Journal of Industrial and Engineering Chemistry

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Effects of oxyfluorination on a multi-walled carbon nanotube electrode for a high-performance glucose sensor

  • Yu, Hye-Ryeon (Department of Fine Chemical Engineering and Applied Chemistry, BK21-E M, Chungnam National University) ;
  • Kim, Jong Gu (Department of Fine Chemical Engineering and Applied Chemistry, BK21-E M, Chungnam National University) ;
  • Im, Ji Sun (Department of Fine Chemical Engineering and Applied Chemistry, BK21-E M, Chungnam National University) ;
  • Bae, Tae-Sung (Department of Fine Chemical Engineering and Applied Chemistry, BK21-E M, Chungnam National University) ;
  • Lee, Young-Seak (Department of Fine Chemical Engineering and Applied Chemistry, BK21-E M, Chungnam National University)
  • Published : 2012.03.25
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Abstract

A glucose sensor electrode was prepared with multi-walled carbon nanotubes (MWNTs) because of its effect on surface modification through oxyfluorination. The oxyfluorination of MWNTs was carried out with $F_2:O_2$ ratios of 7:3, 5:5 and 3:7, which are labeled F7O3-MWNT, F5O5-MWNT, and F3O7-MWNT, based on the oxyfluorination conditions. The hydrophilic functional groups were introduced effectively on the hydrophobic carbon surface. In addition, the amorphous area of the MWNTs was affected by oxyfluorination. The reactivity of the glucose sensor was affected by the oxyfluorination treatment and the existence of amorphous on MWNTs. The optimum O/F percentage was approximately 50%. Therefore, the oxyfluorination conditions are important with amorphous MWNTs. The sensitivity was improved based on the effects of improved interface affinity between the enzyme and the carbon electrode. In addition, the presence of an amorphous area on MWNTs seems to be beneficial for efficient glucose oxidase immobilization, which results in high-performance glucose sensing.

