Journal of Industrial and Engineering Chemistry

  • Volume 36
  • /
  • Pages.293-297
  • /
  • 2016
  • /
  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Synthesis and its characterization of pitch from pyrolyzed fuel oil (PFO)

  • Kim, Jong Gu (Division of Green Chemistry & Engineering Research, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Kim, Ji Hong (Division of Green Chemistry & Engineering Research, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Song, Byung-Jin (Division of Green Chemistry & Engineering Research, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Lee, Chul Wee (Division of Green Chemistry & Engineering Research, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Im, Ji Sun (Division of Green Chemistry & Engineering Research, Korea Research Institute of Chemical Technology (KRICT))
  • Received : 2016.01.07
  • Accepted : 2016.02.16
  • Published : 2016.04.25
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Abstract

Pitch synthesis from pyrolyzed fuel oil (PFO) was conducted to understand the empirical synthesis tendency as a function of reaction temperature. Additionally, the chemical and physical characteristics of PFO and produced pitch are identified using X-ray diffraction analysis, thermogravimetric analysis, softening point analysis, and matrix-assisted laser desorption/ionization-time of flight (MALDI-TOF) analysis. The produced pitch exhibited an enhanced stacking height ($L_C$) value and C/H ratio, which is related to the formation of graphitic structure, according to the increased reaction temperature. The carbon residue yield obtained at $900^{\circ}C$ showed a gradually increased value of up to 42.58% in the sample synthesized at the temperature of $410^{\circ}C$, depending on the increased reaction temperature. The molecular weight distribution of the produced pitches exhibited noticeable variation during the thermal reaction via MALDI-TOF analysis. The variation of the molecular weight fraction is assumed based on the pitch synthesis mechanism, e.g., polymerization, condensation and cracking reaction.

Keywords

Acknowledgement

Grant : Development of preparation technology in petroleum-based pitch and needle/isotropic cokes

Supported by : Ministry of Trade, Industry & Energy (MI)

References

  1. I. Mochida, Y. Korea, C.H. Ku, F. Watanabe, Y. Sakai, Carbon 38 (2000) 305. https://doi.org/10.1016/S0008-6223(99)00176-1
  2. H. Song, X. Chen, X. Chen, S. Xhang, H. Li, Carbon 41 (2003) 3037. https://doi.org/10.1016/S0008-6223(03)00430-5
  3. I. Mochida, K. Shimizu, Y. Korai, Y. Sakai, S. Fujiyama, H. Toshima, T. Hono, Carbon 30 (1992) 55. https://doi.org/10.1016/0008-6223(92)90106-7
  4. J.G. Kim, J.H. Kim, B.J. Song, Y.P. Jeon, C.W. Lee, Y.S. Lee, J.S. Im, Fuel 167 (2016) 25. https://doi.org/10.1016/j.fuel.2015.11.050
  5. S. Chand, J. Mater. Sci. 35 (2000) 1303. https://doi.org/10.1023/A:1004780301489
  6. K. Subhash, S. Manoj, Carbon Lett. 16 (2015) 171. https://doi.org/10.5714/CL.2015.16.3.171
  7. J. Zhu, S.W. Park, H.I. Joh, H.C. Kim, S. Lee, Carbon Lett. 14 (2013) 94. https://doi.org/10.5714/CL.2013.14.2.094
  8. C.J. Ahn, I.S. Park, H.J. Joo, Carbon Lett. 11 (2010) 304. https://doi.org/10.5714/CL.2010.11.4.304
  9. X. Cheng, Q. Zha, X. Li, X. Yang, Fuel Process. Technol. 89 (2008) 1436. https://doi.org/10.1016/j.fuproc.2008.07.003
  10. R. Moriyama, H. Kumagaia, J. Hayashia, C. Yamaguchi, J. Mondorib, H. Matsui, T. Chiba, Carbon 38 (2000) . https://doi.org/10.1016/S0008-6223(99)00152-9
  11. S. Eser, G. Wang, Energy Fuels 21 (2007) 3573. https://doi.org/10.1021/ef060541v
  12. B.J. Kim, Y. Eom, O. Kato, J. Miyawaki, B.C. Kim, I. Mochida, S.H. Yoon, Carbon 77 (2014) 747. https://doi.org/10.1016/j.carbon.2014.05.079
  13. I. Mochida, H. Toshima, Y. Korai, T. Varga, J. Mater. Sci. 25 (1990) 3484. https://doi.org/10.1007/BF00575374
  14. P.P. Li, J.M. Xiong, M.L. Ge, J.C. Sun, W. Zhang, Y.Y. Song, Fuel Process. Technol. 140 (2015) 231. https://doi.org/10.1016/j.fuproc.2015.09.011
  15. H.Y. Kim, Monthly Energy Statistics, Korea Energy Economics Institute, 2015.
  16. W.F. Edwards, L. Jin, M.C. Thies, Carbon 41 (2003) 2761. https://doi.org/10.1016/S0008-6223(03)00386-5
  17. W.A. Burgess, M.C. Thies, Carbon 49 (2011) 636. https://doi.org/10.1016/j.carbon.2010.10.011
  18. B. Manoj, A.G. Kunjomana, Int. J. Electrochem. Sci. 7 (2012) 3127.
  19. M. Dumont, G. Chollon, M.A. Dourges, R. Pailler, X. Bourrat, R. Naslain, J.L. Bruneel, M. Couzi, Carbon 40 (2002) 1475. https://doi.org/10.1016/S0008-6223(01)00320-7
  20. M. Perez, M. Granda, R. Garcia, R. Santamaria, E. Romero, R. Menendez, J. Anal. Appl. Pyrolysis 63 (2002) 223. https://doi.org/10.1016/S0165-2370(01)00156-5
  21. L.M. Manocha, M. Patel, S.M. Manocha, C. Vix-Guterl, P. Ehrburger, Carbon 39 (2001) 663. https://doi.org/10.1016/S0008-6223(00)00178-0

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