Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지
DOI QR코드

DOI QR Code

Formation of Bioactive Ceramic Foams by Polymer Pyrolysis and Self-Blowing

고분자 열분해와 자가발포를 이용한 생체활성 다공체의 제조

  • Kwak, Dae-Hyun (School of Advanced Materials Science & Engineering, Sungkyunkwan University) ;
  • Kim, Jin-Ho (School of Advanced Materials Science & Engineering, Sungkyunkwan University) ;
  • Lee, Eun-Ju (School of Advanced Materials Science & Engineering, Sungkyunkwan University) ;
  • Kim, Deug-Joong (School of Advanced Materials Science & Engineering, Sungkyunkwan University)
  • 곽대현 (성균관대학교 신소재공학과) ;
  • 김진호 (성균관대학교 신소재공학과) ;
  • 이은주 (성균관대학교 신소재공학과) ;
  • 김득중 (성균관대학교 신소재공학과)
  • Received : 2011.08.17
  • Accepted : 2011.09.02
  • Published : 2011.09.30
Download PDF
⟨ Previous Next ⟩

Abstract

Formation and characterization of hydroxyapatite-based porous ceramics derived from polymer pyroysis were investigated. Polymer based process is chosen for preparing porous hydroxyapatite-based ceramics having a high mechanical strength. The hydroxyapatite-based porous ceramic was prepared by a self-blowing process of a polymethylsiloxane with filler and pyrolyzed at above $1000^{\circ}C$. Biphasic material consisted of hydroxyapatite and CaO has been prepared by solid state reaction from calcium hydroxide($Ca(OH)_2$) and calcium hydrogen phosphate dihydrate($CaHPO_4{\cdot}2H_2O$) as a filler material. The influence of filler content on mechanical properties was evaluated. The change of crystalline phase, microstructure and mechanical properties were investigated and discussed.

Keywords

References

  1. A. Balamurugan, S. Kannan, and S. Rajeswari, "Bioactive Sol-Gel Hydroxyapatite Surface for Biomedical Application In-Vitro Study," Trends Biomater. Artif. Organs, 16 [1] 18-20 (2002).
  2. P. Layroll, A. Ito, and T. Tateishi, "Sol-Gel Synthesis of Amorphous Calcium Phosphate and Sintering into Microporous Hydroxyapatite Bioceramics," J. Am. Ceram. Soc., 81 [6] 1421-28 (1998).
  3. D. Shi, G. Jaing, X. Wen, in: K. Khor, et al. (Eds.), "In Vitro Behavior of Hydroxyapatite Prepared by a Thermal Deposition Method, Processing and Fabrication of Advanced Materials VIII," pp. 117, World Scientific, Singapore, 2001.
  4. W. Suchanek and M. Yoshimura, "Processing and Properties Hydroxyapatite Based Biomaterials for Use as Hard Tissue Replacement Implants," J. Mater. Res., 13 94-117 (1998). https://doi.org/10.1557/JMR.1998.0015
  5. Leony Leon C. A., "New Perspectives in Mercury Porosimetry," Adv Colloid Interface Sci., 76-77 341-72 (1998). https://doi.org/10.1016/S0001-8686(98)00052-9
  6. I. M. Kwon, I. H. Song, Y. J. Park, J. W. Lee, H. S. Yun, and H. D. Kim "The Synthesis and Pore Property of Hydrogen Membranes Derived from Polysilazane as Inorganic Polymer," J. Kor. Cream. Soc., 46 [5] 462-66 (2009). https://doi.org/10.4191/KCERS.2009.46.5.462
  7. S. J. Hong, H. C. Ahn, and D. J. Kim, "Reaction Bonded $Si_3N_4$ from Si-Polysilazane Mixture," J. Kor. Cream. Soc., 47 [6] 572-77 (2010) https://doi.org/10.4191/KCERS.2010.47.6.572
  8. T. Gambayan-Roisman, M. Scheffler, P. Buhler, and P. Greil, "Processing of Ceramic Foam by Pyrolysis of Filler Containing Phenylmethyl Polysiloxane Precusor," Ceram. Trans., 108 121-30 (2000).
  9. T. Gembaryan-Roisman, M. Scheffler, T. Takahashi, P. Buhler, and P. Greil, "Formation and Properties of Poly(siloxane) Derived Ceramic Foam," pp.247-51 in Euromat 99, Vol. 12, Ceramics Processing, Reliability, Tribology and Wear. Edited by G. Muller, DGM, Frankfurt, 2000.
  10. J. Zeschky, T. Hofner, C. Arnold, R. Weibmann, D. Bahloul, -Hourlier, M. scheffler, and P. Greil, "Polysilsesquioxane Derived Ceramic Foams with Gradient Porosity," Acta Materialia, 53 927-37 (2005). https://doi.org/10.1016/j.actamat.2004.10.039
  11. P. N. De Aza, F. Guitian, and S. De Aza, "Bioactivity of Wollastonite Ceramics: In Vitro Evaluation," Scripta Metall. Mater., 31 1001-1005 (1994). https://doi.org/10.1016/0956-716X(94)90517-7
  12. P. Siriphannon, Y. Kameshima, A. Yasumori, K. Okada, and S. Hayashi, "Formation of Hydroxyapatite on $CaSiO_3$ Powders in Simulated Body Fluid," J. Eur. Ceram. Soc., 22 511-20 (2002). https://doi.org/10.1016/S0955-2219(01)00301-6
  13. K. Lin, W. Zhai, S. Ni, J. Chang, Y. Zeng, and W. Qian, "Study of the Mechanical Property and In Vitro Biocompatibility of $CaSiO_3$ Ceramics," Ceramics International, 31 323-26 (2005). https://doi.org/10.1016/j.ceramint.2004.05.023

Cited by

  1. Effect of SiC Filler Content on Microstructure and Flexural Strength of Highly Porous SiC Ceramics Fabricated from Carbon-Filled Polysiloxane vol.49, pp.6, 2012, https://doi.org/10.4191/kcers.2012.49.6.625
  2. Effect of Additive Composition on Flexural Strength of Cullet-Loess Tile Bodies vol.50, pp.6, 2013, https://doi.org/10.4191/kcers.2013.50.6.416
  3. Flexural Strength of Polysiloxane-Derived Strontium-Doped SiOC Ceramics vol.52, pp.1, 2015, https://doi.org/10.4191/kcers.2015.52.1.61
  4. 동결 주조법으로 제조된 티타늄 옥사이드 폼의 구조 연구 vol.49, pp.5, 2011, https://doi.org/10.4191/kcers.2012.49.5.427