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Optimum process and energy density analysis of canola oil biodiesel synthesis

  • Lee, Seung-Bum (Department of Chemical Engineering, Dankook University) ;
  • Han, Kyong-Ho (Department of Electronics and Electrical Engineering, Dankook University) ;
  • Lee, Jae-Dong (Division of Energy & Biological Engineering, Kyungwon University) ;
  • Hong, In-Kwon (Department of Chemical Engineering, Dankook University)
  • Received : 2010.02.01
  • Accepted : 2010.03.10
  • Published : 2010.11.25

Abstract

Biodiesel has been recommended as an environmentally benign alternative fuel because it emits a comparatively small amount of air pollutants. Biodiesel can be processed from canola oil, which has a low liquefaction temperature owing to its high unsaturated fatty acid content, which also limits its engine-clogging effects. In this study, optimum conditions such as the amount of methanol, the alkali catalyst, and the reaction temperature were determined for production of biodiesel from canola oil. A maximum biodiesel yield was shown at an oil/methanol mole ratio of 1:6. The optimum amount of catalyst was 1 wt% of potassium hydroxide. The biodiesel yield and the methyl ester content were high when the reaction temperature was $55^{\circ}C$. The consolute temperature for determining the maximum biodiesel yield was proposed in consideration of the boiling point of methanol. The energy density was analyzed for the final products of biodiesel in comparison to the raw canola oil and other plant oil based biodiesels.

Keywords

Acknowledgement

Supported by : Dankook University

References

  1. Z. Helwani, M.R. Othman, N. Aziz, J. Kim, Fuel Process. Technol. 90 (2009) 1502. https://doi.org/10.1016/j.fuproc.2009.07.016
  2. D.Y.C. Leung, X. Wu, M.K.H. Leung, Appl. Energy 87 (2009) 1083.
  3. D. Pimentel, Biofuels, Solar and Wind as Renewable Energy Systems, Springer, Colorado, 2008.
  4. M. Fangrui, A.H. Milford, Biosource Technol. 70 (1999) 1. https://doi.org/10.1016/S0960-8524(99)00025-5
  5. B.H. Uma, Y.S. Kim, J. Ind. Eng. Chem. 15 (1) (2009) 1. https://doi.org/10.2298/CICEQ0901001R
  6. S.J. Lee, E.Y. Kim, Korean J. Biotechnol. Bioeng. 17 (4) (2002) 396.
  7. M. Mittelbach, C. Remschmidt, Biodiesel-The Comprehensive Hanbook, M. Mittelbach, Graz, Austria, 2004.
  8. G.T. Jeong, D.H. Park, Appl. Biochem. Biotechnol. 668 (2006) 129.
  9. A. Demirbas, Energy Convers. Manage. 50 (2009) 14. https://doi.org/10.1016/j.enconman.2008.09.001
  10. K.W. Lee, J.X. Yu, J.H. Mei, L. Yan, Y.W. Kim, K.W. Chung, J. Ind. Eng. Chem. 13 (5) (2007) 799.
  11. G.T. Jeong, H.S. Yang, S.H. Park, D.H. Park, Korean J. Biotechnol. Bioeng. 22 (4) (2007) 222.
  12. W. Xie, X. Huang, H. Li, Biosource Technol. 98 (2007) 936. https://doi.org/10.1016/j.biortech.2006.04.003
  13. S.B. Lee, J.D. Lee, J. Korean Ind. Eng. Chem. 20 (5) (2009) 532.
  14. M.P. Dorado, E. Ballesteros, F.J. Lopez, M. Mittelbach, Energy Fuels 18 (1) (2004) 77. https://doi.org/10.1021/ef0340110
  15. M.W. Formo, Physical Properties of Fats and Fatty Acids; in Bailey's Industrial Oil and Fats, John Wiley & Sons, Inc., Toronto, Canada, 1979, 177.
  16. P. Benjumea, J. Agudelo, A. Agudelo, Fuel 87 (2008) 2069. https://doi.org/10.1016/j.fuel.2007.11.004
  17. G. Vincente, M. Martinez, J. Aracil, Biosource Technol. 98 (2006) 1754.
  18. G.T. Jung, D.H. Yoon, KSSB, Proceedings of Current Biotechnology and Bioengineering (XII), vol. 167, 2003.
  19. H. Nourredini, B.C. Teoh, L.D. Clements, J. Am. Oil Chem. Soc. 69 (1992) 1189. https://doi.org/10.1007/BF02637678
  20. G. Knothe, K.R. Steidley, Fuel 86 (2007) 2560. https://doi.org/10.1016/j.fuel.2007.02.006
  21. A. Demirbas, Fuel 77 (1998) 1117. https://doi.org/10.1016/S0016-2361(97)00289-5

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