
  11. C. J. Israilides, A. Smith, J. E. Harthill, C. Barnett, G. Bambalov, and B. Scanlon, Pullulan Content of the Ethanol Recipitate from Fermented Agro-industrial Wastes, Appl. Microbiol. Biot., 49(5), 613(1998). https://doi.org/10.1007/s002530051222
  12. T. D. Leathers, Biotechnological Production and Applications of Pullulan, Appl. Microbiol. Biot., 62(5), 468(2003). https://doi.org/10.1007/s00253-003-1386-4
  13. R. Schuster, E. Wenzig, and A. Mersmann, Production of the Fungal Exopolysaccharide Pullulan by Batch-wise and Continuous Fermentation, Appl. Microbiol. Biot., 39(2), 155(1993).
  14. M. S. Islam, J. H. Yeum, and A. K. Das, Effect of Pullulan/poly(vinyl alcohol) Blend System on the Montmorillonite Structure with Property Characterization of Electrospun Pullulan/poly(vinyl alcohol)/montmorillonite Nanofibers, J. Colloid Interface Sci., 368(1), 273(2012). https://doi.org/10.1016/j.jcis.2011.11.007
  15. N. T. B. Linh, K. H. Lee, and B. T. Lee, Fabrication of Photocatalytic PVA-$TiO_{2}$ Nanofibrous Hybrid Membrane using the Electrospinning Method, J. Mater. Sci., 46(17), 5615(2011). https://doi.org/10.1007/s10853-011-5511-y
  16. B. Y. Kadem, Study of Some Mechanical Properties of PVA/$TiO_{2}$ Composite by Ultrasonic Technique, International J. of Science and Technology, 1(5), 183(2011).
  17. K. R. Bae, C. H. Ko, Y. Park, Y. Kim, J. S. Bae, J. H. Yeum, I. S. Kim, and W. J. Lee, Structure Control of Nanocrystalline $TiO_{2}$ for the Dye-sensitized Solar Cell Application, Curr. Appl. Phys., 10(3), 406(2010). https://doi.org/10.1016/j.cap.2010.02.012
  18. R. Venckatesh, K. Balachandaran, and R. Sivaraj, Synthesis and Characterization of Nano $TiO_{2}$-$SiO_{2}$: PVA Composite - a Novel Route, International Nano Letters, 2(15), 1(2012). https://doi.org/10.1186/2228-5326-2-1
  19. B. C. Ji, S. S. Bae, M. M. Rabbani, and J. H. Yeum, Photocatalytic Activity of Electrospun PAN/$TiO_{2}$ Nanofibers in Dye Photodecomposition, Textile Coloration and Finishing(J. of Korea Soc. Dyers and Finishers), 25(2), 94(2013). https://doi.org/10.5764/TCF.2013.25.2.94
  20. N. T. B. Linh, K. H. Lee, and B. T. Lee, Fabrication of Photocatalytic PVA-$TiO_{2}$ Nano- Fibrous Hybrid Membrane using the Electrospinning Method, J. Mater. Sci., 46(17), 5615(2011). https://doi.org/10.1007/s10853-011-5511-y
  21. J. Y. Zhang, I. W. Boyd, B. J. O'Sullivan, P. K. Hurley, P. V. Kelly, and J. P. Senateur, Nanocrystalline $TiO_{2}$ Films Studied by Optical, XRD and FTIR Spectroscopy, J. Non-Crystaline Solids, 303(1), 134(2002). https://doi.org/10.1016/S0022-3093(02)00973-0
  22. Y. H. Kim, K. B. Do, J. Y. Choi, M. M. Rabbani, S. I. Han, and J. H. Yeum, Electrospinning Fabrication of Poly(vinyl alcohol)/$TiO_{2}$ Nanofibers, Textile Coloration and Finishing(J. of Korea Soc. Dyers and Finishers), 25(2), 118(2013). https://doi.org/10.5764/TCF.2013.25.2.118

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