Keywords

References

  1. F. Xu, F. Wang, M.N. Gao, L.T. Jin, J.Y. Jin, Talanta 57 (2002) 365. https://doi.org/10.1016/S0039-9140(02)00038-3
  2. V. Lopez-Avila, H.H. Hill, Anal. Chem. 69 (1997) 289. https://doi.org/10.1021/a19700121
  3. J.V.D. Melo, S. Cosnier, C. Mousty, C. Martelet, N. Jaffrezic-Renaulta, Anal. Chem. 74 (2002) 4037. https://doi.org/10.1021/ac025627+
  4. L.C. Clark Jr., C. Lyons, Ann. N. Y. Acad. Sci. 102 (1962) 29.
  5. C.C. Liu, E.J. Lahoda, R.T. Galasco, L.B. Wingard, Biotechnol. Bioeng. 17 (1975) 1695. https://doi.org/10.1002/bit.260171111
  6. D. Savitri, C.K. Mitra, Bioelectrochemistry 47 (1) (1998) 67. https://doi.org/10.1016/S0302-4598(98)00158-5
  7. E.J. Lahoda, C.C. Liu, L.B. Wingard, Biotechnol. Bioeng. 17 (1975) 413. https://doi.org/10.1002/bit.260170309
  8. Z. Rosenzweig, R. Kopelman, Sens. Actuators B: Chem. (1996) 475.
  9. A.A. Manedov, N.A. Kotov, M. Prato, K.M. Guldi, J.P. Wichksted, A. Hirsch, Nat. Mater. 1 (3) (2002) 190. https://doi.org/10.1038/nmat747
  10. T. Zeng, T. Claus, F. Zhang, W. Du, K.L. Cooper, Smart Mater. Struct. 10 (2001) 780. https://doi.org/10.1088/0964-1726/10/4/323
  11. T. Saito, K. Matsushige, K. Tanake, Physica B 323 (2002) 280. https://doi.org/10.1016/S0921-4526(02)00999-7
  12. G. Zheming, L. Chunzhong, W. Gengchao, Z. Ling, C. Qilin, L. Xiaohui, J. Korean Ind. Eng. Chem. 16 (1) (2010) 10. https://doi.org/10.1016/j.jiec.2010.01.028
  13. Y.Y. Kim, J. Yun, Y.S. Lee, H.I. Kim, Carbon Lett. 12 (1) (2011) 48. https://doi.org/10.5714/CL.2011.12.1.048
  14. J.M. Lee, S.J. Kim, J.W. Lim, T.H. Kang, Y.C. Nho, Y.S. Lee, J. Korean Ind. Eng. Chem. 15 (2009) 66. https://doi.org/10.1016/j.jiec.2008.08.010
  15. T. Cheng, H. Lin, M. Chuang, Mater. Lett. 58 (2004) 650. https://doi.org/10.1016/S0167-577X(03)00586-X
  16. T. Seguchi, T. Yagi, S. Ishikawa, Y. Sano, Phys. Chem. 63 (2002) 35.
  17. M.J. Jung, J.W. Lim, I.J. Park, Y.S. Lee, Appl. Chem. Eng. 21 (3) (2010) 317.
  18. J.S. Im, S.J. Kim, P.H. Kang, Y.S. Lee, J. Korean Ind. Eng. Chem. 15 (2009) 699. https://doi.org/10.1016/j.jiec.2009.09.048
  19. M. Anand, J.P. Hobbs, I.J. Brass, R.E. Banks, B.E. Smart, J.C. Tatlow, Organofluorine Chemistry: Principles and Commercial Applications, Plenum Press, New York, 1994
  20. Y.S. Lee, B.K. Lee, Carbon 40 (2002) 2461. https://doi.org/10.1016/S0008-6223(02)00152-5
  21. J.S. Im, S.J. Park, Y.S. Lee, Int. J. Hydrogen Energy 34 (3) (2009) 1423. https://doi.org/10.1016/j.ijhydene.2008.11.054
  22. R. Wilson, A.P.F. Turner, Biosens. Bioelectron. 7 (1992) 165. https://doi.org/10.1016/0956-5663(92)87013-F
  23. Z. Wu, J. Li, D. Timmer, K. Lozano, S. Bose, Int. J. Adhes. Adhes. 29 (5) (2009) 488. https://doi.org/10.1016/j.ijadhadh.2008.10.003
  24. T. Nakajima, Fluorine-Carbon and Fluorine-Carbon Materials, Marcel Dekker, New York, 1995.
  25. S.J. Park, M.K. Seo, Y.S. Lee, Carbon 41 (2003) 723. https://doi.org/10.1016/S0008-6223(02)00384-6
  26. J.M. Lee, J.W. Kim, J.S. Lim, T.J. Kim, S.D. Kim, S.J. Park, Y.S. Lee, Carbon Lett. 8 (2) (2007) 120. https://doi.org/10.5714/CL.2007.8.2.120
  27. A. Misra, A.K. Tyagi, M.K. Singh, D.S. Misra, Diamond Relat. Mater. 15 (2006) 385. https://doi.org/10.1016/j.diamond.2005.08.013
  28. B. Kim, W.M. Sigmund, Langmuir 20 (2004) 8239. https://doi.org/10.1021/la049424n
  29. R.A. Afre, T. Soga, T. Jimbo, M. Kumar, Y. Ando, M. Sharon, Chem. Phys. Lett. 414 (2005) 6. https://doi.org/10.1016/j.cplett.2005.08.040
  30. L. Zhang, V. Liao, Z. Yu, Carbon 48 (2010) 2582. https://doi.org/10.1016/j.carbon.2010.03.061
  31. J.S. Im, S.C. Kang, B.C. Bai, J.K. Suh, Y.S. Lee, Int. J. Hydrogen Energy 36 (2011) 1560. https://doi.org/10.1016/j.ijhydene.2010.10.024
  32. J. Wang, Chem. Rev. 108 (2) (2008) 814. https://doi.org/10.1021/cr068123a
  33. R. Khan, A. Kaushik, P.R. Solanki, A.A. Ansari, M.K. Pandey, B.D. Malhotra, Anal. Chem. Acta 616 (2008) 207. https://doi.org/10.1016/j.aca.2008.04.010
  34. X. Liu, Y. Peng, X. Qu, S. Ai, R. Han, X. Zhu, J. Electroanal. Chem. 654 (2011) 72. https://doi.org/10.1016/j.jelechem.2011.01.024
  35. S. Saha, S.K. Arya, S.P. Singh, K. Sreenivas, B.D. Malhotra, V. Gupta, Anal. Chim. Acta 653 (2009) 212. https://doi.org/10.1016/j.aca.2009.09.002

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