Journal of Industrial and Engineering Chemistry

  • Volume 41
  • /
  • Pages.1-9
  • /
  • 2016
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  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Electrochemical and structural properties of lithium battery anode materials by using a molecular weight controlled pitch derived from petroleum residue

  • Kim, Baek-Hwan (C-Industry Incubation Center, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Kim, Ji-Hong (C-Industry Incubation Center, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Kim, Jong-Gu (C-Industry Incubation Center, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Bae, Min-Jeong (Department of Applied Chemistry and Biological Engineering, Chungnam National University) ;
  • Im, Ji Sun (C-Industry Incubation Center, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Lee, Chul Wee (C-Industry Incubation Center, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Kim, Seok (Department of Chemical and Biomolecular Engineering, Pusan National University)
  • Received : 2016.05.23
  • Accepted : 2016.07.02
  • Published : 2016.09.25
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Abstract

The petroleum pitch derived from pyrolyzed fuel oil (PFO) was prepared and modified using the solvent extraction method to study the effect of the pitch fraction on electrochemical and structural behaviors. The modified pitches were Hexane-insoluble, Toluene-insoluble and NMP-insoluble pitches. To confirm the structural characteristic parameters such as ($L_a$, $d_{002}$, $I_G/I_D$ and true density), X-ray diffraction, Raman spectroscopy and true density measurements were conducted. Electrochemical properties were measured using the coin cell test. Based on the electrochemical properties and structural analyses, the schematic design of the micro-carbon domain was proposed, and the role of each fraction (hexane-soluble, hexane-soluble and toluene-insoluble, Toluene-insoluble and NMPI-insoluble and NMPI fractions) was studied. Each fraction affected the coke during carbonization, and the hexane-soluble fraction and hexane-soluble and toluene-insoluble fraction affected the initial efficiency and $Li^+$ ion diffusion resistance.

Keywords

Acknowledgement

Supported by : Ministry of Science, ICT and Future Planning of Korea

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