Journal of Industrial and Engineering Chemistry

  • Volume 23
  • /
  • Pages.251-256
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  • 2015
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  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Effects of pore structure and PEI impregnation on carbon dioxide adsorption by ZSM-5 zeolites

  • Lee, Chang Hun (Department of Chemical and Biological Engineering, Korea University) ;
  • Hyeon, Dong Hun (Department of Chemical and Biological Engineering, Korea University) ;
  • Jung, Hyunchul (Department of Chemical and Biological Engineering, Korea University) ;
  • Chung, Wonkeun (Department of Chemical and Biological Engineering, Korea University) ;
  • Jo, Dong Hyun (Department of Chemical and Biological Engineering, Korea University) ;
  • Shin, Dong Kun (Department of Chemical and Biological Engineering, Korea University) ;
  • Kim, Sung Hyun (Department of Chemical and Biological Engineering, Korea University)
  • Received : 2014.02.03
  • Accepted : 2014.08.04
  • Published : 2015.05.25
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Abstract

The ZSM-5-type zeolites were prepared using three types of structure directing agent to investigate the effect of pore structure and PEI impregnation on the $CO_2$ adsorption capacity. The $CO_2$ capacity was primarily affected by the number of the adsorption site and the volume for trapping $CO_2$. $CO_2$ was well adsorbed inside the micropore with stronger electric field. The $CO_2$ capacity increased with increasing amounts of impregnated PEI until PEI loading exceeded the total pore volume, because PEI predominantly occupied the pores of ZSM-5. The ZSM-5 with large surface area and total pore volume was the most favorable for amine-impregnated ZSM-5.

Keywords

Acknowledgement

Supported by : Korea CCS R&D Center (KCRC)

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