DOI QR코드

DOI QR Code

Analysis of Poly Aromatic Hydrocarbon (PAH) Pollutants Originated from Local Road Dust by Spacial Measurements

공간 측정에 의한 도로변 발생 다환방향족탄화수소 연구

  • Park, Da-Jeong (Department of Environmental Engineering, Mokpo National University) ;
  • Cho, In-Hwan (Department of Environmental Engineering, Mokpo National University) ;
  • Lee, Kwang-Yul (School of Environmental Science and Engineering, Gwangju Institute of Science and Technology) ;
  • Park, Kihong (School of Environmental Science and Engineering, Gwangju Institute of Science and Technology) ;
  • Lee, Yeong-Jae (National Institute of Environmental Research, Air Quality Research Division) ;
  • Ahn, Joon-Young (National Institute of Environmental Research, Air Quality Research Division) ;
  • Bae, Min-Suk (Department of Environmental Engineering, Mokpo National University)
  • Received : 2016.03.07
  • Accepted : 2016.05.13
  • Published : 2016.06.30

Abstract

Understanding sources and contributions of $PM_{2.5}$ mass and particulate PAHs from traffic-related pollution can provide valuable information for alleviating air contamination from car emissions in urban areas. Two sampling sites at the Gwangju Institute of Science and Technology (GIST, $35.228^{\circ}N$, $126.843^{\circ}E$) and National institute of environmental research NamBu Supersite (NNBS, $35.226^{\circ}N$, $126.848^{\circ}E$) were selected for comprehensive road-oriented-PM investigations. Continuous measurements from optical particle sizer (OPS) and optical particle counter (OPC) with 24 hr integrated filter based samplers for organic carbon, water soluble organic carbon, and Poly Aromatic Hydrocarbons (PAHs) were conducted during Nov. 3 through 22 in 2014. As a result, $PM_{2.5}$ mass concentrations using OPC and OPS in NNBS presented about twice higher than in GIST due to road dust impacts based on wind direction analysis. In addition, ratios of elemental carbon (EC) to organic carbon (OC) and water insoluble organic carbon (WIOC) to organic carbon (OC) supported an additional evidence of the primary pollutant contributions oriented from road dust. PAHs related to 5 rings such as benzo(e&a)pyrene indicates higher associations.

