DOI QR코드

DOI QR Code

미세피치 플립칩 패키지 구현을 위한 EPIG 표면처리에서의 무전해 팔라듐 피막특성 및 확산에 관한 연구

A Study on Electroless Palladium Layer Characteristics and Its Diffusion in the Electroless Palladium Immersion Gold (EPIG) Surface Treatment for Fine Pitch Flip Chip Package

  • Hur, Jin-Young (Surface R&D Group, Korea institute of industrial technology) ;
  • Lee, Chang-Myeon (Surface R&D Group, Korea institute of industrial technology) ;
  • Koo, Seok-Bon (Surface R&D Group, Korea institute of industrial technology) ;
  • Jeon, Jun-Mi (Surface R&D Group, Korea institute of industrial technology) ;
  • Lee, Hong-Kee (Surface R&D Group, Korea institute of industrial technology)
  • 투고 : 2017.06.27
  • 심사 : 2017.06.28
  • 발행 : 2017.06.30

초록

EPIG (Electroless Pd/immersion Au) process was studied to replace ENIG (electroless Ni/immersion Au) and ENEPIG (electroless Ni/electroless Pd/immersion Au) processes for bump surface treatment used in high reliable flip chip packages. The palladium and gold layers formed by EPIG process were uniform with thickness of 125 nm and 34.5 nm, respectively. EPAG (Electroless Pd/autocatalytic Au) also produced even layers of palladium and gold with the thickness of 115 nm and 100 nm. TEM results exhibited that the gold layer in EPIG surface had crystalline structure while the palladium layer was amorphous one. After annealing at 250 nm, XPS analysis indicated that the palladium layer with thickness more than 22~33 nm could act as a diffusion barrier of copper interconnects. As a result of comparing the chip shear strength obtained from ENIG and EPIG surfaces, it was confirmed that the bonding strength was similar each other as 12.337 kg and 12.330 kg, respectively.

키워드

참고문헌

  1. R. Ramanauskas, et al., PCB failure analysis related to the ENIG black pad problem, J. circuit world, 39-3 (2013) 124-132.
  2. P. Snugovsky, et al., Electroless Ni/Immersion Au interconnects: Investigation of black pad in wire bonds and solder joints, J. Electron. Mater. 30 (2001) 1262-1270. https://doi.org/10.1007/s11664-001-0159-z
  3. Jin Yu, et al., A corrosion couple experiment reproducing the black pad phenomenon found after the electroless nickel immersion gold process, Scripta Mater. 63 (2010) 508-511. https://doi.org/10.1016/j.scriptamat.2010.05.015
  4. Y.S. Won, et al., The pH effect on black spots in surface finish: Electroless nickel immersion gold, Appl. Surf. Sci. 257 (2010) 56-61. https://doi.org/10.1016/j.apsusc.2010.06.033
  5. J.W. Yoon, et al., Flip-chip bonding technology and reliability of electronic packaging, J. KWJS, 25-2 (2007) 108-117.
  6. K.S. Choi, et al., Recent trends of flip chip bonding technology, Electronics and telecommunications trends, 28-5 (2013) 100-110
  7. R. Beica, Flip chip market and technology trends, EMPC, (2013) 1-4
  8. J. H. Lee, et al., TSV Interconnection Technology Using Solder Nanoparticles, J. KWJS, 29-3 (2011) 283.
  9. M. S. Kim, et al., Precise Joining Technology on Flexible Substrate by Using Micro-bumps, J. KWJS, 30-5 (2012) 395.
  10. C.K. Chung, et al., The critical oxide thickness for Pb-free reflow soldering on Cu substrate, Thin Solid Films 520 (2012) 5346-5352. https://doi.org/10.1016/j.tsf.2012.03.034
  11. K. Hannigan, et al., Corrosion of RoHS-Compliant surface finishes in corrosive mixed flowing gas environments, J. Electron. Mater. 41 (2012) 611-623. https://doi.org/10.1007/s11664-011-1799-2
  12. Y. Oda, et al, Study of suitable palladium and gold thickness in ENEPIG deposites for lead free soldering and gold wire bonding, 41st International Symposium microelectronics (2008).
  13. W.K. Choi, et al, Effect of Ni layer thickness and soldering time on intermetallic compound formation at the interface between molten Sn-3.5Ag and Ni/Cu substrate, J. Electron. Mater. 28 (1999) 1251-1255. https://doi.org/10.1007/s11664-999-0164-1
  14. M. Ozkok, Direct EP and Direct EPAG - Novel surface finishes for gold-, copper wire bonding and soldering applications, in Microsystems, Packaging, Assembly and Circuits Technology Conference (IMPACT), 7th International (2012) 178-182.
  15. Y. Kikukawa, Electroless Pd/Au plating directly on copper, J-STAGE, 66-11 (2015) 511-513.
  16. C.E. Ho et al, Surface & Coatings Technology, 303, (2016) 103-111. https://doi.org/10.1016/j.surfcoat.2016.03.070
  17. C.E. Ho, et al., Development and evaluation of direct deposition of Au/Pd(P) bilayers over Cu pads in soldering applications, J. Electron. Mater. 41 (2012) 3276-3283. https://doi.org/10.1007/s11664-012-2200-9
  18. C.E. Ho, et al., Interfacial reaction and mechanical characterization of Sn-Ag-Cu/Au/Pd(P)/Cu solder joints: thick Pd(P) deposition, J. Electron. Mater. 44 (2015) 568-580. https://doi.org/10.1007/s11664-014-3513-7
  19. K.H. Lee, Identification and prevention of Black Pad, SMTnet, (2013) 1-13.
  20. M. Oezkoek, et al., Benefits of pure palladium for ENEP and ENEPIG surface finishes, 3rd ESTC (2010) 1-6.
  21. C.R. Kao, et al., Amorphous Pd layer as a highly effective oxidation barrier for surface finish of electronic terminals, Corrosion Science, 83, (2014) 419-422. https://doi.org/10.1016/j.corsci.2014.02.006