Keywords

References

  1. Bae, M.S., D.J. Park, J.H. Lee, J.Y. Ahn, and Y.J. Lee (2016) Source Analysis of Size Distribution and Density Estimation in $PM_{2.5}$ - Part II, Journal of Korean Society for Atmospheric Environment, 32(2), 158-166. (in Korean with English Abstract) https://doi.org/10.5572/KOSAE.2016.32.2.158
  2. Bae, M.S., J. Schauer, J. DeMinter, J. Turner, D. Smith, and R. Cary (2004) Validation of a Semi-Continuous Instrument for Elemental Carbon and Organic Car bon Using a Thermal-Optical Method, Atmospheric Environment, 38, 2885-2893. https://doi.org/10.1016/j.atmosenv.2004.02.027
  3. Bae, M.S., J.Y. Lee, Y.P. Kim, M.H. Oak, J.S. Shin, K.Y. Lee, H.H. Lee, S.Y. Lee, and Y.J. Kim (2012) Analytical Methods of Levoglucosan, a Tracer for Cellulose in Biomass Burning, by Four Different Techniques, Asian Journal of Atmospheric Environment, 6(1), 53-66. https://doi.org/10.5572/ajae.2012.6.1.053
  4. Berger, J. and B. Denby (2011) A generalised model for traffic induced road dust emissions. Model description and evaluation, Atmospheric Environment, 45(22), 3692-3703. https://doi.org/10.1016/j.atmosenv.2011.04.021
  5. Goel, R. and S.K. Guttikunda (2015) Evolution of on-road vehicle exhaust emissions in Delhi, Atmospheric Environment, 105, 78-90. https://doi.org/10.1016/j.atmosenv.2015.01.045
  6. Hallquist, M., J. Wenger, U. Baltensperger, Y. Rudich, D. Simpson, M. Claeys, J. Dommen, N. Donahue, C. George, A. Goldstein, J. Hamilton, H. Herrmann, T. Hoffmann, Y. Iinuma, M. Jang, M. Jenkin, J. Jimenez, A. Kiendler-Scharr, W. Maenhaut, G. McFiggans, T. Mentel, A. Monod, A. Prevot, J. Seinfeld, J. Surratt, R. Szmigielski, and J. Wildt (2009) The formation, properties and impact of secondary organic aerosol: current and emerging issues, Atmospheric Chemistry and Physics, 9(14), 5155-5236. https://doi.org/10.5194/acp-9-5155-2009
  7. Jamhari, A., M. Sahani, M. Latif, K. Chan, H. Tan, M. Khan, and N. Tahir (2014) Concentration and source identification of polycyclic aromatic hydrocarbons (PAHs) in $PM_{10}$ of urban, industrial and semi-urban areas in Malaysia, Atmospheric Environment, 86, 16-27. https://doi.org/10.1016/j.atmosenv.2013.12.019
  8. Jedynska, A., G. Hoek, M. Eeftens, J. Cyrys, M. Keuken, C. Ampe, R. Beelen, G. Cesaroni, F. Forastiere, M. Cirach, K. Hoogh, A. Nazelle, C. Madsen, C. Declercq, K. Eriksen, K. Katsouyanni, H. Akhlaghi, T. Lanki, K. Meliefste, M. Nieuwenhuijsen, M. Oldenwening, A. Pennanen, O. Raaschou-Nielsen, B. Brunekreef, and I. Kooter (2014) Spatial variations of PAH, hopanes/steranes and EC/OC concentrations within and between European study areas, Atmospheric Environment, 87, 239-248. https://doi.org/10.1016/j.atmosenv.2014.01.026
  9. Khairy, M. and R. Lohmann (2013) Source apportionment and risk assessment of polycyclic aromatic hydrocarbons in the atmospheric environment of Alexandria, Egypt, Chemosphere, 91, 895-903. https://doi.org/10.1016/j.chemosphere.2013.02.018
  10. Lee, J., B. Jeong, D.J. Park, and M.S. Bae (2015) A Study of Black Carbon Measurement in Metropolitan Area and Suburban Area of the Korean Peninsula Performed during Pre KORea-US Air Quality Study (KORUS-AQ) Campaign, Journal of Korean Society for Atmospheric Environment, 31(5), 472-481. (in Korean with English Abstract) https://doi.org/10.5572/KOSAE.2015.31.5.472
  11. Li, X., S. Wang, L. Duan, J. Hao, and Y. Nie (2009) Carbonaceous Aerosol Emissions from Household Biofuel Combustion in China, Environmental Science and Technology, 43(15), 6076-6081. https://doi.org/10.1021/es803330j
  12. Liu, W., W. Xie, Z. Zhao, W. Pan, and J. Riley (2000) Investigation of Polycyclic Aromatic Hydrocarbons in Fly Ash from Fluidized Bed Combustion Systems, Environmental Science and Technology, 34(11), 2273-2279. https://doi.org/10.1021/es990944s
  13. Liu, Y., L. Chen, J. Zhao, Y. Wei, Z. Pan, X. Meng, Q. Huang, and W. Li (2010) Polycyclic aromatic hydrocarbons in the surface soil of Shanghai, China: concentrations, distribution and sources, Organic Geochemistry, 41, 355-362. https://doi.org/10.1016/j.orggeochem.2009.12.009
  14. Park, D.J., K.Y. Lee, K. Park, and M.S. Bae (2016) Diurnal Size Distributions of Black Carbon by comparison of Optical Particulate Measurements - Part I, Journal of Korean Society for Atmospheric Environment, 32(1), 1-8. (in Korean with English Abstract) https://doi.org/10.5572/KOSAE.2016.32.1.001
  15. Park, D.J., Y.J. Han, J.Y. Lee, K.Y. Lee, I.H. Cho, E.H. Park, S.M. Yi, and M.S. Bae (2015) Source Profile of Road Dust for Statistical Apportionment Modeling in Seoul, Journal of Korean Society for Atmospheric Environment, 31(2), 105-117. (in Korean with English Abstract) https://doi.org/10.5572/KOSAE.2015.31.2.105
  16. Schauer, J., J. Kleeman, R. Cass, and R. Simoneit (1999) Measurement of Emissions from Air Pollution Sources. 1-5, Environmental Science and Technology, 36(6), 1169-1180. https://doi.org/10.1021/es0108077
  17. Schauer, J., J. Kleeman, R. Cass, and R. Simoneit (2001) Measurement of Emissions from Air Pollution Sources. 3. C1-C29 Organic Compounds from Fireplace Combustion of Wood, Environmental Science and Technology, 35(9), 1716-1728. https://doi.org/10.1021/es001331e
  18. Schmid, M., S. Zimmermann, H. Krug, and B. Sures (2007) Influence of platinum, palladium and rhodium as compared with cadmium, nickel and chromium on cell viability and oxidative stress in human bronchial epithelial cells, Environment International, 33(3), 385-390. https://doi.org/10.1016/j.envint.2006.12.003
  19. Zhang, H., E. Eddings, and A. Sarofim (2008) Pollutant emissions from gasoline combustion. 1. Dependence on fuel structural functionalities, Environmental Science and Technology, 42(15), 5615-5621. https://doi.org/10.1021/es702536e